Advertisement

Journal of Materials Science

, Volume 46, Issue 20, pp 6751–6757 | Cite as

Thermal properties and crystallization of PbO–MoO3–P2O5 glasses

  • Ivana Rösslerová
  • Ladislav KoudelkaEmail author
  • Zdeněk Černošek
  • Petr Mošner
  • Ludvík Beneš
Article

Abstract

Thermal properties and crystallization of glasses from PbO–MoO3–P2O5 ternary system were studied in three compositional series (100 − x)[0.5PbO–0.5P2O5]–xMoO3 (A), 50PbO–yMoO3–(50 − y)P2O5 (B), and (50 − z)PbO–zMoO3–50P2O5 (C). Glass transition temperature, crystallization temperature, coefficient of thermal expansion, and dilatation softening temperature of the studied glasses were determined by differential thermal analysis and dilatometry. Crystallization products of annealed glass samples were investigated by X-ray diffraction and Raman spectroscopy. X-ray diffraction analysis of crystallized glasses revealed the formation of PbP2O6, Pb3P4O13, and PbMoO4 in the samples of the B series. In the series A and C in the samples with a high MoO3 content, crystalline compounds of Pb(MoO2)2(PO4)2 and (MoO2)(PO3)2, respectively, were identified. Raman spectra of crystalline samples confirmed the results of X-ray diffraction measurements and provided also information on thermal stability of glasses and formation of glass-crystalline phases in the studied glass series.

Keywords

Raman Spectrum Glass Transition Temperature MoO3 Crystallization Peak Glass Transition Region 

Notes

Acknowledgements

The authors are grateful for the financial support from the research project No. P106/10/0283 of the Grant Agency of Czech Republic and from the research project No. 0021627501 of the Ministry of Education of Czech Republic.

References

  1. 1.
    Zakis YR, Lusis AR, Lagzdons YL (1982) J Non-Cryst Solids 47:267CrossRefGoogle Scholar
  2. 2.
    Studer F, Lebail A, Raveau B (1986) J Solid State Chem 63:414CrossRefGoogle Scholar
  3. 3.
    Chowdari BVR, Gopalakrishnan R, Tang SH, Kuok SH (1988) Solid State Ion 28–30:704CrossRefGoogle Scholar
  4. 4.
    Pinet O, Dussossoz JL, David C, Fillet C (2008) J Nucl Mater 377:307CrossRefGoogle Scholar
  5. 5.
    Chourasia R, Shrivastava OP, Wattal PK (2009) J Alloys Comp 473:579CrossRefGoogle Scholar
  6. 6.
    Chowdari BVR, Tan KL, Chia WT, Gopalakrishnan R (1990) Solid State Ion 40–41:684CrossRefGoogle Scholar
  7. 7.
    Chowdari BVR, Tan KL, Chia WT, Gopalakrishnan R (1991) J Non-Cryst Solids 128:18CrossRefGoogle Scholar
  8. 8.
    Bih L, Nadiri A, El Amraoui Y (2005) J Phys IV Fr 123:165CrossRefGoogle Scholar
  9. 9.
    Santagneli SH, de Araujo CC, Strojek W, Eckert H, Poirier G, Ribeiro SJL, Messadeq Y (2007) J Phys Chem B 111:10109CrossRefGoogle Scholar
  10. 10.
    Bih L, Nadiri A, Aride J (2002) J Therm Anal Calorim 68:965CrossRefGoogle Scholar
  11. 11.
    Selvaraj U, Rao KJ (1988) J Non-Cryst Solids 104:300CrossRefGoogle Scholar
  12. 12.
    Koudelka L, Rösslerová I, Holubová J, Mošner P, Montagne L, Delevoye L (2011) J Non-Cryst Solids. doi: https://doi.org/10.1016/j.jnoncrysol.2011.03.006 CrossRefGoogle Scholar
  13. 13.
    Yue Y-Z (2008) J Non-Cryst Solids 354:1112CrossRefGoogle Scholar
  14. 14.
    Bobovich YaS (1962) Opt Spektrosk 13:459Google Scholar
  15. 15.
    Chowdari BVR, Tan KL, Chia WT (1993) Mater Res Soc Symp Proc 293:325CrossRefGoogle Scholar
  16. 16.
    Šubčík J, Koudelka L, Mošner P, Montagne L, Trickot G, Delevoye L, Gregora I (2010) J Non-Cryst Solids 356:2509CrossRefGoogle Scholar
  17. 17.
    Masse R, Averbuch-Pouchot MT, Durif A (1985) J Solid State Chem 58:157CrossRefGoogle Scholar
  18. 18.
    Kissinger HE (1957) Anal Chem 29:1702CrossRefGoogle Scholar
  19. 19.
    Šesták J, Berggren G (1971) Thermochim Acta 3:1CrossRefGoogle Scholar
  20. 20.
    Isaac M, Jayasree V, Suresh G, Nayar VU (1992) Ind J Phys B 66:65Google Scholar
  21. 21.
    Flower GL, Baskaran GS, Reddy MS, Veeraiah N (2007) Phys B 2393:61CrossRefGoogle Scholar
  22. 22.
    Morgan SH, Magruder RH (1990) J Am Ceram Soc 73:753CrossRefGoogle Scholar
  23. 23.
    Kierkegaard P (1961) Ark Kemi 18:521Google Scholar
  24. 24.
    Joint Committee on Powder Diffraction Standards, International Centre of Diffraction Data, Swarthmore, PA, USAGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Ivana Rösslerová
    • 1
  • Ladislav Koudelka
    • 1
    Email author
  • Zdeněk Černošek
    • 1
  • Petr Mošner
    • 1
  • Ludvík Beneš
    • 2
  1. 1.Department of General and Inorganic Chemistry, Faculty of Chemical TechnologyUniversity of PardubicePardubiceCzech Republic
  2. 2.Joint Laboratory of Solid State Chemistry of Institute of Macromolecular ChemistryAcademy of Sciences of the Czech Republic and the University of PardubicePardubiceCzech Republic

Personalised recommendations