Journal of Materials Science

, Volume 54, Issue 6, pp 4905–4916 | Cite as

Hierarchical NiCo2−xFexO4/Ni2CoS4 nanoarray-decorated carbon textile anode with enhanced stability and capacitance

  • Zhaohui Liu
  • Chenhao Pan
  • Wen LiEmail author
  • Xiao Zhang
  • Longqiang Wang
  • Bo Lin
  • Shougang ChenEmail author
Energy materials


Subunits of one-dimensional (1D) NiCo2−xFexO4 nanotube and two-dimensional (2D) Ni2CoS4 nanosheet are integrated on carbon textile substrates through a hydrothermal method. With a unique structure and efficient usage of active materials, the prepared NiCo2−xFexO4/Ni2CoS4/carbon textile nanocomposites possess a high specific capacitance of 2220 F g−1 at 1 A g−1 and 91.8% of capacitance retention after 10,000 cycles. The prepared nanocomposites as positive electrode and the biomass carbon as negative electrode are assembled to form an asymmetric supercapacitor, with a maximum energy density of 62.63 Wh kg−1 at a power density of 160.82 W kg−1. The supercapacitor possesses an outstanding cycling stability of 81.6% retention after 10,000 cycles. Tailor-made hollow structure, which could provide sufficient space for the electrode to buffer volume changes due to expansion/contraction of the active material, holds a potential application for high-performance supercapacitors. The superior performance of the hierarchical nanocomposites makes it a promising electrode material for practical application in supercapacitors.



This work was supported by the National Natural Science Foundation (51572249) and the Fundamental Research Funds for the Central Universities (841562011).

Compliance with ethical standards

Conflict of interest

The authors declare no competing financial interest.

Supplementary material

10853_2018_3209_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2368 kb)


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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Material Science and EngineeringOcean University of ChinaQingdaoPeople’s Republic of China
  2. 2.State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdaoPeople’s Republic of China

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