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Journal of Materials Science

, Volume 54, Issue 23, pp 14330–14342 | Cite as

Synthesis and sorption properties of porous resorcinol–formaldehyde resins prepared by polymerization of the emulsion dispersion phase

  • Eduard Anatolevich TokarEmail author
  • Marina Sergeevna Palamarchuk
  • Mikhail Viktorovich Tutov
  • Yulia Alexandrovna Azarova
  • Andrei Mikhailovich Egorin
Chemical routes to materials
  • 60 Downloads

Abstract

Resorcinol–formaldehyde resins for the removal of Cs from liquid media have been synthesized by polymerization of the emulsion dispersion phase. Chemical stability and kinetic parameters of the ion-exchange process in the porous ion exchangers have been estimated using the diffusion coefficient and the exchange half-time. The results of Cs (Cs-133 и Cs-137) removal under static and dynamic conditions are provided. The efficiency of Cs removal from the simulated solution of the evaporator concentrate (EC) containing Cu2+, Co2+, Cr3+, and Ni2+ cations has been estimated. Good prospects of application of porous ion exchangers in the function of materials for Cs removal from highly mineralized alkali media have been demonstrated.

Notes

Acknowledgements

The devices of the Center of Collective Use of Scientific Equipment ‘Far Eastern Center of Structural Investigations’ was used in the present work. The work was financially supported by the Russian Fund for Fundamental Research (RFBR) (Project No. 18-33-00458 \ 18). This work was supported by the Ministry of Education and Science of the Russian Federation, State Order No. 0265-2019-0002 of the Institute of Chemistry FEBRAS (conducting studies of sorption Cs-137, the use of radiometric equipment for the determination of the radionuclide content).

References

  1. 1.
    Hassan NM, Adu-Wusu K (2005) Cesium removal from hanford tank waste solution using resorcinol-formaldehyde resin. Solvent Extr Ion Exch 23:375–389CrossRefGoogle Scholar
  2. 2.
    Ding D, Zhang Z, Chen R, Cai T (2017) Selective removal of cesium by ammonium molybdophosphate—polyacrylonitrile bead and membrane. J Hazard Mater 324:753–761CrossRefGoogle Scholar
  3. 3.
    Russel RL, Fiskum SK, Jagoda LK, Poloski AP (2003) AP-101 Diluted Feed (Envelope A) simulant development report Richland, WA (United States)Google Scholar
  4. 4.
    Fiskum SK, Colburn HA, Rovira AM et al (2019) Cesium removal from AP-105 Hanford tank waste using spherical resorcinol formaldehyde resin. Sep Sci Technol 54:1932–1941CrossRefGoogle Scholar
  5. 5.
    Fiskum SK, Peterson RA, Colburn HA et al (2019) Small- to large-scale comparisons of cesium ion exchange performance with spherical resorcinol formaldehyde resin. Sep Sci Technol 54:1922–1931CrossRefGoogle Scholar
  6. 6.
    Hassan NM, Adu-Wusu K, Marra JC (2004) Resorcinol—formaldehyde adsorption of cesium from Hanford waste solutions, Part I. Batch equilibrium study. J Radioanal Nucl Chem 262:579–586CrossRefGoogle Scholar
  7. 7.
    Kozlov PV, Remizov MB, Makarovsky RA et al (2018) Main approaches, experience and problems of processing of accumulated local radioactive wastes of complex chemical composition in capacities. Radioaktivnyye Otkhody 4:55–66 (in Russian) Google Scholar
  8. 8.
    Pron’ IA, Kolupayev DN, Remizov MB et al (2013) Recycling highly active heterogeneous waste federal state unitary enterprise “Mayak production association” state enterprise “ROSATOM”. Bezopasnost’ yadernykh tekhnologiy i okruzhayushchey sredy 20:28–30 (in Russian) Google Scholar
  9. 9.
    Logunov MV, Karpov VI et al (2011) Approaches to the processing of highly active pults accumulated at FSUE “PO” MAYAK “. Voprosy Radiatsionnoy Bezopasnosti 1:15–28 (in Russian) Google Scholar
  10. 10.
    Ch M, SS PM, AB C et al (2015) Analysis and modeling of fixed bed sorption of cesium by AMP-PAN. J Environ Chem Eng 3:1546–1554CrossRefGoogle Scholar
  11. 11.
    Kamenik J, Dulaiova H, Sebesta F, Stastna K (2013) Fast concentration of dissolved forms of cesium radioisotopes from large seawater samples. J Radioanal Nucl Chem 296:841–846CrossRefGoogle Scholar
  12. 12.
    Zhang X, Wu Y, Chen B, Wei Y (2016) The effect of γ-ray irradiation on the adsorption properties and chemical stability of AMP/SiO2 towards Cs(I) in HNO3 solution. J Radioanal Nucl Chem 310:905–910CrossRefGoogle Scholar
  13. 13.
    Milyutin VV, Mikheev SV, Gelis VM, Kozlitin EA (2009) Sorption of cesium on ferrocyanide sorbents from highly saline solutions. Radiochemistry 51:298–300CrossRefGoogle Scholar
  14. 14.
    Zicman LR, Neacsu E, Done L et al (2017) Investigation and modeling of fixed bed cesium sorption on nickel ferrocyanide, precipitated on silica gel. Rom J Phys 62:806Google Scholar
  15. 15.
    Nilchi A, Atashi H, Javid AH, Saberi R (2007) Preparations of PAN-based adsorbers for separation of cesium and cobalt from radioactive wastes. Appl Radiat Isot 65:482–487CrossRefGoogle Scholar
  16. 16.
    Kozlov PV, Kazadaev AA, Makarovskii RA et al (2016) Development of a process for cesium recovery from the clarified phase of high-level waste storage tanks of the Mayak production association with a ferrocyanide sorbent. Radiochemistry 58:295–301CrossRefGoogle Scholar
  17. 17.
    Milyutin VV, Gelis VM, Ershov BG, Seliverstov AF (2011) Effect of complexing agents and surfactants on coprecipitation of cesium radionuclides with nickel ferrocyanide. Radiochemistry 50:67–69CrossRefGoogle Scholar
  18. 18.
    Hubler TL, Franz JA, Shaw WJ et al (1995) Synthesis, structural characterization, and performance evaluation of resorcinol-formaldehyde (R–F) ion-exchange resin. Retrieved from https://inis.iaea.org/search/search.aspx?orig_q=RN:27020108
  19. 19.
    Arm ST, Blanchard DL, Weier DR (2004) Aging effects of stored SuperLig ®644 Ion Exchange ResinGoogle Scholar
  20. 20.
    Brown GN, Russell RL, Peterson RA (2011) Small-column cesium ion exchange elution testing of spherical resorcinol-formaldehyde. Richland, WAGoogle Scholar
  21. 21.
    Arm ST, Blanchard DL (2004) Pre-conditioning and regeneration requirements of ground gel resorcinol formaldehyde ion exchange resin. Richland, WAGoogle Scholar
  22. 22.
    Kozlov PV, Remizov MB, Logunov MV et al (2017) Sorption extraction of cesium from model alkaline hlw on resorcin-formaldehyde resins of domestic production. Voprosy radiatsionnoy bezopasnosti 80:34–41 (in Russian) Google Scholar
  23. 23.
    Brown GN (2014) Literature review of spherical resorcinol-formaldehyde for cesium ion exchange. Richland, WAGoogle Scholar
  24. 24.
    El-Gammal B, Ibrahim GM, El-Naggar IM (2014) Preparation of some resorcinol formaldehyde resins for the separation of 134CS from acidic waste streams. Desalin Water Treat 52:4721–4733CrossRefGoogle Scholar
  25. 25.
    Liu M, Gan L, Zhao F et al (2007) Carbon foams prepared by an oil-in-water emulsion method. Carbon N Y 45:2710–2712CrossRefGoogle Scholar
  26. 26.
    Gross AF, Nowak AP (2010) Hierarchical carbon foams with independently tunable mesopore and macropore size distributions. Langmuir 26:11378–11383CrossRefGoogle Scholar
  27. 27.
    Boyd GE, Adamson AW, Myers LS (1947) The exchange adsorption of ions from aqueous solutions by organic zeolites. II. Kinetics. J Am Chem Soc 69:2836–2848CrossRefGoogle Scholar
  28. 28.
    Reichenberg D (1953) Properties of ion-exchange resins in relation to their structure. III. Kinetics of exchange. J Am Chem Soc 75:589–597CrossRefGoogle Scholar
  29. 29.
    Doǧan M, Özdemir Y, Alkan M (2007) Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite. Dye Pigment 75:701–713CrossRefGoogle Scholar
  30. 30.
    Giles CH, Smith D, Huitson A (1974) A general treatment and classification of the solute adsorption isotherm. I. Theoretical. J Colloid Interface Sci 47:755–765CrossRefGoogle Scholar
  31. 31.
    Egorin AM, Tutov MV, Didenko NA et al (2015) Effect of parameters of thermal treatment of resorcinol–formaldehyde resins on their chemical stability and 137Cs uptake efficiency. J Radioanal Nucl Chem 304:281–286CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Institute of Chemistry, Far Eastern Branch, Russian Academy of SciencesVladivostokRussia
  2. 2.Far Eastern Federal UniversityVladivostokRussia

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