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Journal of Materials Science

, Volume 44, Issue 24, pp 6576–6582 | Cite as

Solvent influence on isomer separation and conformation control of the cyclohexanedicarboxylate ligand toward La(III) coordination polymeric framework

  • Ge Tian
  • Guangshan Zhu
  • Bao-Lian Su
  • Shilun Qiu
Mesostructured Materials

Abstract

Two novel coordination polymers have been synthesized using 1,4-cyclohexanedicarboxylic acid (chdcH2) by the solvent diffusion method. In the presence of different solvents, cis and trans conformations of chdcH2 were completely separated. The reaction in DMF/glycol resulted in a 1D chain framework La(cis-chdc)(DMF)2(NO3) (1) and the reaction in DMSO resulted in the formation of a novel 3D ReO3 topology La2(trans-chdc)3(DMSO)4 (2). Additionally, the solvent molecules (DMF and DMSO) also acted as coordination ligands in the formation of extended structures.

Keywords

Coordination Polymer Nitrate Anion DMSO Molecule Cyclohexane Ring Trans Conformation 

Notes

Acknowledgements

This work was supported by the State Basic Research Project (G2000077507), the National Nature Science Foundation of China (Grant nos. 29873017, 20101004, and 20371020), and the Belgian Federal Government IUAP-PAI program (INANOMAT P6/17) project.

Supplementary material

10853_2009_3633_MOESM1_ESM.doc (212 kb)
Supplementary material 1 (DOC 211 kb)

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  1. 1.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of ChemistryJilin UniversityChangchunChina
  2. 2.Laboratory of Inorganic Materials Chemistry (CMI)The University of Namur (FUNDP)NamurBelgium

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