It is greatly meaningful but remains very challenging to obtain high-performance microwave absorber with thin thickness, lightweight, wide bandwidth, and strong absorption. Here, sulfur-enriched nitrogen-doped carbon nanofibers (S-NCFs) with excellent microwave absorption performance have been constructed through electrospinning technology and heat treatment with sublimed sulfur. Experimental results and the theoretical calculation evidenced that nitrogenous carbon nanofibers doping with sulfur could not only generate a large number of electric dipoles but also favor the promotion of conductivity. Benefiting from the unique architecture and heteroatoms doping that contributed to the well-matched impedance and dielectric enhancement, the S-NCFs exhibited the minimum reflection loss (RL) of − 48.67 dB at 16.1 GHz with a matching thickness of 1.39 mm at a filler loading of as low as 15%. In addition, the samples can obtain the broadest effective absorption bandwidth (EAB, RL < − 10 dB) of 4.90 GHz with the thickness of 1.53 mm. This work provides a facile and efficient approach for fabricating carbon materials as lightweight and highly efficient microwave absorbers.
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Ma M, Yang R, Zhang C, Wang B, Zhao Z, Hu W, Liu Z, Yu D, Wen F, He J, Tian Y (2019) Direct large-scale fabrication of C-encapsulated B4C nanoparticles with tunable dielectric properties as excellent microwave absorbers. Carbon 148:504–511
Xie P, Zhang Z, Wang Z, Sun K, Fan R (2019) Targeted double negative properties in silver/silica random metamaterials by precise control of microstructures. Research 2019:1021368
Ren K, Wang Y, Ye C, Du Z, Bian J, Long C, Zhao S, Li W, Guan J (2019) Realizing significant dielectric dispersion of composites based on highly conducting silver-coated glass microspheres for wide-band non-magnetic microwave absorbers. J Mater Chem C 7:528–542
Li X, Wang L, You W, Xing L, Yu X, Li Y, Che R (2019) Morphology-controlled synthesis and excellent microwave absorption performance of ZnCo2O4 nanostructures via a self-assembly process of flake units. Nanoscale 11:2694–2702
Xie P, Li H, He B, Dang F, Lin J, Fan R, Hou C, Liu H, Zhang J, Ma Y, Guo Z (2018) Bio-gel derived nickel/carbon nanocomposites with enhanced microwave absorption. J Mater Chem C 6:8812–8822
Yin Y, Liu X, Wei X, Yu R, Shui J (2016) Porous CNTs/Co composite derived from zeolitic imidazolate framework: a lightweight, ultrathin, and highly efficient electromagnetic wave absorber. ACS Appl Mater Interfaces 8:34686–34698
Liu Y, Chen Z, Xie W, Song S, Zhang Y, Dong L (2019) In-situ growth and graphitization synthesis of porous Fe3O4/carbon fiber composites derived from biomass as lightweight microwave absorber. ACS Sustain Chem Eng 7:5318–5328
Liu J, Che R, Chen H, Zhang F, Xia F, Wu Q, Wang M (2012) Microwave absorption enhancement of multifunctional composite microspheres with spinel Fe3O4 cores and anatase TiO2 shells. Small 8:1214–1221
Jiang Y, Fu X, Zhang Z, Du W, Xie P, Cheng C, Fan R (2019) Enhanced microwave absorption properties of Fe3C/C nanofibers prepared by electrospinning. J Alloys Compd 804:305–313
Xu H, Yin X, Fan X, Tang Z, Hou Z, Li M, Li X, Zhang L, Cheng L (2019) Constructing a tunable heterogeneous interface in bimetallic metal-organic frameworks derived porous carbon for excellent microwave absorption performance. Carbon 148:421–429
Wei H, Yin X, Li X, Li M, Dang X, Zhang L, Cheng L (2019) Controllable synthesis of defective carbon nanotubes/Sc2Si2O7 ceramic with adjustable dielectric properties for broadband high-performance microwave absorption. Carbon 147:276–283
Cheng C, Fan R, Fan G, Liu H, Zhang J, Shen J, Ma Q, Wei R, Guo Z (2019) Tunable negative permittivity and magnetic performance of yttrium iron garnet/polypyrrole metacomposites at the RF frequency. J Mater Chem C 7:3160–3167
Lu Y, Wang Y, Li H, Lin Y, Jiang Z, Xie Z, Kuang Q, Zheng L (2015) MOF-derived porous Co/C nanocomposites with excellent electromagnetic wave absorption properties. ACS Appl Mater Interfaces 7:13604–13611
Li X, Yin X, Xu H, Han M, Li M, Liang S, Cheng L, Zhang L (2018) Ultralight MXene-coated, interconnected SiCnws three-dimensional lamellar foams for efficient microwave absorption in the X-band. ACS Appl Mater Interfaces 10:34524–34533
Quan B, Shi W, Ong SJH, Lu X, Wang PL, Ji G, Guo Y, Zheng L, Xu ZJ (2019) Defect engineering in two common types of dielectric materials for electromagnetic absorption applications. Adv Funct Mater 29:1901236
Qu Y, Du Y, Fan G, Xin J, Liu Y, Xie P, You S, Zhang Z, Sun K, Fan R (2019) Low-temperature sintering Graphene/CaCu3Ti4O12 nanocomposites with tunable negative permittivity. J Alloys Compd 771:699–710
Wang F, Wang N, Han X, Liu D, Wang Y, Cui L, Xu P, Du Y (2019) Core-shell FeCo@carbon nanoparticles encapsulated in polydopamine-derived carbon nanocages for efficient microwave absorption. Carbon 145:701–711
Cheng Y, Li Z, Li Y, Dai S, Ji G, Zhao H, Cao J, Du Y (2018) Rationally regulating complex dielectric parameters of mesoporous carbon hollow spheres to carry out efficient microwave absorption. Carbon 127:643–652
Krivanek OL, Chisholm MF, Nicolosi V, Pennycook TJ, Corbin GJ, Dellby N, Murfitt MF, Own CS, Szilagyi ZS, Oxley MP (2010) Atom-by-atom structural and chemical analysis by annular dark-field electron microscopy. Nature 464:571
Zhang X, Guo J, Guan P, Qin G, Pennycook SJ (2015) Gigahertz dielectric polarization of substitutional single niobium atoms in defective graphitic layers. Phys Rev Lett 115:147601
Li X, Hu X, Zhou L, Wen R, Xu X, Chou S, Chen L, Cao A-M, Dou S (2019) A S/N-doped high-capacity mesoporous carbon anode for Na-ion batteries. J Mater Chem A 7:11976–11984
Hou C, Wang J, Du W, Wang J, Du Y, Liu C, Zhang J, Hou H, Dang F, Zhao L, Guo Z (2019) One-pot synthesized molybdenum dioxide–molybdenum carbide heterostructures coupled with 3D holey carbon nanosheets for highly efficient and ultrastable cycling lithium-ion storage. J Mater Chem A 7:13460–13472
Sun X, Wang C, Gong Y, Gu L, Chen Q, Yu Y (2018) A flexible sulfur-enriched nitrogen doped multichannel hollow carbon nanofibers film for high performance sodium storage. Small 14:e1802218
Liu J, Ji Y-G, Qiao B, Zhao F, Gao H, Chen P, An Z, Chen X, Chen Y (2018) N,S Co-doped carbon nanofibers derived from bacterial cellulose/poly(methylene blue) hybrids: efficient electrocatalyst for oxygen reduction reaction. Catalysts 8:269
Li Y, Liu R, Pang X, Zhao X, Zhang Y, Qin G, Zhang X (2018) Fe@C nanocapsules with substitutional sulfur heteroatoms in graphitic shells for improving microwave absorption at gigahertz frequencies. Carbon 126:372–381
Yuan X, Xue X, Ma H, Guo S, Cheng L (2017) Preparation of nitrogen and sulfur co-doped ordered mesoporous carbon for enhanced microwave absorption performance. Nanotechnology 28:375705
Liu Q, Cao Q, Bi H, Liang C, Yuan K, She W, Yang Y, Che R (2016) CoNi@SiO2 @TiO2 and CoNi@Air@TiO2 microspheres with strong wideband microwave absorption. Adv Mater 28:486–490
Zhang X, Ji G, Liu W, Quan B, Liang X, Shang C, Cheng Y, Du Y (2015) Thermal conversion of an Fe(3)O(4)@metal-organic framework: a new method for an efficient Fe-Co/nanoporous carbon microwave absorbing material. Nanoscale 7:12932–12942
Guo L, An Q, Xiao Z, Zhai S-R, Cui L (2019) Inherent N-doped honeycomb-like carbon/Fe3O4 composites with versatility for efficient microwave absorption and wastewater treatment. ACS Sustain Chem Eng 7:9237–9248
Kresse G, Joubert D (1999) From ultrasoft pseudopotentials to the projector augmented-wave method. Phys Rev B 59:1758–1775
Perdew JP, Burke K, Ernzerhof M (1996) Generalized gradient approximation made simple. Phys Rev Lett 77:3865–3868
Blöchl PE (1994) Projector augmented-wave method. Phys Rev B 50:17953–17979
Wu Z, Tian K, Huang T, Hu W, Xie F, Wang J, Su M, Li L (2018) Hierarchically porous carbons derived from biomasses with excellent microwave absorption performance. ACS Appl Mater Interfaces 10:11108–11115
Yang Y, Xu C, Xia Y, Wang T, Li F (2010) Synthesis and microwave absorption properties of FeCo nanoplates. J Alloys Compd 493:549–552
Xiang J, Li J, Zhang X, Ye Q, Xu J, Shen X (2014) Magnetic carbon nanofibers containing uniformly dispersed Fe/Co/Ni nanoparticles as stable and high-performance electromagnetic wave absorbers. J Mater Chem A 2:16905–16914
Liu Q, Liu X, Feng H, Shui H, Yu R (2017) Metal organic framework-derived Fe/carbon porous composite with low Fe content for lightweight and highly efficient electromagnetic wave absorber. Chem Eng J 314:320–327
Hou Y, Huang T, Wen Z, Mao S, Cui S, Chen J (2014) Metal − organic framework-derived nitrogen-doped core-shell-structured porous Fe/Fe3C@ C nanoboxes supported on graphene sheets for efficient oxygen reduction reactions. Adv Energy Mater 4:1400337
Ding D, Wang Y, Li X, Qiang R, Xu P, Chu W, Han X, Du Y (2017) Rational design of core-shell Co@C microspheres for high-performance microwave absorption. Carbon 111:722–732
Ma J, Zhang X, Liu W, Ji G (2016) Direct synthesis of MOF-derived nanoporous CuO/carbon composites for high impedance matching and advanced microwave absorption. J Mater Chem C 4:11419–11426
Huang L, Li J, Wang Z, Li Y, He X, Yuan Y (2019) Microwave absorption enhancement of porous C@CoFe2O4 nanocomposites derived from eggshell membrane. Carbon 143:507–516
Qiao Y, Ma M, Liu Y, Li S, Lu Z, Yue H, Dong H, Cao Z, Yin Y, Yang S (2016) First-principles and experimental study of nitrogen/sulfur co-doped carbon nanosheets as anodes for rechargeable sodium ion batteries. J Mater Chem A 4:15565–15574
Wu Z, Pei K, Xing L, Yu X, You W, Che R (2019) Enhanced microwave absorption performance from magnetic coupling of magnetic nanoparticles suspended within hierarchically tubular composite. Adv Funct Mater 29:1901448
Fang J, Shang Y, Chen Z, Wei W, Hu Y, Yue X, Jiang Z (2017) Rice husk-based hierarchically porous carbon and magnetic particles composites for highly efficient electromagnetic wave attenuation. J Mater Chem C 5:4695–4705
Fang J, Liu T, Chen Z, Wang Y, Wei W, Yue X, Jiang Z (2016) A wormhole-like porous carbon/magnetic particles composite as an efficient broadband electromagnetic wave absorber. Nanoscale 8:8899–8909
Li S, Huang Y, Ding L, Zong M, Zhang N, Qin X, Liu P (2019) Synthesis and enhancement of microwave absorption property by coating silicon dioxide and polyaniline for Fe-Co alloy. J Magn Magn Mater 486:165259
This work was supported by National Natural Science Foundation of China (No. 51601105), China Postdoctoral Science Foundation (Grant Nos. 2017M622199, 2018T110687), Young Elite Scientists Sponsorship Program by CAST (Grant No. 2017QNRC001), and Innovation Program of Shanghai Municipal Education Commission (Grant No. 2019-01-07-00-10-E00053).
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Jiang, Y., Fu, X., Tian, R. et al. Nitrogen-doped carbon nanofibers with sulfur heteroatoms for improving microwave absorption. J Mater Sci (2020). https://doi.org/10.1007/s10853-020-04430-y