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New insights into water dynamics of Portland cement paste with nano-additives using quasielastic neutron scattering

  • Kunal Kupwade-Patil
  • Ali Bumajdad
  • Craig M. Brown
  • Madhusudan Tyagi
  • Nicholas P. Butch
  • Abdullah F. Jamsheer
  • Oral Büyüköztürk
Composites
  • 39 Downloads

Abstract

Early-age hydration kinetics of Portland cement with nano-additives such as nano-silica (NS) was examined using quasielastic neutron scattering (QENS). Cement pastes with different ratios of Portland cement to NS were prepared. The concentration of the NS played a major role in controlling the free and bound water during the hydration of the cement paste. Additionally, the effects of metakaolin (MK) with NS in Portland cements revealed that MK acts as a retarder by decreasing the bounding water capacity during the early age of hydration. An increase in the concentration of NS affected the degree of hydration by reducing the amount of free and mobile water in the gel pores when compared to Portland cement paste. Here, we show that the concentration of NS governs the early-age hydration process in Portland cements.

Notes

Acknowledgements

We thank the “Kuwait Foundation for the Advancement of Sciences” and “Kuwait-MIT Center for Natural Resources and the Environment” for their support during this work. The identification of any commercial product or trade name does not imply endorsement or recommendation by the National Institute of Standards and Technology (NIST). We acknowledge fruitful discussions with Dr. Andrew Allen from NIST.

References

  1. 1.
    Sobolev K, Lin Z, Flores-Vivian I, Pradoto R (2016) Nano-engineered cements with enhanced mechanical performance. J Am Ceram Soc 99(2):564–572.  https://doi.org/10.1111/jace.13819 CrossRefGoogle Scholar
  2. 2.
    Jamsheer AF, Kupwade-Patil K, Büyüköztürk O, Bumajdad A (2018) Analysis of engineered cement paste using silica nanoparticles and metakaolin using 29Si NMR, water adsorption and synchrotron X-ray Diffraction. Constr Build Mater 180:698–709.  https://doi.org/10.1016/j.conbuildmat.2018.05.272 CrossRefGoogle Scholar
  3. 3.
    Brzozowski P, Horszczaruk E, Hrabiuk K (2017) The influence of natural and nano-additives on early strength of cement mortars. Procedia Eng 172:127–134.  https://doi.org/10.1016/j.proeng.2017.02.034 CrossRefGoogle Scholar
  4. 4.
    Shah SP, Hou P, Konsta-Gdoutos MS (2016) Nano-modification of cementitious material: toward a stronger and durable concrete. J Sustain Cem-Based Mater 5(1–2):1–22.  https://doi.org/10.1080/21650373.2015.1086286 Google Scholar
  5. 5.
    Kupwade-Patil K, Cardenas H (2013) Electrokinetic nanoparticle treatment for corrosion remediation on simulated reinforced bridge deck. J Nanopart Res 15(9):1–16.  https://doi.org/10.1007/s11051-013-1952-3 CrossRefGoogle Scholar
  6. 6.
    Senff L, Labrincha JA, Ferreira VM, Hotza D, Repette WL (2009) Effect of nano-silica on rheology and fresh properties of cement pastes and mortars. Constr Build Mater 23(7):2487–2491.  https://doi.org/10.1016/j.conbuildmat.2009.02.005 CrossRefGoogle Scholar
  7. 7.
    Madani H, Bagheri A, Parhizkar T (2012) The pozzolanic reactivity of monodispersed nanosilica hydrosols and their influence on the hydration characteristics of Portland cement. Cem Concr Res 42(12):1563–1570.  https://doi.org/10.1016/j.cemconres.2012.09.004 CrossRefGoogle Scholar
  8. 8.
    Singh LP, Zhu W, Howind T, Sharma U (2017) Quantification and characterization of C–S–H in silica nanoparticles incorporated cementitious system. Cement Concr Compos 79:106–116.  https://doi.org/10.1016/j.cemconcomp.2017.02.004 CrossRefGoogle Scholar
  9. 9.
    Singh LP, Bhattacharyya SK, Shah SP, Mishra G, Ahalawat S, Sharma U (2015) Studies on early stage hydration of tricalcium silicate incorporating silica nanoparticles: Part I. Constr Build Mater 74:278–286.  https://doi.org/10.1016/j.conbuildmat.2014.08.046 CrossRefGoogle Scholar
  10. 10.
    Singh LP, Bhattacharyya SK, Shah SP, Mishra G, Sharma U (2016) Studies on early stage hydration of tricalcium silicate incorporating silica nanoparticles: part II. Constr Build Mater 102:943–949.  https://doi.org/10.1016/j.conbuildmat.2015.05.084 CrossRefGoogle Scholar
  11. 11.
    Biernacki JJ, Bullard JW, Sant G, Brown K, Glasser Fredrik P, Jones S, Ley T, Livingston R, Nicoleau L, Olek J, Sanchez F, Shahsavari R, Stutzman PE, Sobolev K, Prater T (2017) Cements in the 21st century: challenges, perspectives, and opportunities. J Am Ceram Soc 100(7):2746–2773.  https://doi.org/10.1111/jace.14948 CrossRefGoogle Scholar
  12. 12.
    Thomas JJ, FitzGerald SA, Neumann DA, Livingston RA (2001) State of water in hydrating tricalcium silicate and portland cement pastes as measured by quasi-elastic neutron scattering. J Am Ceram Soc 84(8):1811–1816.  https://doi.org/10.1111/j.1151-2916.2001.tb00919.x CrossRefGoogle Scholar
  13. 13.
    Kupwade-Patil K, Tyagi M, Brown CM, Büyüköztürk O (2016) Water dynamics in cement paste at early age prepared with pozzolanic volcanic ash and Ordinary Portland Cement using quasielastic neutron scattering. Cem Concr Res 86:55–62.  https://doi.org/10.1016/j.cemconres.2016.04.011 CrossRefGoogle Scholar
  14. 14.
    Allen AJ, McLaughlin JC, Neumann DA, Livingston RA (2004) In situ quasi-elastic scattering characterization of particle size effects on the hydration of tricalcium silicate. J Mater Res 19(11):3242–3254.  https://doi.org/10.1557/JMR.2004.0415 CrossRefGoogle Scholar
  15. 15.
    Bordallo HN, Aldridge LP, Fouquet P, Pardo LC, Unruh T, Wuttke J, Yokaichiya F (2009) Hindered water motions in hardened cement pastes investigated over broad time and length scales. ACS Appl Mater Interfaces 1(10):2154–2162.  https://doi.org/10.1021/am900332n CrossRefGoogle Scholar
  16. 16.
    Peterson V (2010) Studying the hydration of cement systems in real-time using quasielastic and inelastic neutron scattering. In: Eckold G, Schober H, Nagler SE (eds) Studying kinetics with neutrons, Springer series in solid-state sciences, vol 161. Springer, Berlin, pp 19–75.  https://doi.org/10.1007/978-3-642-03309-4_2 Google Scholar
  17. 17.
    Kupwade-Patil K, Diallo SO, Hossain DZ, Islam MR, Allouche EN (2016) Investigation of activation kinetics in geopolymer paste using quasielastic neutron scattering. Constr Build Mater 120:181–188.  https://doi.org/10.1016/j.conbuildmat.2016.05.104 CrossRefGoogle Scholar
  18. 18.
    Duran A, Serna C, Fornes V, Fernandez Navarro JM (1986) Structural considerations about SiO2 glasses prepared by sol-gel. J Non-Cryst Solids 82(1):69–77.  https://doi.org/10.1016/0022-3093(86)90112-2 CrossRefGoogle Scholar
  19. 19.
    Meyer A, Dimeo RM, Gehring PM, Neumann DA (2003) The high-flux backscattering spectrometer at the NIST Center for Neutron Research. Rev Sci Instrum 74(5):2759–2777.  https://doi.org/10.1063/1.1568557 CrossRefGoogle Scholar
  20. 20.
    Azuah RT, Kneller LR, Qiu Y, Tregenna-Piggott PLW, Brown CM, Copley JRD, Dimeo RM (2009) DAVE: a comprehensive software suite for the reduction, visualization, and analysis of low energy neutron spectroscopic data. J Res Nat Inst Stand Technol 114(6):341–358CrossRefGoogle Scholar
  21. 21.
    Berliner R, Popovici M, Herwig K, Jennings HM, Thomas J (1997) Neutron scattering studies of hydrating cement pastes. Physica B 241–243:1237–1239.  https://doi.org/10.1016/S0921-4526(97)00819-3 CrossRefGoogle Scholar
  22. 22.
    Berliner R, Popovici M, Herwig KW, Berliner M, Jennings HM, Thomas JJ (1998) Quasielastic neutron scattering study of the effect of water-to-cement ratio on the hydration kinetics of tricalcium silicate. Cem Concr Res 28(2):231–243.  https://doi.org/10.1016/S0008-8846(97)00260-3 CrossRefGoogle Scholar
  23. 23.
    Peterson VK, Brown CM, Livingston RA (2006) Quasielastic and inelastic neutron scattering study of the hydration of monoclinic and triclinic tricalcium silicate. Chem Phys 326(2–3):381–389.  https://doi.org/10.1016/j.chemphys.2006.02.016 CrossRefGoogle Scholar
  24. 24.
    Peterson VK, Neumann DA, Livingston RA (2005) Hydration of tricalcium and dicalcium silicate mixtures studied using quasielastic neutron scattering. J Phys Chem B 109(30):14449–14453.  https://doi.org/10.1021/jp052147o CrossRefGoogle Scholar
  25. 25.
    Bordallo HN, Aldridge LP, Desmedt A (2006) Water dynamics in hardened ordinary portland cement paste or concrete: from quasielastic neutron scattering. J Phys Chem B 110(36):17966–17976.  https://doi.org/10.1021/jp062922f CrossRefGoogle Scholar
  26. 26.
    Egami T, Billinge SJL (2012) Underneath the Bragg peaks: structural analysis of complex materials. Elsevier Science, AmsterdamGoogle Scholar
  27. 27.
    Kupwade-Patil K, Chin S, Ilavsky J, Andrews RN, Bumajdad A, Büyüköztürk O (2018) Hydration kinetics and morphology of cement pastes with pozzolanic volcanic ash studied via synchrotron-based techniques. J Mater Sci 53(3):1743–1757.  https://doi.org/10.1007/s10853-017-1659-4 CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Laboratory for Infrastructure Science and Sustainability (LISS), Department of Civil and Environmental EngineeringMassachusetts Institute of TechnologyCambridgeUSA
  2. 2.Nano-Science Group, Department of Chemistry, Faculty of ScienceKuwait UniversitySafatKuwait
  3. 3.NIST Center for Neutron Research (NCNR)National Institute of Standards and TechnologyGaithersburgUSA
  4. 4.Department of Chemical and Biomolecular EngineeringUniversity of DelawareNewarkUSA
  5. 5.Department of Materials Science and EngineeringUniversity of MarylandCollege ParkUSA
  6. 6.Department of PhysicsUniversity of MarylandCollege ParkUSA

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