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Ultralight and compressible mussel-inspired dopamine-conjugated poly(aspartic acid)/Fe3+-multifunctionalized graphene aerogel

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Abstract

The reduced graphene oxide (rGO) aerogels are particularly attractive owing to their ultralight-weight, high surface area and interconnected macroporosity for energy storage applications. However, pure rGO aerogels are generally weak and brittle to limit their practical applications. To overcome this drawback, a small amount of synthetic dopamine-conjugated poly(aspartic acid) was mixed with graphene oxide to fabricate ultralight rGO aerogels with high porosity and mechanical integrity via hydrothermal reactions at 80 °C and freeze-drying process. In addition, the Fe3+ ionic species was chosen for an additional cross-linker to further strengthen the ultralight poly(aspartic acid/dopamine) functionalized rGO aerogel, abbreviation for PAAD/rGO, through the coordination bonding between Fe3+ and carboxylic acid or catechol groups of both polymer and rGO sheets at pH 9 (PAAD/rGO-Fe❾). The hybrid electrodes of PAAD/rGO-Fe❾ showed the reversible transformation of the Fe3+ tris-catecholate complexes into mono-catecholate promoting Quinone (Q)-hydroquinone (QH2) in 1.0 mol L−1 H2SO4 electrolyte, thus delivering a high specific capacitance of 276.4 F g−1 at 0.5 A g−1 and capacitance retention of 88.2% after 5000 cycles. Moreover, this compressible aerogel provided high strength with 150 kPa without noticeable structural fracture after 80% compression and repeated deformation processes suggesting applications in energy storage and absorption.

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References

  1. 1

    Huang H, Chen P, Zhang X, Lu Y, Zhan W (2013) Edge-to-edge assembled graphene oxide aerogels with outstanding mechanical performance and superhigh chemical activity. Small 9(8):1397–1404

  2. 2

    Qian Y, Ismail IM, Stein A (2014) Ultralight, high-surface-area, multifunctional graphene-based aerogels from self-assembly of graphene oxide and resol. Carbon 68:221–231

  3. 3

    Zhang X, Sui Z, Xu B, Yue S, Luo Y, Zhan W, Liu B (2010) Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources. J Mater Chem 21(18):6494–6497

  4. 4

    Zhao Y, Hu C, Hu Y, Cheng H, Shi G, Qu L (2012) A versatile, ultralight, nitrogen-doped graphene framework. Angew Chem 124(45):11533–11537

  5. 5

    Worsley MA, Pauzauskie PJ, Olson TY, Biener J, Satcher JH Jr, Baumann TF (2010) Synthesis of graphene aerogel with high electrical conductivity. J Am Chem Soc 132:14067–14069

  6. 6

    Ye S, Feng J, Wu P (2013) Highly elastic graphene oxide-epoxy composite aerogels via simple freeze-drying and subsequent routine curing. J Mater Chem A 1(10):3495–3502

  7. 7

    Sun H, Xu Z, Gao C (2013) Multifunctional, ultra-flyweight, synergistically assembled carbon aerogels. Adv Mater 25(18):2554–2560

  8. 8

    Huang X, Chen J, Yu H, Cai R, Peng S, Yan Q, Hng HH (2013) Carbon buffered-transition metal oxide nanoparticle-graphene hybrid nanosheets as high-performance anode materials for lithium ion batteries. J Mater Chem A 1(23):6901–6907

  9. 9

    Yu X, Kim HJ, Hong JY, Jung YM, Kwon KD, Kong J, Park HS (2015) Elucidating surface redox charge storage of phosphorus-incorporated graphenes with hierarchical architectures. Nano Energy 15:576–586

  10. 10

    Yeon SH, Yoon H, Lee SH, Kim JE, Lim S, Shin KH, Park HS, Jin CS, Ahn W, Cheong HW, Choi Y, Yu HR (2015) Enhanced anode performance of micro/meso-porous reduced graphene oxide prepared from carbide-derived carbon for energy storage devices. Carbon 91:241–251

  11. 11

    Zhang L, Xia Z (2011) Mechanisms of oxygen reduction reaction on nitrogen-doped graphene for fuel cells. J Phys Chem C 115(22):11170–11176

  12. 12

    Shao Y, Wang J, Wu H, Liu J, Aksay IA, Lin Y (2010) Graphene based electrochemical sensors and biosensors: a Review. Electroanalysis 22(10):1027–1036

  13. 13

    Kang Y, Yu X, Kota M, Park HS (2017) Carbon nanotubes branched on three-dimensional, nitrogen-incorporated reduced graphene oxide/iron oxide hybrid architectures for lithium ion battery anode. J Alloys Compd 726:88–94

  14. 14

    Huang Y, Liang J, Chen Y (2012) An overview of the applications of graphene-based materials in supercapacitors. Small 8(12):1805–1834

  15. 15

    Zhang XY, Sun SH, Sun XJ, Zhao YR, Chen L, Yang Y, Li DB (2016) Plasma-induced, nitrogen-doped graphene-based aerogels for high-performance supercapacitors. Light Sci Appl 5(10):e16130-1–e16130-7

  16. 16

    Ha H, Shanmuganathan K, Ellison CJ (2015) Mechanically stable thermally crosslinked poly (acrylic acid)/reduced graphene oxide aerogels. ACS Appl Mater Interfaces 7(11):6220–6229

  17. 17

    Hu H, Zhao Z, Wan W, Gogotsi Y, Qiu J (2013) Ultralight and highly compressible graphene aerogels. Adv Mater 25(15):2219–2223

  18. 18

    Li L, Li B, Zhang J (2016) Dopamine-mediated fabrication of ultralight graphene aerogels with low volume shrinkage. J Mater Chem A 4(2):512–518

  19. 19

    Gao H, Sun Y, Zhou J, Xu R, Duan H (2013) Mussel-inspired synthesis of polydopamine-functionalized graphene hydrogel as reusable adsorbents for water purification. ACS Appl Mater Interfaces 5(2):425–432

  20. 20

    Chen L, Li Y, Du Q, Wang Z, Xia Y, Yedinak E, Ci L (2017) High performance agar/graphene oxide composite aerogel for methylene blue removal. Carbohydr Polym 155:345–353

  21. 21

    Hong JY, Yun S, Wie JJ, Zhang X, Dresselhaus MS, Kong J, Park HS (2016) Cartilage-inspired superelastic ultradurable graphene aerogels prepared by the selective gluing of intersheet joints. Nanoscale 8(26):12900–12909

  22. 22

    Hong JY, Bak BM, Wie JJ, Kong J, Park HS (2015) Reversibly compressible, highly elastic, and durable graphene aerogels for energy storage devices under limiting conditions. Adv Funct Mater 25(7):1053–1062

  23. 23

    Kim SK, Cho J, Moore JS, Park HS, Braun PV (2016) High-performance mesostructured organic hybrid pseudocapacitor electrodes. Adv Funct Mater 26(6):903–910

  24. 24

    Wilson E, Islam MF (2015) Ultracompressible, high-rate supercapacitors from graphene-coated carbon nanotube aerogels. ACS Appl Mater Interfaces 7(9):5612–5618

  25. 25

    Wu XL, Xu AW (2014) Carbonaceous hydrogels and aerogels for supercapacitors. J Mater Chem A 2(14):4852–4864

  26. 26

    Wu ZS, Yang S, Sun Y, Parvez K, Feng X, Müllen K (2012) 3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction. J Am Chem Soc 134(22):9082–9085

  27. 27

    Choi J, Yang M, Kim SK (2017) Pseudocapacitive organic catechol derivative-functionalized three-dimensional graphene aerogel hybrid electrodes for high-performance supercapacitors. Appl Surf Sci 422:316–320

  28. 28

    Kim SK, Kim YK, Lee H, Lee SB, Park HS (2014) Superior pseudocapacitive behavior of confined lignin nanocrystals for renewable energy-storage materials. Chemsuschem 7(4):1094–1101

  29. 29

    Roldán S, Blanco C, Granda M, Menéndez R, Santamaría R (2011) Towards a further generation of high-energy carbon-based capacitors by using redox-active electrolytes. Angew Chem Int Ed 50(7):1699–1701

  30. 30

    Yoshimura T, Ochi Y, Fujioka R (2005) Synthesis and properties of hydrogels based on polyaspartamides with various pendants. Polym Bull 55(5):377–383

  31. 31

    Nakato T, Yoshitake M, Matsubara K, Tomida M, Kakuchi T (1998) Relationships between structure and properties of poly (aspartic acid)s. Macromolecules 31(7):2107–2113

  32. 32

    Umeda S, Nakade H, Kakuchi T (2011) Preparation of superabsorbent hydrogels from poly(aspartic acid) by chemical crosslinking. Polym Bull 67(7):1285–1292

  33. 33

    Wang B, Jeon YS, Park HS, Kim YJ, Kim JH (2015) Mussel-mimetic self-healing polyaspartamide derivative gel via boron-catechol interactions. Express Polym Lett 9:799–808

  34. 34

    Bae IH, Park IK, Park DS, Lee H, Jeong MH (2012) Thromboresistant and endothelialization effects of dopamine-mediated heparin coating on a stent material surface. J Mater Sci Mater Med 23(5):1259–1269

  35. 35

    Xu Z (2013) Mechanics of metal-catecholate complexes: the roles of coordination state and metal types. Sci Rep 3:2914-1–2914-7

  36. 36

    Shen TZ, Hong SH, Song JK (2014) Electro-optical switching of graphene oxide liquid crystals with an extremely large Kerr coefficient. Nat Mater 13(4):394–399

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Acknowledgement

This work was supported by the Basic Science Research Program through the National Research Foundation (NRF) of Korea, funded by the Ministry of Education, Science and Technology (NRF-2016R1D1A1A09918727).

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Correspondence to Ho Seok Park or Ji-Heung Kim.

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Wang, B., Kang, Y., Shen, T. et al. Ultralight and compressible mussel-inspired dopamine-conjugated poly(aspartic acid)/Fe3+-multifunctionalized graphene aerogel. J Mater Sci 53, 16484–16499 (2018). https://doi.org/10.1007/s10853-018-2777-3

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