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Journal of Materials Science

, Volume 54, Issue 8, pp 6332–6346 | Cite as

Investigation on the optimization, design and microwave absorption properties of BaTb0.2Eu0.2Fe11.6O19/PANI decorated on reduced graphene oxide nanocomposites

  • Juhua LuoEmail author
  • Lu Yue
  • Hongru Ji
  • Kang Zhang
  • Ning Yu
Electronic materials
  • 66 Downloads

Abstract

A novel hybrid material with excellent microwave absorption property has been designed by decorating reduced graphene oxide with Ba Tb0.2Eu0.2Fe11.6O19/PANI composite, and the effect of graphene content on microwave absorption property has been investigated. The microstructure of the composite is characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, field emission scanning electron microscope, transmission electron microscope and Raman spectroscopy. The mechanism of microwave absorption is discussed minutely. The result shows that the ternary nanocomposites demonstrate unexceptionable microwave absorption property due to its special nanostructures and synergistic effect among BaTb0.2Eu0.2Fe11.6O19, PANI and RGO. The minimum reflection loss can reach − 60.9 dB at 16.4 GHz with a thickness of only 1.95 mm, and the corresponding effective absorption bandwidth (below − 10 dB) is 4.2 GHz. BaTb0.2Eu0.2Fe11.6O19/PANI/RGO composite can be one of the most promising microwave absorption materials.

Notes

Acknowledgements

This work was supported by the Flagship Major Development of Jiangsu Higher Education Institutions (Grant No. PPZY2015A025) and Jiangsu Provincial Department of Education (Grant No. 18KJA430016) and Joint Open Fund of Jiangsu Collaborative Innovation Center for Ecological Building Material and Environmental Protection Equipments and Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province and Key Laboratory for Ecological-Environment Materials of Jiangsu Province (Grant No. JH201826).

References

  1. 1.
    Ding D, Wang Y, Li XD, Qiang R, Xu P, Chu WL, Han XJ, Du YC (2017) Rational design of core–shell Co@C microspheres for high-performance microwave absorption. Carbon 111:722–732CrossRefGoogle Scholar
  2. 2.
    Verma M, Singh AP, Sambyal P, Singh BP, Dhawan SK, Choudhary V (2015) Barium ferrite decorated reduced graphene oxide composite for effective electromagnetic interference shielding. Phys Chem Chem Phys 17:1610–1618CrossRefGoogle Scholar
  3. 3.
    Liu PJ, Ng VMH, Yao ZJ, Zhou JT, Lei YM, Yang ZH, Kong LB (2017) Microwave absorption properties of double-layer absorbers based on Co0.2Ni0.4Zn0.4Fe2O4 ferrite and reduced graphene oxide composites. J Alloys Compd 701:841–849CrossRefGoogle Scholar
  4. 4.
    Xu HB, Bie SW, Xu YS, Yuan W, Chen Q, Jiang JJ (2016) Broad bandwidth of thin composite radar absorbing structures embedded with frequency selective surfaces. Compos Part A Appl Sci Manuf 80:111–117CrossRefGoogle Scholar
  5. 5.
    Kim ST, Kim SS (2016) Microwave absorbance of Ni–Fe thin films on hollow ceramic microspheres dispersed in a rubber matrix. J Alloys Compd 687:22–27CrossRefGoogle Scholar
  6. 6.
    Wang Y, Huang Y, Wang QF (2012) Preparation and magnetic properties of BaFe12O19/Ni0.8Zn0.2Fe2O4 composite ferrite. J Magn Magn Mater 324:3024–3028CrossRefGoogle Scholar
  7. 7.
    Li YQ, Huang Y, Qi SH, Niu FF, Niu L (2011) Preparation, and magnetic and electromagnetic properties of La-doped strontium ferrite films. J Magn Magn Mater 323:2224–2232CrossRefGoogle Scholar
  8. 8.
    Sun C, Sun KN, Chui PF (2012) Microwave absorption properties of Ce-substituted M-type barium ferrite. J Magn Magn Mater 324:802–805CrossRefGoogle Scholar
  9. 9.
    Zhang ZY, Liu XX, Wang XJ, Wu YP, Li R (2012) Effect of Nd–Co substitution on magnetic and microwave absorption properties of SrFe12O19 hexaferrites. J Alloys Compd 525:114–119CrossRefGoogle Scholar
  10. 10.
    Xie Y, Hong XW, Gao YH, Li MJ, Liu JM, Wang J, Lu J (2012) Synthesis and characterization of La/Nd-doped barium-ferrite/polypyrrole nanocomposites. Synth Metals 162:677–681CrossRefGoogle Scholar
  11. 11.
    Li J, He S, Shi KZ, Wu Y, Bai H, Hong Y, Wu WJ, Meng QX, Jia DC, Zhou ZX (2018) Coexistence of broad-bandwidth and strong microwave absorption in Co2+–Zr4+ co-doped barium ferrite ceramics. Ceram Int 44:6953–6958CrossRefGoogle Scholar
  12. 12.
    Cheng YK, Ren XH (2016) Enhanced microwave absorbing properties of La3+ substituting barium hexaferrite. J Supercond Nov Magn 29:803–808CrossRefGoogle Scholar
  13. 13.
    Cao MS, Yang J, Song WL, Zhang DQ, Wen B, Jin HB, Hou ZL, Yuan J (2012) Ferroferric oxide/multiwalled carbon nanotube vs polyaniline/ferroferric oxide/multiwalled carbon nanotube multihetero-structures for highly effective microwave absorption. ACS Appl Mater Interfaces 4:6948–6955Google Scholar
  14. 14.
    Singh K, Ohlan A, Pham VH, Varshney BRS, Jang J, Hur SH, Choi WM, Kumar M, Dhawan SK, Kong BS, Chung JS (2013) Nanostructured graphene/Fe3O4 incorporated polyaniline as a high performance shield against electromagnetic pollution. Nanoscale 5:2411–2420CrossRefGoogle Scholar
  15. 15.
    Liu JL, Zhang J, Li YQ, Zhang M (2015) Microwave absorbing properties of barium hexa-ferrite/polyaniline core–shell nanocomposites with controlled shell thickness. Mater Chem Phys 163:470–477CrossRefGoogle Scholar
  16. 16.
    Feng WJ, Zhao X, Zheng WQ, Gang JT, Cao Y, Yang H (2017) Microwave absorption properties of BaFe12O19 prepared in different temperature with polyaniline nanocomposites. Adv Mater Res 1142:211–215CrossRefGoogle Scholar
  17. 17.
    Luo JH, Shen P, Yao W, Jiang CF, Xu JG (2016) Synthesis, characterization, and microwave absorption properties of reduced graphene oxide/strontium ferrite/polyaniline nanocomposites. Nanoscale Res Lett 11:141CrossRefGoogle Scholar
  18. 18.
    Lv HL, Guo YH, Yang ZH, Cheng Y, Wang LY, Zhang BS, Zhao Y, Xu ZCJ, Ji GB (2016) A brief introduction to the fabrication and synthesis of graphene based composites for the realization of electromagnetic absorbing materials. J Mater Chem C 5:491–512CrossRefGoogle Scholar
  19. 19.
    Cao MS, Chen H, Wang XX, Zhang M, Zhang YL, Shu JC, Yang HJ, Fang XY, Yuan J (2018) Graphene nanohybrids: excellent electromagnetic properties for the absorbing and shielding of electromagnetic waves. J Mater Chem C 6:4586–4602CrossRefGoogle Scholar
  20. 20.
    Lai YR, Wang SY, Qian DL, Zhong ST, Wang YP, Han SJ, Jiang W (2017) Tunable electromagnetic wave absorption properties of nickel microspheres decorated reduced graphene oxide. Ceram Int 43:12904–12914CrossRefGoogle Scholar
  21. 21.
    Ma J, Wang XX, Cao WQ, Han C, Yang HJ, Yuan J, Cao MS (2018) A facile fabrication and highly tunable microwave absorption of 3D flowerlike Co3O4–rGO hybrid-architectures. Chem Eng J 339:487–498CrossRefGoogle Scholar
  22. 22.
    Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRefGoogle Scholar
  23. 23.
    Bhattacharya P, Dhibar S, Hatui G, Mandal A, Das T, Das CK (2014) Graphene decorated with hexagonal shaped M-type ferrite and polyaniline wrapper: a potential candidate for electromagnetic wave absorbing and energy storage device applications. RSC Adv 4:17039–17053CrossRefGoogle Scholar
  24. 24.
    Wang Y, Wu XM, Zhang WZ, Huang S (2015) Facile synthesis of Ni/PANI/RGO composites and their excellent electromagnetic wave absorption properties. Synth Metals 210:165–170CrossRefGoogle Scholar
  25. 25.
    Baniasadi A, Ghasemi A, Nemati A, Ghadikolaei MA, Paimozd E (2014) Effect of Ti–Zn substitution on structural, magnetic and microwave absorption characteristics of strontium hexaferrite. J Alloys Compd 583:325–328CrossRefGoogle Scholar
  26. 26.
    Li M, Huang XY, Wu C, Xu HP, Jiang PK, Tanaka T (2012) Fabrication of two-dimensional hybrid sheets by decorating insulating PANI on reduced graphene oxide for polymer nanocomposites with low dielectric loss and high dielectric constant. J Mater Chem 22:23477–23484CrossRefGoogle Scholar
  27. 27.
    Sawangphruk M, Suksomboon M, Kongsupornsak K, Khuntilo J, Srimuk P, Sanguansak Y, Klunbud P, Suktha P, Chiochan P (2013) High-performance supercapacitors based on silver nanoparticle-polyaniline-graphene nanocomposites coated on flexible carbon fiber paper. J Mater Chem A 1:9630–9636CrossRefGoogle Scholar
  28. 28.
    Luo JH, Zuo Y, Shen P, Yan Z, Zhang K (2017) Excellent microwave absorption properties by tuned electromagnetic parameters in polyaniline-coated Ba0.9La0.1Fe11.9Ni0.1O19/reduced graphene oxide nanocomposites. RSC Adv 7:36433–36443CrossRefGoogle Scholar
  29. 29.
    Sözeri Hüseyin, Mehmedi Z, Kavas Hüseyin, Baykal Abdülhadi (2015) Magnetic and microwave properties of BaFe12O19 substituted with magnetic, non-magnetic and dielectric ions. Ceram Int 41:9602–9609CrossRefGoogle Scholar
  30. 30.
    Xu Y, Yang GL, Chu DP, Zhai HR (1990) Theory of the single ion magnetocrystalline anisotropy of 3D ions. Phys Status Solidi B 157:685–693CrossRefGoogle Scholar
  31. 31.
    Wen B, Cao MS, Lu MM, Cao WQ, Shi HL, Liu J, Wang XX, Jin HB, Fang XY, Wang WZ, Yuan J (2014) Reduced graphene oxides: light-weight and high-efficiency electromagnetic interference shielding at elevated temperatures. Adv Mater 26:3484–3489CrossRefGoogle Scholar
  32. 32.
    Wang TS, Liu ZH, Lu MM, Wen B, Ouyang QY, Chen YJ, Zhu CL, Gao P, Li CY, Cao MS, Qi LH (2013) Graphene-Fe3O4 nanohybrids: synthesis and excellent electromagnetic absorption properties. J Appl Phys 113:024314CrossRefGoogle Scholar
  33. 33.
    Feng W, Wang YM, Chen JC, Wang L, Guo LX, Ouyang JH, Jia DC, Zhou Y (2016) Reduced graphene oxide decorated with in situ growing ZnO nanocrystals: facile synthesis and enhanced microwave absorption properties. Carbon 108:52–60CrossRefGoogle Scholar
  34. 34.
    Panwar V, Mehra RM (2010) Analysis of electrical, dielectric, and electromagnetic interference shielding behavior of graphite filled high density polyethylene composites. Polym Eng Sci 48:2178–2187CrossRefGoogle Scholar
  35. 35.
    Liu XG, Wu ND, Cui CY, Bi NN, Sun YP (2015) One pot synthesis of Fe3O4/MnO2 core–shell structured nanocomposites and their application as microwave absorbers. RSC Adv 5:24016–24022CrossRefGoogle Scholar
  36. 36.
    Zong M, Huang Y, Zhao Y, Sun X, Qu CH, Luo DD, Zheng JB (2013) Facile preparation, high microwave absorption and microwave absorbing mechanism of RGO–Fe3O4 composites. RSC Adv 3:23638–23648CrossRefGoogle Scholar
  37. 37.
    Zhou W, Long L, Xiao P, Li Y, Luo H, Hua WD, Yin RM (2017) Silicon carbide nano-fibers in situ grown on carbon fibers for enhanced microwave absorption properties. Ceram Int 43:5628–5634CrossRefGoogle Scholar
  38. 38.
    Fang J, Liu T, Chen Z, Wang Y, Wei W, Yue X, Jiang Z (2016) A wormhole-like porous carbon/magnetic particles composite as an efficient broadband electromagnetic wave absorber. Nanoscale 8:8899–8909CrossRefGoogle Scholar
  39. 39.
    Wei X, Wang GS, Yin PG (2018) Designed fabrication of reduced graphene oxides/Ni hybrids for effective electromagnetic absorption and shielding. Carbon 139:759–767CrossRefGoogle Scholar
  40. 40.
    Zhang XJ, Wang GS, Cao WQ, Wei YZ, Liang JF, Cao MS (2014) Enhanced microwave absorption property of reduced graphene oxide (RGO)-MnFe2O4 nanocomposites and polyvinylidene fluoride. ACS Appl Mater Interfaces 6:7471–7478CrossRefGoogle Scholar
  41. 41.
    Cao MS, Wang XX, Cao WQ, Fang XY, Wen B, Yuan J (2018) Thermally driven transport and relaxation switching self-powered electromagnetic energy conversion. Small 14:1800987CrossRefGoogle Scholar
  42. 42.
    Cao WQ, Wang XX, Yuan J, Wang WZ, Cao MS (2015) Temperature dependent microwave absorption of ultrathin graphene composites. J Mater Chem C 3:10017–10022CrossRefGoogle Scholar
  43. 43.
    Wen B, Cao MS, Hou ZL, Song WL, Zhang L, Lu MM, Jin HB, Fang XY, Wang WZ, Yuan J (2013) Temperature dependent microwave attenuation behavior for carbon-nanotube/silica composites. Carbon 65:124–139CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringYancheng Institute of TechnologyYanchengChina
  2. 2.Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu ProvinceYancheng Institute of TechnologyYanchengChina

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