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Simple synthesis of TiNb6O17/C composite toward high-rate lithium storage

  • Ruixue Sun
  • Ying Tao
  • Hongxian Sun
  • Weihua Chen
  • Guangyin LiuEmail author
  • Yang YueEmail author
  • Min Hu
  • Miao Liu
Energy materials
  • 12 Downloads

Abstract

As one kind of promising anode materials for Li-ion batteries, titanium niobium oxides have attracted great attention due to their high theoretical capacities and high rate performances. Herein, TiNb6O17/C composite with TiNb6O17 nanocrystals distributed among amorphous carbon has been synthesized via an in situ sol–gel and then thermal decomposition process. The as-synthesized TiNb6O17/C composite presents reduced crystal size and improved electronic conductivity compared with the pristine TiNb6O17. The TiNb6O17/C displays both excellent rate performance (high specific capacity of 129 mA h g−1 at 30 C) and good cyclic performance (low capacity decay rate of 0.016% per cycle for 500 cycles at 10 C). These results indicate that the approach as reported is a simple yet effective way for high-performance anode with high-rate capability.

Notes

Acknowledgements

This work is supported by the National Natural Science Foundation of China (No. 21501101), the Natural Science Foundation of Henan Department of Education (No. 16B150012), the Technological Project of Henan Province (No. 172102210423), the Special Foundation of the Nanyang Normal University (No. 70356) and National Natural Science Foundation of China (21771164), Henan Province (No. 15HASTIT003).

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of Chemistry and Pharmaceutical EngineeringNanyang Normal UniversityNanyangPeople’s Republic of China
  2. 2.College of Chemistry and Molecular EngineeringZhengzhou UniversityZhengzhouPeople’s Republic of China
  3. 3.College of ScienceHenan Agricultural UniversityZhengzhouPeople’s Republic of China

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