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Journal of Materials Science

, Volume 44, Issue 24, pp 6683–6692 | Cite as

Perfluoroalkylsulfonic acid-functionalized periodic mesostructured organosilica: a strongly acidic heterogeneous catalyst

  • David Dubé
  • Micha Rat
  • Wei Shen
  • François Béland
  • Serge Kaliaguine
Mesostructured Materials

Abstract

Periodic mesostructured organosilicas (PMO) were synthesized using 1,2-bis(trimethoxysilyl)ethane (BTME) under acidic conditions using Pluronic 123 as surfactant. The PMO ethane-silicas were then grafted with 1,2,2-trifluoro-2-hydroxy-1-trifluoromethylethane sulfonic acid β-sultone yielding a new perfluoroalkylsulfonic acid PMO catalyst. Ordered hexagonal mesostructures (P6mm) with surface areas up to 500 m2/g and narrow pore size distribution (around 5.1 nm) were obtained. This work thus provides an example of chemical modification for the conception of functionalized PMO acid catalysts. Liquid phase self-condensation of heptanal and acetalization of heptanal by 1-butanol were performed at 30 and 75 °C in the presence of these catalysts and results were compared with those obtained with several other heterogeneous hydrophobic acid catalysts.

Keywords

Acid Site Heptanal Proton Conductivity Sulfonic Acid Group Trimethoxysilyl 

Notes

Acknowledgements

The authors thank NSERC for financial support. The authors are grateful to G. Lemay, Dr. S. Mikhailenko, Dr. B. Nohair, and B. Levasseur for assistance in the experimental work.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • David Dubé
    • 1
  • Micha Rat
    • 1
  • Wei Shen
    • 1
  • François Béland
    • 2
  • Serge Kaliaguine
    • 1
  1. 1.Department of Chemical EngineeringLaval UniversityQuebec CityCanada
  2. 2.SiliCycle Inc.Quebec CityCanada

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