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Journal of Materials Science

, Volume 54, Issue 19, pp 12747–12757 | Cite as

A facile synthesis of nitrogen-doped hierarchical porous carbon with hollow sphere structure for high-performance supercapacitors

  • Yunpeng Shang
  • Xudong Hu
  • Xin Li
  • Shu Cai
  • Guangchuan Liang
  • Junmei Zhao
  • Chunming ZhengEmail author
  • Xiaohong SunEmail author
Energy materials
  • 12 Downloads

Abstract

In this work, nitrogen-doped carbon with hierarchical porous and hollow sphere structure has been synthesized through a simple and facile route of spray drying using glycine as the nitrogen-containing carbon source. After KOH activation, the prepared material (NHPCA) shows a large specific surface area of 962 m2 g−1 with moderate N-doping of 5.74% and exhibits a high specific capacitance of 271 F g−1 in 6 M KOH electrolyte at 1.0 A g−1, remarkable rate capability and particularly stable cycling performance with no significant specific capacitance drop after 10000 cycles at 1.0 A g−1. The excellent electrochemical properties come from the unique structure and the doping of nitrogen. The hierarchical pore structure improves the efficiency of electrolyte ions transport, and diffusion and the hollow sphere structure further facilitates mass transport. The doping of nitrogen increases the total capacitance by providing redox pseudo-capacitance. The results indicate the as-prepared nitrogen-doped carbon with hierarchical porous and hollow sphere structure can be used as a hopeful candidate for an efficient electrode of commercial supercapacitors devices.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China, NSFC (51772205, 51572192, 51772208, 51472179), and the General Program of Municipal Natural Science Foundation of Tianjin (17JCYBJC17000, 17JCYBJC22700).

Compliance with ethical standards

Conflict of interest

All authors listed have declared that they have no conflict of interest.

Supplementary material

10853_2019_3744_MOESM1_ESM.docx (533 kb)
Supplementary material 1 (DOCX 532 kb)

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Authors and Affiliations

  1. 1.School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin UniversityTianjinPeople’s Republic of China
  2. 2.State Key Laboratory of Hollow-Fiber Membrane Materials and Membrane Processes, School of Environmental and Chemical EngineeringTianjin Polytechnic UniversityTianjinPeople’s Republic of China
  3. 3.Department of Chemistry and BiochemistryUniversity of California, Santa BarbaraSanta BarbaraUSA
  4. 4.Institute of Power Source and Ecomaterials ScienceHebei University of TechnologyTianjinPeople’s Republic of China
  5. 5.CAS Key Laboratory of Green Process and Engineering, Institute of Process EngineeringChinese Academy of SciencesBeijingPeople’s Republic of China

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