Advertisement

Energy transfer and multicolor tunable emission in single-phase Eu3+ doped K3TbB6O12 phosphors

  • Ji Zhao
  • Dan Zhao
  • Ya-Ping Yu
  • Shan-Xiu Huang
  • Rui-Juan Zhang
  • Wei Wei
  • Zhao Ma
  • Bao-Zhong Liu
Article

Abstract

A series of green-to-red color-tunable K3Tb1−xEuxB6O12 phosphors were synthesized via the high temperature solid-state reaction method. The crystal structure, morphology, luminescent properties and energy transfer of K3Tb1−xEux B6O12 were systematically investigated in detail. The obtained phosphors display both a green emission of Tb3+ and a red emission of Eu3+ with considerable intensity under ultraviolet excitation (377 nm). The emission colors of the phosphors can be tuned from green (0.291, 0.598) through yellow (0.528, 0.428), orange (0.573, 0.387) and eventually to red (0.629, 0.357) by adjusting the x values. These results show that the K3Tb1−xEuxB6O12 phosphors may find potential applications in the field of displays and lighting.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21201056, 51671080, 51471065, 21201056 and U1304522), and Program for Innovative Research Team (in Science and Technology) in the University of Henan Province (16IRTSTHN005).

Supplementary material

10854_2018_152_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2397 KB)

References

  1. 1.
    H.K. Liu, L.B. Liao, D. Yang, Q.F. Guo, L.F. Mei, Ceram. Int. 42, 16579 (2016)CrossRefGoogle Scholar
  2. 2.
    H.J. Deng, Z.W. Gao, N. Xue, J.H. Jeong, R.J. Yu, J. Lumin. 192, 684 (2017)CrossRefGoogle Scholar
  3. 3.
    J. Zhang, M.X. Chen, Y.L. Gao, Displays 49, 35 (2017)CrossRefGoogle Scholar
  4. 4.
    X.Y. Fu, L.J. Fang, S.Y. Niu, H.W. Zhang, J. Lumin. 142, 163 (2013)CrossRefGoogle Scholar
  5. 5.
    B. Han, J.T. Zhang, B.K. Liu, J. Zhang, H.Z. Shi, Mater. Lett. 181, 305 (2016)CrossRefGoogle Scholar
  6. 6.
    X.B. Li, Q. Liu, W.T. Huang, S.H. Chen, L.X. Wang, M.X. Yu, Q.T. Zhang, Ceram. Int. 44, 1909 (2018)CrossRefGoogle Scholar
  7. 7.
    Z.F. Mu, E.H. Song, D.Y. Zhu, J.Q. Feng, Y.T. Yang, Displays 43, 18 (2016)CrossRefGoogle Scholar
  8. 8.
    C.H. Huang, T.W. Kuo, T.M. Chen, ACS Appl. Mater. Inter. 2, 1395 (2010)CrossRefGoogle Scholar
  9. 9.
    T. Sakamoto, S. Kousaka, K. Uematsu, T. Lshigaki, K. Toda, M. Sato, Phys. Status Solidi 8, 2731 (2011)CrossRefGoogle Scholar
  10. 10.
    J.H. Kim, M.J. Kim, J.H. Song, I.K. Choi, D.H. Park, Y.C. You, Y.C. You, Y.C. Kim, D.S. Zang, SID Digest Tech. Papers 40, 258 (2012)CrossRefGoogle Scholar
  11. 11.
    L. Chen, Y. Jiang, G. Yang, G. Zhang, X. Xin, D. Kong, J. Rare Earth 27, 312 (2009)CrossRefGoogle Scholar
  12. 12.
    M.X. Zhao, Z.J. Zhao, L.Q. Yang, L.L. Dong, A.Q. Xia, S.Y. Chang, Y.H. Wei, Z.P. Liu, J. Lumin. 194, 297 (2018)CrossRefGoogle Scholar
  13. 13.
    D.Y. Wang, T.M. Chen, B.M. Cheng, Inorg. Chem. 51, 2961 (2012)CrossRefGoogle Scholar
  14. 14.
    J.T. Ingle, A.B. Gawande, R.P. Sonekar, S.K. Omanwar, Y. Wang, L. Zhao, J. Alloy. Compd. 585, 633 (2014)CrossRefGoogle Scholar
  15. 15.
    A. Shyichuk, S. Lis, Mater. Chem. Phys. 140, 447 (2013)CrossRefGoogle Scholar
  16. 16.
    D. Zhan, F.X. Ma, R.J. Zhang, M. Huang, P.F. Chen, R.H. Zhang, W. Wei, Z. Krist-Cryst. Mater. 231, 525 (2016)Google Scholar
  17. 17.
    R.D. Shanon, Acta Cryst 32, 751 (1976)CrossRefGoogle Scholar
  18. 18.
    X.G. Zhang, J.L. Zhang, Y.B. Chen, M.L. Gong, Ceram. Int. 42, 13919 (2016)CrossRefGoogle Scholar
  19. 19.
    D. Zhao, F.X. Ma, Y.C. Fan, L. Zhang, R.J. Zhang, P.G. Duan, Dalton Trans. 46, 8673 (2017)CrossRefGoogle Scholar
  20. 20.
    J. Zhao, S.X. Huang, D. Zhao, J. Chen, Y. Tian, Q. Zong, Y.C. Fan, C.K. Nie, B.Z. Liu, Optik 161, 342 (2018)CrossRefGoogle Scholar
  21. 21.
    Y.G. Zhu, C. Tong, R.Q. Dai, C.Y. Xu, L. Yang, Y.D. Li, Mater. Lett. 213, 245 (2018)CrossRefGoogle Scholar
  22. 22.
    B. Han, Y.Z. Dai, J. Zhang, H.Z. Shi, Mater. Lett. 204, 145 (2017)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Chemistry and Chemical EngineeringHenan Polytechnic UniversityJiaozuoChina
  2. 2.Department of ChemistryCapital Normal UniversityBeijingChina
  3. 3.Henan Key Laboratory of Coal Green ConversionHenan Polytechnic UniversityJiaozuoChina

Personalised recommendations