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Journal of Materials Science

, Volume 44, Issue 23, pp 6447–6450 | Cite as

Shape- and size-controlled synthesis of coordination polymer {[Cu(en)2][KFe(CN)6]}n nano/micro-crystals

  • Shikui WuEmail author
  • Xiaoping Shen
  • Baosen Cao
  • Li Lin
  • Kecheng Shen
  • Wei Liu
Letter

Introduction

In the last decade, chemists have devoted their efforts and enormous attention to coordination polymers (CP) with infinitely extended structures due to their intriguing properties and potential applications in catalysis [1], gas storage [2, 3], nonlinear optics [4], molecular magnet [5], and molecular recognition and separations [6, 7]. Recently, CP nanocrystals, nanosized coordination polymers with finite repeating units, have aroused a growing interest due to their special properties distinctive from conventional bulk CP [8]. Up to now, the CP nanocrystals of Prussian blue analogies [9, 10, 11] have been intensively studied and various nanocrystals including nanoparticles, nanocubes, nanorods, and nanotubes have been successfully synthesized. However, it still remains a key research challenge to fabricate CP nano/micro-crystals with controlled shape and size, although some works have been demonstrated by several groups [12, 13, 14, 15, 16] in the past 3 years. This new...

Keywords

Coordination Polymer Prussian Blue Standard Pattern Classical Nucleation Theory Ultrasonic Radiation 

Notes

Acknowledgements

Thanks for financial support from the Natural Science Foundation of Jiangsu Province (No. BK2009196) and the Foundation of State Key Laboratory of Coordination Chemistry.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Shikui Wu
    • 1
    • 2
    Email author
  • Xiaoping Shen
    • 2
  • Baosen Cao
    • 1
  • Li Lin
    • 1
  • Kecheng Shen
    • 2
  • Wei Liu
    • 2
  1. 1.China National Food and Safery Supervision and Inspection Center, Haidian District Institute of Products Quality Supervision and InspectionBeijingPeople’s Republic of China
  2. 2.School of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiangPeople’s Republic of China

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