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Electrochemical performances of graphene and MWCNT supported metallurgical grade silicon anodes

  • Gizem Hatipoglu
  • Miraç Alaf
  • Hatem Akbulut
Article
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Abstract

In this study, we described the production of metallurgical grade silicon based MWCNTs and graphene reinforced composite anodes to be an alternative for solving the volume expansion problem of silicon anodes. The active materials of composite anodes were prepared via high energy ball milling methods. The first stage of production was to grind the low cost metallurgical grade silicon into micrometer particles by ring milling and high-energy ball milling methods. To get yolk–shell structure, the obtained particles were coated with carbon and etched by using hydrofluoric acid, respectively. Hummers method was used to prepare graphene oxide and the obtained graphene oxide was reduced to graphene via using hydrazine hydrate solution. We used scanning electron microscopy and X-ray diffraction to evaluate the structure and morphology of the composite anodes. The electrochemical performances of composite anodes were characterized by galvanostatic charge/discharge, cyclic voltammetry and electrochemical impedance spectroscopy techniques. The results indicated that the yolk-shell structured silicon/MWCNT/Graphene composite anode yielded specific discharge capacity value of 695.65 mAh/g after 500 cycles at the current density of 200 mA/g.

Notes

Acknowledgements

This work is supported by the Scientific and Technological Research Council of Turkey (TUBITAK) under the contract number 214M125. The authors would like to thank TUBITAK and acknowledge the contribution of the COST Action CA15107 (MultiComp). We thank Davut Uzun, Associate Professor for support about TUBITAK Marmara Research Center Battery Technologies Laboratory.

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Dept. of Metallurgy and Materials EngineeringSakarya UniversitySakaryaTurkey
  2. 2.Dept. of Metallurgy and Materials EngineeringBilecik Şeyh Edebali UniversityBilecikTurkey

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