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Journal of Materials Science

, Volume 54, Issue 23, pp 14624–14633 | Cite as

Copolymerization strategy to prepare polymethyl methacrylate-based copolymer with broad-band ultraviolet shielding and luminescent down-shifting properties

  • Junxian Huang
  • Heng ChenEmail author
  • Beibei Hao
  • Wei Dai
  • Shaojun ChenEmail author
Polymers & biopolymers
  • 176 Downloads

Abstract

In this contribution, copolymerization strategy was reported to prepare polymethyl methacrylate (PMMA)-based ultraviolet (UV) shielding copolymers where polymerizable UV absorbers were synthesized and further copolymerized with methyl methacrylate. The copolymer was characterized by 1H NMR, GPC, TGA, and UV–Vis spectroscopy. The prepared copolymer was found to exhibit high thermal stability compared with its blending counterparts, along with quite a high UV shielding efficiency demonstrated by the fact that full-band UV blocking was achieved when only 2% UV absorbers were added to copolymer. Furthermore, this copolymer also obtained high quantum yield luminescence that emitted bright blue light under UV irradiation. Given its good stability, high UV blocking efficiency, and outstanding luminescence property, the prepared PMMA copolymer is expected to have promising potential in UV shielding and photovoltaic applications.

Notes

Acknowledgement

The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China (Grant Nos. 51773120, 51802201), the Natural Science Foundation of Guangdong (Grant Nos. 2016A030313050, 2017A030310045), the Science and Technology Project of Shenzhen City (Grant Nos. JCYJ20170412105034748), the Top Talent Launch Scientific Research Projects of Shenzhen (827-000133), and the Graduate Innovation and Development Foundation of Shenzhen University (PIDFP-ZR2018030).

Supplementary material

10853_2019_3961_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2387 kb)

References

  1. 1.
    Zayat M, Garcia-Parejo P, Levy D (2007) Preventing UV-light damage of light sensitive materials using a highly protective UV-absorbing coating. Chem Soc Rev 36:1270–1281CrossRefGoogle Scholar
  2. 2.
    Rabek JF (1995) Polymer photodegradation. In: Mechanisms and experimental methods. Chapman & Hall, LondonGoogle Scholar
  3. 3.
    Pattison DI, Davies MJ (2006) Actions of ultraviolet light on cellular structures. In: Cancer: cell structures, carcinogens and genomic instability. Experientia supplementum, vol 96. Birkhäuser Basel, pp 131–157Google Scholar
  4. 4.
    Kim KH (2011) A comparative life cycle assessment of a transparent composite façade system and a glass curtain wall system. Energy Bulidings 43:3436–3445CrossRefGoogle Scholar
  5. 5.
    Wang J, Xu Y, Zhang W (2014) Finite element simulation of PMMA aircraft windshield against bird strike by using a rate and temperature dependent nonlinear viscoelastic constitutive model. Compos Struct 108:21–30CrossRefGoogle Scholar
  6. 6.
    Fang N, Lee H, Sun C, Zhang X (2005) Sub-diffraction-limited optical imaging with a silver superlens. Science 308:157–534CrossRefGoogle Scholar
  7. 7.
    Ali U, Karim KJBA, Buang NA (2015) A review of the properties and applications of poly(methyl methacrylate) (PMMA). Polym Rev 55:678–705CrossRefGoogle Scholar
  8. 8.
    Koziej D, Fischer F, Kränzlin N, Caseri WR, Niederberger M (2009) Nonaqueous TiO2 nanoparticle synthesis: a versatile basis for the fabrication of self-supporting, transparent, and UV-absorbing composite films. ACS Appl Mater Interfaces 1:1097–1104CrossRefGoogle Scholar
  9. 9.
    Zhang Y, Wang X, Liu YX, Song SY, Liu DP (2012) Highly transparent bulk PMMA/ZnO nanocomposites with bright visible luminescence and efficient UV-shielding capability. J Mater Chem 22:11971–11977CrossRefGoogle Scholar
  10. 10.
    Hu J, Zhou Y, Sheng X (2015) Optical diffusers with enhanced properties based on novel polysiloxane@CeO2@PMMA fillers. J Mater Chem C 3:2223–2230CrossRefGoogle Scholar
  11. 11.
    Indermühle C, Puzenat E, Simonet F, Peruchon L, Brochier C, Guillard C (2016) Modelling of UV optical ageing of optical fibre fabric coated with TiO2. Appl Catal B Environ 182:229–235CrossRefGoogle Scholar
  12. 12.
    Cockell CS, Knowland J (1999) Ultraviolet radiation screening compounds. Biol Rev 74:311–345CrossRefGoogle Scholar
  13. 13.
    Gago-Ferrero P, Díaz-Cruz MS, Barceló D (2012) An overview of UV-absorbing compounds (organic UV filters) in aquatic biota. Anal Bionanal Chem 404:2597–2610CrossRefGoogle Scholar
  14. 14.
    Stranks SD, Eperon GE, Grancini G, Menelaou C, Alcocer JP, Leijtens T, Herz LM, Petrozza A, Snaith HJ (2013) Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 342:341–344CrossRefGoogle Scholar
  15. 15.
    Li F, Ma C, Wang H, Hu W, Yu W, Sheikh AD, Wu T (2015) Ambipolar solution-processed hybrid perovskite phototransistors. Nat Commun 6:8238CrossRefGoogle Scholar
  16. 16.
    Liu J, Wang K, Zheng W, Huang W, Li CH, You XZ (2013) Improving spectral response of monocrystalline silicon photovoltaic modules using high efficient luminescent down-shifting Eu3 + complexes. Prog Photovolt Res Appl 21:668–675CrossRefGoogle Scholar
  17. 17.
    Hodgson SD, Brooks WSM, Clayton AJ, Kartopu G, Barrioz V, Irvine SJC (2013) Enhancing blue photoresponse in CdTe photovoltaics by luminescent down-shifting using semiconductor quantum dot/PMMA films. Nano Energy 2:21–27CrossRefGoogle Scholar
  18. 18.
    Li Y, Li Z, Wang Y, Compaan A, Ren T, Dong WJ (2013) Increasing the power output of a CdTe solar cell via luminescent down shifting molecules with intramolecular charge transfer and aggregation-induced emission characteristics. Energy Environ Sci 6:2907–2911CrossRefGoogle Scholar
  19. 19.
    Griffini G, Bella F, Nisic F, Dragonetti C, Levi M, Bongiovanni R, Turri S (2015) Multifunctional luminescant down-shifting fluoropolymer coating: a straightforward strategy to improve the UV-light harvesting ability and long-term outdoor stability of organic dye-sensitized solar cells. Adv Energy Mater 5:1401312CrossRefGoogle Scholar
  20. 20.
    Zhang X, Liu W, Yang D, Qiu X (2019) Biomimetic supertough and strong biodegradable polymeric materials with improved thermal properties and excellent UV-blocking performance. Adv Funct Mater 29:1806912CrossRefGoogle Scholar
  21. 21.
    Ding L, Liu L, Chen Y, Du Y, Guan S, Bai Y, Huang Y (2019) Modification of poly(ethylene terephthalate) by copolymerization of plant-derived α-truxillic acid with excellent ultraviolet shielding and mechanical properties. Chem Eng J 374:1317–1325CrossRefGoogle Scholar
  22. 22.
    Dong L, Liu XD, Xiong ZR, Sheng DK, Zhou Y, Yang YM (2019) Preparation and characterization of UV-absorbing PVDF membranes via pre-irradiation induced graft polymerization. Chin J Polym Sci 37:493–499CrossRefGoogle Scholar
  23. 23.
    Shi L, Yang JH, Zhang HB, Chen YM, Yang SC, Wu C, Zeng H, Yoshihito O, Zhang Q (2016) Carbon dots with high fluorescence quantum yield: the fluorescence originates from organic fluorophores. Nanoscale 8:14374–14378CrossRefGoogle Scholar
  24. 24.
    Chen H, Yan X, Feng Q, Zhao P, Xu X, Ng DHL, Bian L (2017) Citric acid/cysteine-modified cellulose-based materials: green preparation and their applications in anticounterfeiting, chemical sensing, and UV shielding. ACS Sustain Chem Eng 5:11387–11394CrossRefGoogle Scholar
  25. 25.
    Chen H, Li R, Xu X, Zhao P, Wong DSH, Chen X, Chen S, Yan X (2019) Citrate-based fluorophores in polymeric matrix by easy and green in situ synthesis for full-band UV shielding and emissive transparent display. J Mater Sci 54:1236–1247CrossRefGoogle Scholar
  26. 26.
    Xie Z, Kim JP, Cai Q, Zhang Y, Guo J, Dhami RS, Li L, Kong B, Su Y, Schug KA, Yang J (2017) Synthesis and characterization of citrate-based fluorescent small molecules and biodegradable polymers. Acta Biomater 50:361–369CrossRefGoogle Scholar
  27. 27.
    Birks JB (1970) Photophysics of aromatic molecules. Wiley, LondonGoogle Scholar
  28. 28.
    Uekert T, Solodovnyk A, Ponomarenko S, Osvet A, Levchuk I, Gast J, Batentschuk M, Forberich K, Stern E, Egelhaaf HJ, Brabec CJ (2016) Nanostructured organosilicon luminophores in highly efficient luminescent down-shifting layers for thin film photovoltaics. Sol Energy Mater Sol Cells 155:1–8CrossRefGoogle Scholar
  29. 29.
    McKenna B, Evans RC (2017) Towards efficient spectral converters through materials design for luminescent solar devices. Adv Mater 29:1606491CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Guangdong Research Centre for Interfacial Engineering of Functional Materials, Shenzhen Key Laboratory of Polymer Science and Technology, College of Materials Science and EngineeringShenzhen UniversityShenzhenChina

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