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Journal of Materials Science

, Volume 43, Issue 15, pp 5336–5341 | Cite as

Hydrogen sorption characteristics of the composites 90 wt.% Mg (MgH2)–10 wt.% V0.855Ti0.095Fe0.05

  • Eli GrigorovaEmail author
  • Mitko Khristov
  • Maria Khrussanova
  • Pavel Peshev
Article

Abstract

The hydrogen absorption–desorption characteristics of composites containing 90 wt.% Mg or MgH2 and 10 wt.% of the intermetallic compound V0.855Ti0.095Fe0.05 obtained by mechanical alloying for 1 and 5 h in an inert medium were investigated. Absorption measurements were performed under a hydrogen pressure P = 1 MPa at temperatures of 623, 573, 523, and 473 K. Dehydriding was studied at 623 and 573 K and a pressure of 0.15 MPa. It was established that the presence of the additive improved significantly the hydriding kinetics of magnesium while the effect of the duration of mechanical alloying was less pronounced. Due to the small difference in specific surface areas and crystallite sizes, both composites investigated showed no substantial difference in behavior during absorption and desorption of hydrogen. The best absorption–desorption properties were found with the composite 90 wt.% Mg–10 wt.% V0.855Ti0.095Fe0.05 mechanically activated for 5 h.

Keywords

Crystallite Size Mechanical Alloy Hydrogen Storage Absorption Capacity MgH2 

Notes

Acknowledgements

The financial support of the National Fund of Scientific Investigations of Bulgaria under contract No X-1407/2004 is highly appreciated.

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Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Eli Grigorova
    • 1
    Email author
  • Mitko Khristov
    • 1
  • Maria Khrussanova
    • 1
  • Pavel Peshev
    • 1
  1. 1.Institute of General and Inorganic ChemistryBulgarian Academy of SciencesSofiaBulgaria

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