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Journal of Materials Science

, Volume 44, Issue 1, pp 204–211 | Cite as

Dielectric response features and oxygen migration on rare earth modified lead titanate ferroelectric ceramics

  • A. Peláiz-BarrancoEmail author
  • J. D. S. Guerra
  • F. Calderón-Piñar
  • C. Aragó
  • O. García-Zaldívar
  • R. López-Noda
  • J. A. Gonzalo
  • J. A. Eiras
Article

Abstract

Rare earth (RE) and manganese-modified lead titanate ceramics were studied concerning the presence of two peaks in the temperature dependence of the dielectric permittivity. An eventual incorporation of the RE into A-site and/or B-site in the perovskite structure and the oxygen migration were considered as causes of the observed phenomenon. The structural analysis showed that at least a small amount of Ti4+ could be substituted by the RE ions. It was considered from the pyroelectric and electrical conductivity results that, even when an eventual incorporation of the RE into the A-site and/or B-site of the structure could be possible, both peaks could not be associated with paraelectric–ferroelectric (PE-FE) phase transitions. The observed peak at lower temperatures has been associated with the PE-FE phase transitions, whereas the hopping of oxygen vacancies has been considered as the cause for the dielectric anomaly observed at higher temperatures.

Keywords

Rare Earth Oxygen Vacancy Dielectric Permittivity Perovskite Structure Thermal Hysteresis 

Notes

Acknowledgements

The authors wish to thank the Third World Academy of Sciences (RG/PHYS/LA No. 99-050, No. 02-225, No. 05-043) and FAPESP Brazilian agency (Proc. No. 06/60013-5) for financial support, and ICTP for financial support of Latin-American Network of Ferroelectric Materials (NET-43). Dr. Peláiz-Barranco wishes to thank Universidad Autónoma de Madrid for financial support. Dr. Calderón-Piñar wishes to thank the ICTP program for Training and Research in Italian laboratories.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • A. Peláiz-Barranco
    • 1
    Email author
  • J. D. S. Guerra
    • 2
  • F. Calderón-Piñar
    • 1
  • C. Aragó
    • 3
  • O. García-Zaldívar
    • 1
  • R. López-Noda
    • 4
  • J. A. Gonzalo
    • 3
  • J. A. Eiras
    • 5
  1. 1.Facultad de Física-Instituto de Ciencia y Tecnología de MaterialesUniversidad de La Habana. San Lázaro y L La HabanaCuba
  2. 2.Departamento de Física e QuímicaUniversidade Estadual PaulistaIlha SolteiraBrazil
  3. 3.Departamento de Física de Materiales, Facultad de CienciasUniversidad Autónoma de MadridMadridSpain
  4. 4.Departamento de Física AplicadaICIMAFLa HabanaCuba
  5. 5.Departamento de FísicaUniversidade Federal de São CarlosSao CarlosBrazil

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