Journal of Materials Science

, Volume 54, Issue 8, pp 6651–6667 | Cite as

The shock-induced chemical reaction behaviour of Al/Ni composites by cold rolling and powder compaction

  • Wei Xiong
  • Xianfeng ZhangEmail author
  • Li Zheng
  • Kuo Bao
  • Haihua Chen
  • Zhongwei Guan


Al/Ni composites are typical structural energetic materials, which have dual functions of structural and energetic characteristics. In order to investigate the influence of manufacturing methods on shock-induced chemical reaction (SICR) behaviour of Al/Ni composites, Al/Ni multi-layered composites with 3–5 cold-rolling passes and Al/Ni powder composites were obtained. Microstructural observation using scanning electron microscopy (SEM) and two-step impact initiation experiments were performed on the four Al/Ni composites. Furthermore, mesoscale simulations, through importing SEM images into the finite element analysis to reflect the real microstructures of the composites, were performed to analyse the particle deformation and temperature rise under shock compression conditions. The experimental results showed the distinct differences on the SICR characteristics among the four Al/Ni composites (i.e. by 3, 4 and 5 cold-rolling passes and powder compaction). The manufacturing methods provided the control of the particle sizes, particle distribution and the content of the interfacial intermetallics at scale of different microstructures, which ultimately affected the temperature distribution, as well as the contact between Al and Ni in Al/Ni composites under shock loading. As a result, the Al/Ni powder composites showed the highest energy release capacity among the four composites, while the energy release capability of Al/Ni multi-layered composites decreased with the growth of rolling passes.



This research is supported by the National Program for Support of Top-notch Young Professionals of China, the Fundamental Research Funds for the Central Universities (No. 30916011305) and China Scholarship Council. The authors would also like to thank Mr. Jiajie Deng, Mr. Fei Gao, Mr. Chuang Liu, Mr. Chenyang Xu, Mr. Wenjie Wang, Miss Mengting Tan and Miss Xue Wu for their great support on the current experimental work.


  1. 1.
    Song I, Thadhani NN (1992) Shock-induced chemical reactions and synthesis of nickel aluminides. Metall Mater Trans A 23(1):41–48. CrossRefGoogle Scholar
  2. 2.
    Kuk SW, Ryu HJ, Yu J (2014) Effects of the Al/Ni ratio on the reactions in the compression-bonded Ni-sputtered Al foil multilayer. J Alloys Compd 589:455–461. CrossRefGoogle Scholar
  3. 3.
    Baker EL, Daniels AS, Ng KW, Martin VO, Orosz JP (2001) Barnie: a unitary demolition warhead. Paper presented at the 19th International Symposium on Ballistics Interlaken, SwitzerlandGoogle Scholar
  4. 4.
    Nielson DB, Ashcroft BN, Doll DW (2013) Reactive material compositions and projectiles containing same.. U.S. patent 8,568,541Google Scholar
  5. 5.
    Hugus GD, Sheridan EW, Brooks GW (2012) Structural metallic binders for reactive fragmentation weapons. U.S. patent 8,250,985Google Scholar
  6. 6.
    Reeves RV, Mukasyan AS, Son SF (2010) Thermal and impact reaction initiation in Ni/Al heterogeneous reactive systems. J Phys Chem C 114(35):14772–14780CrossRefGoogle Scholar
  7. 7.
    Herbold EB, Thadhani NN, Jordan JL (2011) Observation of a minimum reaction initiation threshold in ball-milled Ni + Al under high-rate mechanical loading. J Appl Phys 109(6):066108CrossRefGoogle Scholar
  8. 8.
    Qiao L, Zhang XF, He Y, Zhao XN, Guan ZW (2013) Multiscale modelling on the shock-induced chemical reactions of multifunctional energetic structural materials. J Appl Phys 113(17):173513. CrossRefGoogle Scholar
  9. 9.
    Eakins DE, Thadhani NN (2008) Mesoscale simulation of the configuration-dependent shock-compression response of Ni + Al powder mixtures. Acta Mater 56(7):1496–1510CrossRefGoogle Scholar
  10. 10.
    Cherukara MJ, Germann TC, Kober EM, Strachan A (2016) Shock loading of granular Ni/Al composites. Part 2: shock-induced chemistry. J Phys Chem C 120(12):6804–6813CrossRefGoogle Scholar
  11. 11.
    Cherukara MJ, Germann TC, Kober EM, Strachan A (2014) Shock loading of granular Ni/Al composites. Part 1: mechanics of loading. J Phys Chem C 118(45):26377–26386. CrossRefGoogle Scholar
  12. 12.
    Martin M (2005) Processing and characterization of energetic and structural behavior of nickel aluminum with polymer binders. Master dissertation, Georgia Institute of TechnologyGoogle Scholar
  13. 13.
    Zhang XF, Shi AS, Qiao L, Zhang J, Zhang YG, Guan ZW (2013) Experimental study on impact-initiated characters of multifunctional energetic structural materials. J Appl Phys 113(8):083508. CrossRefGoogle Scholar
  14. 14.
    Wei CT, Vitali E, Jiang F, Du SW, Benson DJ, Vecchio KS, Thadhani NN, Meyers MA (2012) Quasi-static and dynamic response of explosively consolidated metal–aluminum powder mixtures. Acta Mater 60(3):1418–1432. CrossRefGoogle Scholar
  15. 15.
    Aydelotte BB, Thadhani NN (2013) Mechanistic aspects of impact initiated reactions in explosively consolidated metal + aluminum powder mixtures. Mater Sci Eng, A 570:164–171. CrossRefGoogle Scholar
  16. 16.
    Kelly SC, Thadhani NN (2016) Shock compression response of highly reactive Ni + Al multilayered thin foils. J Appl Phys 119(9):095903. CrossRefGoogle Scholar
  17. 17.
    Knepper R, Snyder MR, Fritz G, Fisher K, Knio OM, Weihs TP (2009) Effect of varying bilayer spacing distribution on reaction heat and velocity in reactive Al/Ni multilayers. J Appl Phys 105(8):083504. CrossRefGoogle Scholar
  18. 18.
    Specht PE, Thadhani NN, Weihs TP (2012) Configurational effects on shock wave propagation in Ni–Al multilayer composites. J Appl Phys 111(7):073527. CrossRefGoogle Scholar
  19. 19.
    Specht PE, Weihs TP, Thadhani NN (2016) Interfacial effects on the dispersion and dissipation of shock waves in Ni/Al multilayer composites. J Dyn Behav Mater 2(4):500–510. CrossRefGoogle Scholar
  20. 20.
    Gavens AJ, Van Heerden D, Mann AB, Reiss ME, Weihs TP (2000) Effect of intermixing on self-propagating exothermic reactions in Al/Ni nanolaminate foils. J Appl Phys 87(3):1255–1263. CrossRefGoogle Scholar
  21. 21.
    Ma E, Thompson CV, Clevenger LA, Tu KN (1990) Self-propagating explosive reactions in Al/Ni multilayer thin films. Appl Phys Lett 57(12):1262–1264. CrossRefGoogle Scholar
  22. 22.
    Kuk SW, Yu J, Ryu HJ (2015) Effects of interfacial Al oxide layers: control of reaction behavior in micrometer-scale Al/Ni multilayers. Mater Design 84:372–377. CrossRefGoogle Scholar
  23. 23.
    Ji C, He Y, Wang CT, He Y, Pan X, Jiao J, Guo L (2017) Investigation on shock-induced reaction characteristics of an Al/Ni composite processed via accumulative roll-bonding. Mater Design 116:591–598CrossRefGoogle Scholar
  24. 24.
    Dunbar E, Thadhani NN (1993) High-pressure shock activation and mixing of nickel–aluminum powder mixtures. J Mater Sci 28:2903–2914. CrossRefGoogle Scholar
  25. 25.
    Thiers L, Mukasyan AS, Varma A (2002) Thermal explosion in Ni–Al system: influence of reaction medium microstructure. Combust Flame 131(1):198–209. CrossRefGoogle Scholar
  26. 26.
    Xiong W, Zhang X, Tan M, Liu C, Wu X (2016) The energy release characteristics of shock-induced chemical reaction of Al/Ni composites. J Phys Chem C 120(43):24551–24559. CrossRefGoogle Scholar
  27. 27.
    Johnson GR, Cook WH (1983) A constitutive model and data for metals subjected to large strains, high strain rates and high temperatures. In: Proceedings of the 7th international symposium on ballistics. The Hague, pp 541–547Google Scholar
  28. 28.
    Lemons DS, Lund CM (1999) Thermodynamics of high temperature, Mie–Gruneisen solids. Am J Phys 67(12):1105–1108. CrossRefGoogle Scholar
  29. 29.
    Meyers MA (1994) Dynamic behavior of materials. Wiley, New YorkCrossRefGoogle Scholar
  30. 30.
    Tang W, Zhang R (2008) Introduction to theory and computation of equation of state. Higher Education Press, BeijingGoogle Scholar
  31. 31.
    Vitali E, Wei CT, Benson DJ, Meyers MA (2011) Effects of geometry and intermetallic bonding on the mechanical response, spalling and fragmentation of Ni–Al laminates. Acta Mater 59(15):5869–5880. CrossRefGoogle Scholar
  32. 32.
    Peyre P, Chaieb I, Braham C (2007) FEM calculation of residual stresses induced by laser shock processing in stainless steels. Model Simul Mater Sci 15(3):205–221. CrossRefGoogle Scholar
  33. 33.
    Reding DJ (2010) Multiscale chemical reactions in reactive powder metal mixtures during shock compression. J Appl Phys 108:024905. CrossRefGoogle Scholar
  34. 34.
    Ames RG (2005) Vented chamber calorimetry for impact-initiated energetic materials. Paper presented at the 43rd AIAA Aerospace Sciences Meeting and Exhibit, Reno, NevadaGoogle Scholar
  35. 35.
    Lynch DD, Kunkel RW, Juarascio SS (1997) An analysis comparison using the vulnerability analysis for surface targets (VAST) computer code and the computation of vulnerable area and repair time (COVART III) computer code. Army Research Lab, AdelphiGoogle Scholar
  36. 36.
    Xiong W, Zhang XF, Wu Y, He Y, Wang CT, Guo L (2015) Influence of additives on microstructures, mechanical properties and shock-induced reaction characteristics of Al/Ni composites. J Alloys Compd 648:540–549. CrossRefGoogle Scholar
  37. 37.
    Boslough MB (1990) A thermochemical model for shock-induced reactions (heat detonations) in solids. J Chem Phys 92(3):1839–1848. CrossRefGoogle Scholar
  38. 38.
    White JDE, Reeves RV, Son SF, Mukasyan AS (2009) Thermal explosion in Al–Ni system influence of mechanical activation. J Phys Chem A 113:13541–13547CrossRefGoogle Scholar

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Authors and Affiliations

  1. 1.School of Mechanical EngineeringNanjing University of Science and TechnologyNanjingChina
  2. 2.School of Material Science and EngineeringShenyang University of TechnologyShenyangChina
  3. 3.School of EngineeringUniversity of LiverpoolLiverpoolUK

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