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Preparation and characterization of BaCo0.5Nb0.5O3-based new high temperature NTC sensitive ceramics

  • Xvqiong LiEmail author
  • Ying Luo
  • Guohua Chen
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Abstract

A new type of high temperature NTC thermal sensitive ceramics BaCoxNbxTi(1−2x)O3 (BCNT) was synthesized via a solid-state reaction process. The as-prepared ceramics were obtained by sintering at 1300 °C for 1 h in air. According to the XRD and SEM analysis, BCNT form a solid solution with cubic phase, and the content of BaTiO3 (BT) has insignificant influence on the mean grain size of the ceramics. The BaCo0.5Nb0.5O3 (BCN) based materials show typical NTC effect in the whole temperature measuring range (25–500 °C). The room temperature resistivity (ρ25), thermal constant (B25/85) and activation energy (Ea) increase monotonously with the increase of BT content. The TG-DSC results show that there is no phase transition in the temperature range from 25 to 1000 °C, which indicate that the structure of the BCN-based ceramics is stable at high temperature.

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Notes

Acknowledgements

The authors gratefully acknowledge the National Science Foundation of China (Grant No. 51462005) for providing the financial support.

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Guangxi Key Laboratory of Precision Navigation Technology and ApplicationGuilin University of Electronic TechnologyGuilinPeople’s Republic of China
  2. 2.Research Center for Materials Science and EngineeringGuilin University of Electronic TechnologyGuilinPeople’s Republic of China
  3. 3.Guangxi Key Laboratory of Super Hard Materials, Chinese National Engineering Research Center for Special Mineral MaterialsChina Nonferrous Metal (Guilin) Geology and Mining Co, LtdGuilinPeople’s Republic of China

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