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Journal of Materials Science

, Volume 54, Issue 18, pp 11991–11999 | Cite as

Preparation of (Vx, Ti1−x)2C MXenes and their performance as anode materials for LIBs

  • Ying Wang
  • Wei Zheng
  • Peigen ZhangEmail author
  • Wubian Tian
  • Jian Chen
  • ZhengMing SunEmail author
Energy materials
  • 67 Downloads

Abstract

MXenes as anode materials for Li-ion batteries (LIBs) have shown excellent electrochemical performance, and they still have great potential. To explore the effect of chemical composition on their electrochemical performance, herein we report an approach for preparation of (Vx, Ti1−x)2C MXenes (x = 1, 0.7, 0.5, 0.3, 0) via etching their precursor solid solutions of (Vx, Ti1−x)2AlC. The exfoliated (Vx, Ti1−x)2C MXenes with good multilayered morphology exhibit good electrochemical properties when used as anodes of LIBs, and the electrochemical performance is optimized for the solid solution of (V0.5, Ti0.5)2C which possesses the highest reversible capacity of 204.9 mAh g−1 and a coulombic efficiency of nearly 100% at 1 A g−1. The heteroatoms in M site of MXene are responsible for the enhanced lithium storage performance.

Notes

Acknowledgements

This work was supported by the Grants of National Natural Science Foundation of China (51731004 and 51671054) and Zhishan Youth Scholar Program of SEU.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and EngineeringSoutheast UniversityNanjingChina

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