Journal of Materials Science

, Volume 54, Issue 9, pp 6895–6907 | Cite as

In situ green preparation of silver nanoparticles/chemical pulp fiber composites with excellent catalytic performance

  • Hao Gong
  • Mengru Liu
  • Hailong LiEmail author
Chemical routes to materials


In this paper, silver nanoparticles (Ag NPs) were successfully prepared in situ by chemical pulp fiber (CPF) without any additional reductants. In the green synthesis of Ag NPs, CPF acted as both a weak reductant and a stable carrier. The effect of different synthesis conditions was investigated, and the Ag NP load rate was up to 28.12 wt%. The size of the Ag NPs followed a standard Gaussian distribution, ranging from 10 to 50 nm, and a face-centered cubic structure was identified by XRD and TEM. In addition, the AgNPs/CPF composites exhibited good thermostability below 280 °C according to TG analysis. Owing to the high load rate and large specific surface area of Ag NPs, AgNPs/CPF composites exhibited excellent catalytic performance in the reduction of 4-nitrophenol to 4-aminophenol by NaBH4. The conversion rate was up to 95.91% after recycling 50 times, and the catalyst was easily separated from the reaction system. Based on the advantages of high conversion rate, excellent catalytic activity and reusability, AgNPs/CPF composites hold tremendous potential in eliminating nitrophenol and its derivatives from industrial pollution.



The authors acknowledge the Science and Technology Planning Project of Guangdong Province (2015A020215007), the National Natural Science Foundation of China (No. 31670586), the Fundamental Research Funds for the Central Universities (2017ZD091) and the State Key Laboratory of Pulp and Paper Engineering Program (2016C05) for sponsoring this research.


  1. 1.
    Sharma VK, Yngard RA, Lin Y (2009) Silver nanoparticles: green synthesis and their antimicrobial activities. Adv Colloid Interface Sci 145:83–96CrossRefGoogle Scholar
  2. 2.
    El-Nour K, Eftaiha A, Al-Warthan A, Ammar RAA (2010) Synthesis and applications of silver nanoparticles. Arab J Chem 3:135–140CrossRefGoogle Scholar
  3. 3.
    Hsieh CT, Pan C, Chen WY (2011) Synthesis of silver nanoparticles on carbon papers for electrochemical catalysts. J Power Sources 196:6055–6061CrossRefGoogle Scholar
  4. 4.
    Liu X, Cheng H, Cui P (2014) Catalysis by silver nanoparticles/porous silicon for the reduction of nitroaromatics in the presence of sodium borohydride. Appl Surf Sci 292:695–701CrossRefGoogle Scholar
  5. 5.
    Tsukamoto D, Shiro A, Shiraishi Y, Sugano Y, Ichikawa S, Tanaka S, Hirai T (2012) Photocatalytic H2O2 Production from Ethanol/O2 System Using TiO2 Loaded with Au–Ag Bimetallic Alloy Nanoparticles. Acs Catal 2:599–603CrossRefGoogle Scholar
  6. 6.
    Zheng LQ, Yu XD, Xu JJ, Chen HY (2014) Reversible catalysis for the reaction between methyl orange and NaBH4 by silver nanoparticles. Chem Commun 51:1050–1053CrossRefGoogle Scholar
  7. 7.
    Morones JR, Elechiguerra JL, Camacho A, Holt K, Kouri JB, Ramã-Rez JT, Yacaman MJ (2005) The bactericidal effect of silver nanoparticles. Nanotechnology 16:2346–2353CrossRefGoogle Scholar
  8. 8.
    Kim JS, Kuk E, Yu KN et al (2007) Antimicrobial effects of silver nanoparticles. Nanomed-Nanaotechnol 3:95–101CrossRefGoogle Scholar
  9. 9.
    Dong HW, Park KH, Seo JH et al (2011) Enhanced power conversion efficiency in PCDTBT/PC70BM Bulk heterojunction photovoltaic devices with embedded silver nanoparticle clusters. Adv Energy Mater 1:766–770CrossRefGoogle Scholar
  10. 10.
    Hakonen A, Andersson PO, Stenbæk SM, Rindzevicius T, Käll M (2015) Explosive and chemical threat detection by surface-enhanced Raman scattering: a review. Anal Chim Acta 893:1–13CrossRefGoogle Scholar
  11. 11.
    Sondi I, Goia DV, Matijević E (2003) Preparation of highly concentrated stable dispersions of uniform silver nanoparticles. J Colloid Interface Sci 260:75–81CrossRefGoogle Scholar
  12. 12.
    Hu G, Liang G, Zhang W, Jin W, Zhang Y, Chen Q, Cai Y, Zhang W (2018) Silver nanoparticles with low cytotoxicity: controlled synthesis and surface modification with histidine. J Mater Sci 53:4768–4780. CrossRefGoogle Scholar
  13. 13.
    Shinde VV, Kim JH, Patil PS (2013) One-step synthesis and characterization of anisotropic silver nanoparticles: application for enhanced antibacterial activity of natural fabric. J Mater Sci 48:8393–8401. CrossRefGoogle Scholar
  14. 14.
    Liang M, Zhang G, Feng Y, Li R, Hou P, Zhang J, Wang J (2018) Facile synthesis of silver nanoparticles on amino-modified cellulose paper and their catalytic properties. J Mater Sci 53:1568–1579. CrossRefGoogle Scholar
  15. 15.
    Dong X, Ji X, Wu H, Zhao L, Li J, Yang W (2009) Shape control of silver nanoparticles by stepwise citrate reduction. J Phys Chem C 113:6573–6576CrossRefGoogle Scholar
  16. 16.
    Yung KC, Wu SP, Liem H (2009) Synthesis of submicron sized silver powder for metal deposition via laser sintered inkjet printing. J Mater Sci 44:154–159. CrossRefGoogle Scholar
  17. 17.
    Ucar N, Demirsoy N, Onen A et al (2015) The effect of reduction methods and stabilizer (PVP) on the properties of polyacrylonitrile (PAN) composite nanofibers in the presence of nanosilver. J Mater Sci 50:1855–1864. CrossRefGoogle Scholar
  18. 18.
    Pol VG, Srivastava DN, Palchik O, Palchik V, Slifkin MA, Weiss AM, Gedanken A (2002) Sonochemical Deposition of Silver Nanoparticles on Silica Spheres. Langmuir 18:3352–3357CrossRefGoogle Scholar
  19. 19.
    Shahverdi AR, Minaeian S, Shahverdi HR, Jamalifar H, Nohi AA (2007) Rapid synthesis of silver nanoparticles using culture supernatants of Enterobacteria: a novel biological approach. Process Biochem 42:919–923CrossRefGoogle Scholar
  20. 20.
    Mukherjee P, Ahmad A, Mandal D et al (2001) Fungus-mediated synthesis of silver nanoparticles and their immobilization in the mycelial matrix: a novel biological approach to nanoparticle synthesis. Nano Lett 1:515–519CrossRefGoogle Scholar
  21. 21.
    Suman TY, Rajasree SRR, Kanchana A, Elizabeth SB (2013) Biosynthesis, characterization and cytotoxic effect of plant mediated silver nanoparticles using Morinda citrifolia root extract. Colloid Surface B 106:74–78CrossRefGoogle Scholar
  22. 22.
    Liu JF, Yu SJ, Yin YG, Chao JB (2012) Methods for separation, identification, characterization and quantification of silver nanoparticles. Trend Anal Chem 33:95–106CrossRefGoogle Scholar
  23. 23.
    Blaker JJ, Lee KY, Bismarck A (2011) Hierarchical composites made entirely from renewable resources. J Biobased Mater Bio 5:1–16CrossRefGoogle Scholar
  24. 24.
    Samyn P, Barhoum A, Öhlund T, Dufresne A (2018) Review: nanoparticles and nanostructured materials in papermaking. J Mater Sci 53:146–184. CrossRefGoogle Scholar
  25. 25.
    Gessler K, Krauss N, Steiner T, Betzel C, Sandmann C, Saenger W (1994) Crystal structure of beta-d-cellotetraose hemihydrate with implications for the structure of cellulose II. Science 266:1027–1029CrossRefGoogle Scholar
  26. 26.
    Yang HP, Yan R, Chen HP, Zheng CG, Lee DH, Liang DT (2006) In-depth investigation of biomass pyrolysis based on three major components: hemicellulose, cellulose and lignin. Energy Fuel 20:388–393CrossRefGoogle Scholar
  27. 27.
    Csóka L, Božanić DK, Nagy V, Dimitrijevićbranković S, Luyt AS, Grozdits G, Djoković V (2012) Viscoelastic properties and antimicrobial activity of cellulose fiber sheets impregnated with Ag nanoparticles. Carbohyd Polym 90:1139–1146CrossRefGoogle Scholar
  28. 28.
    Kamal T, Ahmad I, Khan SB, Asiri AM (2017) Synthesis and catalytic properties of silver nanoparticles supported on porous cellulose acetate sheets and wet-spun fibers. Carbohyd Polym 157:294–302CrossRefGoogle Scholar
  29. 29.
    He JH, Kunitake T, Nakao A (2003) Facile in situ synthesis of noble metal nanoparticles in porous cellulose fibers. Chem Mater 15:4401–4406CrossRefGoogle Scholar
  30. 30.
    Omrani AA, Taghavinia N (2012) Photo-induced growth of silver nanoparticles using UV sensitivity of cellulose fibers. Appl Surf Sci 258:2373–2377CrossRefGoogle Scholar
  31. 31.
    Dan VG, Matijević E (1998) Preparation of monodispersed metal particles. New J Chem 22:1203–1215CrossRefGoogle Scholar
  32. 32.
    Liz-Marzán LM (2004) Nanometals: formation and color. Mater Today 7:26–31CrossRefGoogle Scholar
  33. 33.
    Texier I, Rémita S, Pierre Archirel A, Mostafavi M (1996) Reduction of Ag1I(NH3)2+ to Ag10(NH3)2 in solution. Redox potential and spectral study. J Phys Chem 100:12472–12476CrossRefGoogle Scholar
  34. 34.
    Shrivastava S, Bera T, Roy A, Singh G, Ramachandrarao P, Dash D (2007) Characterization of enhanced antibacterial effects of novel silver nanoparticles. Nanotechnology 18:225103CrossRefGoogle Scholar
  35. 35.
    Ahmad N, Sharma S, Alam MK, Singh VN, Shamsi SF, Mehta BR, Fatma A (2010) Rapid synthesis of silver nanoparticles using dried medicinal plant of basil. Colloid Surface B 81:81–86CrossRefGoogle Scholar
  36. 36.
    Likius DS, Nagai H, Aoyama S, Mochizuki C, Hara H, Baba N, Sato M (2012) Percolation threshold for electrical resistivity of Ag-nanoparticle/titania composite thin films fabricated using molecular precursor method. J Mater Sci 47:3890–3899. CrossRefGoogle Scholar
  37. 37.
    Park SY, Baker JO, Himmel ME, Parilla PA, Johnson DK (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnol Biofuels 3:1–10CrossRefGoogle Scholar
  38. 38.
    Segal L, Creely JJ, Martin AEJ, Conrad AE (1959) An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text Res J 29:786–794CrossRefGoogle Scholar
  39. 39.
    Li RJ, Fei JM, Cai YR, Li YF, Feng JQ, Yao JM (2009) Cellulose whiskers extracted from mulberry: a novel biomass production. Carbohyd Polym 76:94–99CrossRefGoogle Scholar
  40. 40.
    Chou KS, Lu YC (2007) The application of nanosized silver colloids in far infrared low-emissive coating. Thin Solid Films 515:7217–7221CrossRefGoogle Scholar
  41. 41.
    Hu S, Hsieh YL (2015) Synthesis of surface bound silver nanoparticles on cellulose fibers using lignin as multi-functional agent. Carbohyd Polym 131:134–141CrossRefGoogle Scholar
  42. 42.
    Abdel-Mohsen AM, Hrdina R, Burgert L et al (2013) Antibacterial activity and cell viability of hyaluronan fiber with silver nanoparticles. Carbohyd Polym 92:1177–1187CrossRefGoogle Scholar
  43. 43.
    Cui J, Hu C, Yang Y, Wu Y, Yang L, Wang Y, Liu Y, Jiang Z (2012) Facile fabrication of carbonaceous nanospheres loaded with silver nanoparticles as antibacterial materials. J Mater Sci 22:8121–8126. CrossRefGoogle Scholar
  44. 44.
    Kang JG, Sohn Y (2012) Interfacial nature of Ag nanoparticles supported on TiO photocatalysts. J Mater Sci 47:824–832. CrossRefGoogle Scholar
  45. 45.
    Liang M, Su R, Qi W, Yu Y, Wang L, He Z (2014) Synthesis of well-dispersed Ag nanoparticles on eggshell membrane for catalytic reduction of 4-nitrophenol. J Mater Sci 49:1639–1647. CrossRefGoogle Scholar
  46. 46.
    Sun L, Lv P, Li H, Wang F, Su W, Zhang L (2018) One-step synthesis of Au–Ag alloy nanoparticles using soluble starch and their photocatalytic performance for 4-nitrophenol degradation. J Mater Sci 53:15895–15906. CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.State Key Laboratory of Pulp and Paper EngineeringSouth China University of TechnologyGuangzhouChina

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