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Journal of Materials Science

, Volume 54, Issue 23, pp 14378–14387 | Cite as

Highly conductive, flexible and functional multi-channel graphene microtube fabricated by electrospray deposition technique

  • He Gong
  • Meng-Fei Li
  • Jun-Xiang Yan
  • Miao-Ling Lin
  • Xue-Lu Liu
  • Bin Sun
  • Ping-Heng Tan
  • Yun-Ze Long
  • Wen-Peng HanEmail author
Composites & nanocomposites
  • 112 Downloads

Abstract

Highly conductive and flexible graphene-based microtubes (μ-GTs) have many potential applications in catalyst supports and wearable electronics. However, there is a lack of effective method to fabricate the high-performance μ-GTs, especially the multi-channel ones. In this work, the electrostatic spray deposition technique was introduced to fabricate the graphene oxide-coated polyester thread from cost-efficient graphene oxide suspensions. After the polyester thread template was removed along with the reduction of graphene oxide by thermal annealing, the multi-channel μ-GT was prepared successfully. Due to the multiple structure of the cross section and the vertically aligned reduced graphene oxide sheets of the tube wall, the multi-channel μ-GT exhibits many excellent properties, such as highly conductive, good flexibility, and functionalization. For example, the electrical conductivity of the multi-channel μ-GT thermally reduced at 1200 °C is about 1.99 × 104 S m−1 at room temperature and can light a LED as a conductive wire. And the electrical conductivity is nearly invariable in either the straight or bent state though a cyclic bending test up to 800 times. In addition, the TiO2/multi-channel μ-GT composite shows strong photocurrent response in which the multi-channel μ-GT provides a super platform due to the high specific surface area. The high-performance μ-GTs obtained by the simple method opens the immense potentials for application in wearable devices.

Notes

Acknowledgements

The authors acknowledge support from National Natural Science Foundation of China (11604173, 51673103 and 11474277), Project of Shandong Province Higher Educational Science and Technology Program (J16LJ07), Project funded by China Postdoctoral Science Foundation (2017M612195), and PT acknowledges support from the Beijing Municipal Science and Technology Commission.

Compliance with ethical standards

Conflict of interest

The authors declare no competing financial interest.

Supplementary material

10853_2019_3933_MOESM1_ESM.mpg (2.7 mb)
The video of the multi-channel μ-GT used as a conductive wire for lighting a LED1 (MPG 2796 kb)

References

  1. 1.
    Balandin AA, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F, Lau C (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8(3):902–907CrossRefGoogle Scholar
  2. 2.
    Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438(7065):197–200CrossRefGoogle Scholar
  3. 3.
    Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science 306(5696):666–669CrossRefGoogle Scholar
  4. 4.
    Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887):385–388CrossRefGoogle Scholar
  5. 5.
    Dong Z, Jiang C, Cheng H, Zhao Y, Shi G, Jiang L, Qu L (2012) Facile fabrication of light, flexible and multifunctional graphene fibers. Adv Mater 24(14):1856–1861CrossRefGoogle Scholar
  6. 6.
    Jang EY, Carretero-González J, Choi A et al (2012) Fibers of reduced graphene oxide nanoribbons. Nanotechnology 23(23):235601CrossRefGoogle Scholar
  7. 7.
    Xu Z, Gao C (2011) Graphene chiral liquid crystals and macroscopic assembled fibres. Nat Commun 2:571CrossRefGoogle Scholar
  8. 8.
    Kwak J, Chu JH, Choi JK et al (2012) Near room-temperature synthesis of transfer-free graphene films. Nat Commun 3:645CrossRefGoogle Scholar
  9. 9.
    Liang M, Wang J, Luo B, Qiu T, Zhi L (2012) High-efficiency and room-temperature reduction of graphene oxide: a facile green approach towards flexible graphene films. Small 8(8):1180–1184CrossRefGoogle Scholar
  10. 10.
    Kim F, Cote LJ, Huang J (2010) Graphene oxide: surface activity and two-dimensional assembly. Adv Mater 22(17):1954–1958CrossRefGoogle Scholar
  11. 11.
    Li X, Cai W, Jinho A et al (2009) Large-area synthesis of high-quality and uniform graphene films on copper foils. Science 324(5932):1312–1314CrossRefGoogle Scholar
  12. 12.
    Wang G, Sun X, Lu F, Sun H, Yu M, Jiang W, Liu C, Lian J (2012) Flexible pillared graphene-paper electrodes for high-performance electrochemical supercapacitors. Small 8(3):452–459CrossRefGoogle Scholar
  13. 13.
    Ye X, Zhou Q, Jia C, Tang Z, Zhu Y, Wan Z (2017) Producing large-area, foldable graphene paper from graphite oxide suspensions by in situ chemical reduction process. Carbon 114:424–434CrossRefGoogle Scholar
  14. 14.
    Li C, Shi G (2012) Three-dimensional graphene architectures. Nanoscale 4(18):5549–5563CrossRefGoogle Scholar
  15. 15.
    Xu Y, Sheng K, Li C, Shi G (2010) Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano 4(7):4324–4330CrossRefGoogle Scholar
  16. 16.
    Bi H, Yin K, Xie X et al (2012) Low temperature casting of graphene with high compressive strength. Adv Mater 24(37):5124–5129CrossRefGoogle Scholar
  17. 17.
    Zhao J, Ren W, Cheng HM (2012) Graphene sponge for efficient and repeatable adsorption and desorption of water contaminations. J Mater Chem 22(38):20197–20202CrossRefGoogle Scholar
  18. 18.
    Xu Z, Sun H, Zhao X, Gao C (2013) Ultrastrong fibers assembled from giant graphene oxide sheets. Adv Mater 25(2):188–193CrossRefGoogle Scholar
  19. 19.
    Xiang C, Young CC, Wang X et al (2013) Large flake graphene oxide fibers with unconventional 100% knot efficiency and highly aligned small flake graphene oxide fibers. Adv Mater 25(33):4592–4597CrossRefGoogle Scholar
  20. 20.
    Li J, Li J, Li L, Yu M, Ma H, Zhang B (2014) Flexible graphene fibers prepared by chemical reduction-induced self-assembly. J Mater Chem A 2(18):6359–6362CrossRefGoogle Scholar
  21. 21.
    Xin G, Yao T, Sun H et al (2015) Highly thermally conductive and mechanically strong graphene fibers. Science 349(6252):1083–1087CrossRefGoogle Scholar
  22. 22.
    Xu Z, Liu Y, Zhao X et al (2016) Ultrastiff and strong graphene fibers via full-scale synergetic defect engineering. Adv Mater 28(30):6449–6456CrossRefGoogle Scholar
  23. 23.
    Kim IH, Yun T, Kim JE et al (2018) Mussel-inspired defect engineering of graphene liquid crystalline fibers for synergistic enhancement of mechanical strength and electrical conductivity. Adv Mater 30(40):1803267CrossRefGoogle Scholar
  24. 24.
    Ma T, Gao HL, Cong HP et al (2018) A bioinspired interface design for improving the strength and electrical conductivity of graphene-based fibers. Adv Mater 30(15):1706435CrossRefGoogle Scholar
  25. 25.
    Zhang Z, Zhang P, Zhang D, Lin H, Chen Y (2018) A new strategy for the preparation of flexible macroscopic graphene fibers as supercapacitor electrodes. Mater Des 157:170–178CrossRefGoogle Scholar
  26. 26.
    Zhao Y, Jiang C, Hu C et al (2013) Large-scale spinning assembly of neat, morphology-defined, graphene-based hollow fibers. ACS Nano 7(3):2406–2412CrossRefGoogle Scholar
  27. 27.
    Chen T, Dai L (2015) Macroscopic graphene fibers directly assembled from CVD-grown fiber-shaped hollow graphene tubes. Angew Chem 127(49):15160–15163CrossRefGoogle Scholar
  28. 28.
    Yang J, Weng W, Zhang Y et al (2018) Highly flexible and shape-persistent graphene microtube and its application in supercapacitor. Carbon 126:419–425CrossRefGoogle Scholar
  29. 29.
    Hu C, Zhao Y, Cheng H et al (2012) Graphene microtubings: controlled fabrication and site-specific functionalization. Nano Lett 12(11):5879–5884CrossRefGoogle Scholar
  30. 30.
    Wang X, Qiu Y, Cao W, Hu P (2015) Highly stretchable and conductive core–sheath chemical vapor deposition graphene fibers and their applications in safe strain sensors. Chem Mater 27(20):6969–6975CrossRefGoogle Scholar
  31. 31.
    Tang H, Yang C, Lin Z, Yang Q, Kang F, Wong CP (2015) Electrospray-deposition of graphene electrodes: a simple technique to build high-performance supercapacitors. Nanoscale 7(20):9133–9139CrossRefGoogle Scholar
  32. 32.
    Beidaghi M, Wang Z, Gu L, Wang C (2012) Electrostatic spray deposition of graphene nanoplatelets for high-power thin-film supercapacitor electrodes. J Solid State Electrochem 16(10):3341–3348CrossRefGoogle Scholar
  33. 33.
    Xin G, Sun H, Hu T, Fard HR, Sun X, Koratkar N, Borca-Tasciuc T, Lian J (2014) Large-area freestanding graphene paper for superior thermal management. Adv Mater 26(26):4521–4526CrossRefGoogle Scholar
  34. 34.
    Yan J, Leng Y, Guo Y et al (2019) Highly conductive graphene paper with vertically aligned reduced graphene oxide sheets fabricated by improved electrospray deposition technique. ACS Appl Mater Interfaces 11:10810–10817CrossRefGoogle Scholar
  35. 35.
    Pei S, Cheng HM (2012) The reduction of graphene oxide. Carbon 50(9):3210–3228CrossRefGoogle Scholar
  36. 36.
    Wu JB, Lin M, Cong X, Liu HN, Tan PH (2018) Raman spectroscopy of graphene-based materials and its applications in related devices. Chem Soc Rev 47(5):1822–1873CrossRefGoogle Scholar
  37. 37.
    Díez-Betriu X, Álvarez-García S, Botas C, Álvarez P, Sánchez-Marcos J, Prieto C, Menéndez R, de Andrés A (2013) Raman spectroscopy for the study of reduction mechanisms and optimization of conductivity in graphene oxide thin films. J Mater Chem C 1(41):6905–6912CrossRefGoogle Scholar
  38. 38.
    Pei S, Zhao J, Du J, Ren W, Cheng HM (2010) Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon 48(15):4466–4474CrossRefGoogle Scholar
  39. 39.
    Shin HJ, Kim KK, Benayad A et al (2009) Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance. Adv Funct Mater 19(12):1987–1992CrossRefGoogle Scholar
  40. 40.
    Li X, Zhang G, Bai X, Sun X, Wang X, Wang E, Dai H (2008) Highly conducting graphene sheets and Langmuir–Blodgett films. Nat Nanotechnol 3(9):538–542CrossRefGoogle Scholar
  41. 41.
    Dai Y, Jing Y, Zeng J et al (2011) Nanocables composed of anatase nanofibers wrapped in uv-light reduced graphene oxide and their enhancement of photoinduced electron transfer in photoanodes. J Mater Chem 21(45):18174–18179CrossRefGoogle Scholar
  42. 42.
    Liang D, Cui C, Hu H et al (2014) One-step hydrothermal synthesis of anatase TiO2/reduced graphene oxide nanocomposites with enhanced photocatalytic activity. J Alloys Compd 582:236–240CrossRefGoogle Scholar
  43. 43.
    Zou F, Yu Y, Cao N, Wu L, Zhi J (2011) A novel approach for synthesis of TiO2–graphene nanocomposites and their photoelectrical properties. Scripta Mater 64(7):621–624CrossRefGoogle Scholar
  44. 44.
    Zhang Y, Pan C (2011) TiO2/graphene composite from thermal reaction of graphene oxide and its photocatalytic activity in visible light. J Mater Sci 46(8):2622–2626.  https://doi.org/10.1007/s10853-010-5116-x CrossRefGoogle Scholar
  45. 45.
    Park S, Lee KS, Bozoklu G, Cai W, Nguyen ST, Ruoff RS (2008) Graphene oxide papers modified by divalent ions—enhancing mechanical properties via chemical cross-linking. ACS Nano 2:572–578CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of PhysicsQingdao UniversityQingdaoChina
  2. 2.State Key Laboratory of Superlattices and Microstructures, Institute of SemiconductorsChinese Academy of SciencesBeijingChina
  3. 3.State Key Laboratory of Bio-Fibers and Eco-TextilesQingdao UniversityQingdaoChina

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