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Journal of Materials Science

, Volume 44, Issue 5, pp 1283–1286 | Cite as

Bulk heterojunction organic solar cell based on a novel fluorescent fluorine–boron complex

  • Fen Qiao
  • Aimin LiuEmail author
  • Ying Zhou
  • Yi Xiao
  • Ping Ou Yang
Article

Abstract

The photovoltaic properties of solar cells were investigated via spin coating the poly (2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene) (MEH-PPV) and a newly synthesized n-type difluoro [2-(2-pyridinyl)-1H-indene-1,3(2H)-dionato-N2, O1]-(T-4)-boron (PIDB) with lower LUMO level as active layers. The active layers were characterized in solid state by means of absorption and photoluminescence (PL) spectra with three mixtures ratios in weight. Compared to the pure MEH-PPV, the results showed the blend of MEH-PPV and PIDB enhanced the light intensity as well as broadened the wavelength range of absorption; the intensities of PL spectra of the blends are quenched and confirmed the electron transferred from the photoexcited MEH-PPV backbone to PIDB. Much higher power conversation efficiency was achieved when their mixtures were with a ration of 1:1 by weight. The improved performance of device is attributed to the reduction of contact resistance, which derived from the impedance analysis.

Keywords

Active Layer Fill Factor Organic Solar Cell Phenylene Vinylene Photovoltaic Characteristic 

Notes

Acknowledgements

Authors thank Ying Zhou for the materials supply and Yang Ping Ou for meaningful discussion in experiments.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Fen Qiao
    • 1
  • Aimin Liu
    • 1
    Email author
  • Ying Zhou
    • 2
  • Yi Xiao
    • 2
  • Ping Ou Yang
    • 3
  1. 1.School of Physics and Optoelectronic TechnologyDalian University of TechnologyDalianPeople’s Republic of China
  2. 2.The State Key Laboratory of Fine ChemicalsDalian University of TechnologyDalianPeople’s Republic of China
  3. 3.Key Laboratory of Luminescence and Optical InformationBeijing Jiaotong UniversityBeijingPeople’s Republic of China

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