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Facile synthesis of SiO2/C anode using PVC as carbon source for lithium-ion batteries

  • Jian Li
  • Shengliang Yang
  • Hongming ZhouEmail author
  • Lihua Wang
  • Zhaohui Yang
  • Pengyu Meng
  • Leshan Hu
  • Rong Hu
Article
  • 150 Downloads

Abstract

SiO2/C composites using polyvinyl chloride (PVC) as carbon sources are prepared successfully via a facile and low-cost approach. In this paper, the effect of four coating ratios on the SiO2/C materials is investigated. When tested as an anode material for lithium-ion batteries, the samples possessing a high carbon content display a better electrochemical stability. The high-content PVC pyrolytic carbon can provide a malleable and high electrical conductivity carbon layer for SiO2, which has more defects and benefits the diffusion of Li ions between the electrolyte and SiO2/C. However, considering the low capacity of the PVC pyrolytic carbon, a carbon content of 25% was chosen as the best coating ratio. This SiO2/C electrode shows a reversible capacity of 695 mAh g−1 at a current density of 100 mA g−1 after 200 cycles, with a capacity retention of 86.4% after the first cycle. The electrode also displays a discharge capacity of 535 mAh g−1 at a current density of 1 A g−1. Taking into consideration the facileness and the low cost of the synthetic method, this SiO2/C composite anode material may have a great prospect of industrialization.

Notes

Funding

This study was funded by "Natural Science Foundation of Jilin Province (51371198) and Natural Science Foundation of Hunan province (2017JJ2168).

References

  1. 1.
    J.B. Goodenough, K.S. Park, J. Am. Chem. Soc. 135(4), 1167 (2013)Google Scholar
  2. 2.
    M. Armand, J.M. Tarascon, Nature 451(7179), 652 (2008)Google Scholar
  3. 3.
    R.C. Ambare, R.S. Mane, B.J. Lokhande, Int. J. Adv. Res. 3, 1943 (2016)Google Scholar
  4. 4.
    L. Ji, X. Zhang, Carbon 47(14), 3219 (2009)Google Scholar
  5. 5.
    J. Zhang, C. Zhang, Z. Liu, J. Zheng, Y. Zuo, C. Xue, C. Li, B. Cheng, J. Power Sources 339, 86 (2017)Google Scholar
  6. 6.
    M.N. Obrovac, L.J. Krause, J. Electrochem. Soc. 154(2), A103 (2007)Google Scholar
  7. 7.
    N. Fukata, M. Mitome, Y. Bando, W. Wu, Z.L. Wang, Nano Energy 26, 37 (2016)Google Scholar
  8. 8.
    K. Xiao, Q. Tang, Z. Liu, A. Hu, S. Zhang, W. Deng, X. Chen, Ceram. Int. 44(4), 3548 (2017)Google Scholar
  9. 9.
    Z.S. Wen, J. Yang, B.F. Wang, K. Wang, Y. Liu, Electrochem. Commun. 5(2), 165 (2003)Google Scholar
  10. 10.
    X. Zuo, J. Zhu, P. Müller-Buschbaum, Y. Cheng, Nano Energy 31, 113 (2017)Google Scholar
  11. 11.
    T. Chen, J. Wu, Q. Zhang, X. Su, J. Power Sources 363, 126 (2017)Google Scholar
  12. 12.
    Y. Yao, J. Zhang, L. Xue, T. Huang, A. Yu, J. Power Sources 196(23), 10240 (2011)Google Scholar
  13. 13.
    W.S. Chang, C.M. Park, J.H. Kim, Y.U. Kim, G. Jeong, H.J. Sohn, Energy Environ. Sci. 5(5), 6895 (2012)Google Scholar
  14. 14.
    L. Wang, J. Xue, B. Gao, P. Gao, C. Mou, J. Li, RSC Adv. 4(110), 64744 (2014)Google Scholar
  15. 15.
    G. Lener, A.A. Garcia-Blanco, O. Furlong, M. Nazzarro, K. Sapag, D.E. Barraco, E.P.M. Leiva, Electrochim. Acta 279, 289 (2018)Google Scholar
  16. 16.
    Y. Zhou, Z. Tian, R. Fan, S. Zhao, R. Zhou, H. Guo, Z. Wang, Powder Technol. 284, 365 (2015)Google Scholar
  17. 17.
    S. Wang, N. Zhao, C. Shi, E. Liu, C. He, F. He, L. Ma, Appl. Surf. Sci. 433, 428 (2018)Google Scholar
  18. 18.
    Z. Gu, X. Xia, C. Liu, X. Hu, Y. Chen, Z. Wang, H. Liu, J. Alloys Compd. 757, 265 (2018)Google Scholar
  19. 19.
    H. Xia, Z. Yin, F. Zheng, Y. Zhang, Mater. Lett. 205, 83 (2017)Google Scholar
  20. 20.
    D. Nan, J.G. Wang, Z.H. Huang, L. Wang, W. Shen, F. Kang, Electrochem. Commun. 34(9), 52 (2013)Google Scholar
  21. 21.
    W.R. Liu, Y.C. Yen, H.C. Wu, M. Winter, N.L. Wu, J. Appl. Electrochem. 39(9), 1643 (2009)Google Scholar
  22. 22.
    Y. Jiang, D. Mu, S. Chen, B. Wu, Z. Zhao, Y. Wu, Z. Ding, F. Wu, J. Alloys Compd. 744, 7 (2018)Google Scholar
  23. 23.
    H.Y. Lee, J.K. Baek, S.W. Jang, S.M. Lee, S.T. Hong, K.Y. Lee, M.H. Kim, J. Power Sources 101(2), 206 (2001)Google Scholar
  24. 24.
    H. Aso, K. Matsuoka, A. Sharma, A. Tomita, Carbon 42(14), 2963 (2004)Google Scholar
  25. 25.
    F. Albertúsa, A. Llerena, J. Alpízar, V. Cerdá, M. Luque, A. Ríos, M. Valcárcel, Anal. Chim. Acta 355(1), 23 (1997)Google Scholar
  26. 26.
    H.L. Zhang, F. Li, C. Liu, H.M. Cheng, J. Phys. Chem. C 112(20), 7767 (2008)Google Scholar
  27. 27.
    Y. Bai, Z. Wang, C. Wu, R. Xu, F. Wu, Y. Liu, H. Li, Y. Li, J. Lu, K. Amine, ACS Appl. Mater. Interfaces 7(9), 5598 (2015)Google Scholar
  28. 28.
    Q. Si, K. Hanai, T. Ichikawa, A. Hirano, N. Imanishi, Y. Takeda, O. Yamamoto, J. Power Sources 195(6), 1720 (2010)Google Scholar
  29. 29.
    S.J. Park, Y.J. Kim, H. Lee, J. Power Sources 196(11), 5133 (2011)Google Scholar
  30. 30.
    H. Li, H. Zhou, Chem. Commun. 48(9), 1201 (2012)Google Scholar
  31. 31.
    A. Castro, D. Soares, C. Vilarinho, F. Castro, Waste Manag. 32(5), 847 (2012)Google Scholar
  32. 32.
    X. Wu, Z. Shi, C. Wang, J. Jin, J. Electroanal. Chem. 746, 62 (2015)Google Scholar
  33. 33.
    X. Ma, Z. Wei, H. Han, X. Wang, K. Cui, L. Yang, Chem. Eng. J. 323(1), 252 (2018)Google Scholar
  34. 34.
    L. Yin, M. Wu, Y. Li, G. Wu. Y. Wang, Y. Wang, New Carbon Mater. 32(4), 311 (2017)Google Scholar
  35. 35.
    B.J. Lokhande, R.C. Ambare, R.S. Mane, S.R. Bharadwaj, Curr. Appl. Phys. 13, 985 (2013)Google Scholar
  36. 36.
    Y. Ren, M. Li, J. Power Sources 306, 459 (2016)Google Scholar
  37. 37.
    Y. Hyun, J.Y. Choi, H.K. Park, J. Young Bae, C.S. Lee, Mater. Res. Bull. 82(1), 92 (2016)Google Scholar
  38. 38.
    H. Wu, Y. Cui, Nano Today 7(5), 414 (2012)Google Scholar
  39. 39.
    H. Nara, T. Yokoshima, T. Momma, T. Osaka, Energy Environ. Sci. 5, 6500 (2012)Google Scholar
  40. 40.
    H. Nara, T. Yokoshima, M. Otaki, T. Momma, T. Osaka, Electrochim. Acta 110, 403 (2013)Google Scholar
  41. 41.
    L. Zhang, K. Shen, W. He, Y. Liu, S. Guo, Int. J. Electrochem. Sci. 12, 10221 (2017)Google Scholar
  42. 42.
    X. Liu, Y. Chen, H. Liu, Z.Q. Liu, J. Mater. Sci. Technol. 33(3), 239 (2016)Google Scholar
  43. 43.
    Y. Ju, J.A. Tang, K. Zhu, Y. Meng, C. Wang, G. Chen, Y. Wei, Y. Gao, Electrochim. Acta 191, 411 (2016)Google Scholar
  44. 44.
    R.C. Ambare, S.R. Bharadwaj, B.J. Lokhande, Appl. Surf. Sci. 349, 887 (2015)Google Scholar
  45. 45.
    R.C. Ambare, P. Shinde, U.T. Nakate, B.J. Lokhande, R.S. Mane, Appl. Surf. Sci. 453, 214 (2018)Google Scholar
  46. 46.
    M. Zhou, F. Pu, Z. Wang, T. Cai, H. Chen, H. Zhang, S. Guan, Phys. Chem. Chem. Phys. 15(27), 11394 (2013)Google Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringCentral South UniversityChangshaChina
  2. 2.Hunan Zhengyuan Institute for Energy Storage Materials and DevicesChangshaChina

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