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Study on selective oxidations of gold nanorod and mesoporous silica-coated gold nanorod

  • Zihua WuEmail author
  • Yuling Liang
  • Qing Guo
  • Keqiu Zhang
  • Shifang Liang
  • Liyun Yang
  • Qi Xiao
  • Dan WangEmail author
Chemical routes to materials

Abstract

The structural control-based manipulation of the anisotropic surface plasmon resonance (SPR) property of gold nanorod (AuNR) is significant and has wide application value in many fields. In this work, the quantitative studies of the ends-selective oxidations of AuNR and silica-coated AuNR using chloroauric acid as a oxidant were carried out. Results show that when the selective oxidation extent of AuNR was denoted by the aspect ratio changing rate, a linear relationship was displayed between this rate and the added amount of the oxidant, which suggested the Au(III)-induced selective oxidation of the nanoscaled Au(0) also proceeded stoichiometrically. In addition, different structural evolutions of silica coating layer that were determined to be caused by the different stabilities of the silica structure and described as the shape-adaptive change and the rigid state were found upon proceeding of oxidation. The study also showed that the structural change of the silica coating layer only had little influences on the mesopore size and its distribution state. These results should be valuable in better understanding the surface chemistry of AuNR and benefit the SPR variation-based and the silica coating-involved applications of AuNR.

Notes

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (21573078) and BAGUI Scholar Program of Guangxi Province of China.

Author contributions

The manuscript was written through contributions of all authors. All authors have given approval to the final version of the manuscript.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

10853_2019_3429_MOESM1_ESM.pdf (327 kb)
The Supplementary material is available free of charge on the Springer Publications website at DOI: Data from characterization analysis, UV–Vis–NIR characterization, FT-IR characterization (PDF) (PDF 327 kb)

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of Chemistry and MaterialsNanning Normal UniversityNanningPeople’s Republic of China
  2. 2.Guangxi Key Laboratory of Natural Polymer Chemistry and PhysicsNanning Normal UniversityNanningPeople’s Republic of China

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