Journal of Materials Science

, Volume 54, Issue 7, pp 5961–5970 | Cite as

Excellent self-healing and antifogging coatings based on polyvinyl alcohol/hydrolyzed poly(styrene-co-maleic anhydride)

  • Shuai Luo
  • Xuan Qiao
  • Qiu-Yu Wang
  • Yun-Fei Zhang
  • Ping Fu
  • Zhi-Dong Lin
  • Fei-Peng DuEmail author
  • Chun Cheng


To develop low-cost and high-performance self-healing antifogging coatings, polyvinyl alcohol/hydrolyzed poly(styrene-co-maleic anhydride) (PVA/H-PSMA) coatings were prepared from a mixed solution of polyvinyl alcohol (PVA) and hydrolyzed poly(styrene-co-maleic anhydride) (H-PSMA) via spin coating and annealing. The microstructure, antifogging behavior, and self-healing ability were investigated. High transparency and low surface roughness were observed when the PVA/H-PSMA film was coated on glass slides. The PVA/H-PSMA coatings showed excellent antifogging performance in a warm, humid environment. The coatings also performed well when transferred from a refrigerator to room temperature. The antifogging coatings showed desirable water resistance due to strong chemical bonding between PVA and H-PSMA, as well as excellent self-healing ability due to hydrogen bonding self-assembly in the PVA/H-PSMA structure. The coatings still exhibited excellent antifogging effects after 20 scratching-repairing cycles, illustrating their potential use in practical applications.



This work was supported by the Natural National Science Foundation of China (51373126). The authors also appreciated the Scientific Research Fund Project of Wuhan Institute of Technology (K201779) and Undergraduate Innovation and Entrepreneurship Training Program Project of Hubei Province (201710490038).

Supplementary material

10853_2018_3279_MOESM1_ESM.docx (668 kb)
Supplementary material 1 (DOCX 667 kb)


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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringWuhan Institute of TechnologyWuhanChina
  2. 2.Department of Materials Science and EngineeringSouthern University of Science and TechnologyShenzhenChina

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