Journal of Materials Science

, Volume 43, Issue 14, pp 4910–4914 | Cite as

A new method for the kinetic study of cyclization reaction during stabilization of polyacrylonitrile fibers

  • Yongping HouEmail author
  • Tongqing Sun
  • Haojing Wang
  • Dong Wu


A new method for the kinetic study of cyclization reaction using the chemical shrinkage was described. The kinetic parameters derived by function fit were used to predict the rate constant at a given temperature and the feasibility of this method was verified by the Kissinger method. The results indicate that the method is feasible and the order of cyclization reaction is relevant to stabilization temperature with an activation energy of 159.11 kJ/mol.


Differential Scanning Calorimetry Shrinkage Itaconic Acid Cyclization Reaction Kissinger Method 



This work was funded by a grant from the National Ministries and Commission Emphases Foundation of China.


  1. 1.
    Jain MK, Balasubramanian M, Desai P, Abhiraman AS (1987) J Mater Sci 22:301. doi: CrossRefGoogle Scholar
  2. 2.
    Devasia R, Nair CP, Sivadasan P, Catherine BK, Ninan KN (2003) J Appl Polym Sci 88:915CrossRefGoogle Scholar
  3. 3.
    Preta IF, Sakata SK, Garcia G, Zimmermann JP, Galembeck F, Giovedi C (2007) J Therm Anal Calorim 87(3):657CrossRefGoogle Scholar
  4. 4.
    Pan G, Muto N, Miyayama M, Yanagida H (1992) J Mater Sci 27:3497. doi: CrossRefGoogle Scholar
  5. 5.
    Kim YJ, Park CR (2005) Carbon 43:2397CrossRefGoogle Scholar
  6. 6.
    Min BG, Sreekumar TV, Uchida T, Kumar S (2005) Carbon 43:599CrossRefGoogle Scholar
  7. 7.
    Warner SB, Peebles LH, Uhlmann DR (1979) J Mater Sci 14:556. doi: CrossRefGoogle Scholar
  8. 8.
    Fitzer E, Muller DJ (1975) Carbon 13:63CrossRefGoogle Scholar
  9. 9.
    Ko TH, Ting HY, Lin CH (1988) J Mater Sci Lett 35:631Google Scholar
  10. 10.
    Bajaj P, Sreekumar TV, Sen K (2001) Polymer 42:1707CrossRefGoogle Scholar
  11. 11.
    Han S, Yoon GH, Suh SK, Kim WG, Moon TJ (1999) J Polym Sci 37:713CrossRefGoogle Scholar
  12. 12.
    Bhat GS, Cook FL, Abhiraman AS (1990) Carbon 28:377CrossRefGoogle Scholar
  13. 13.
    Fitzer E, Frohs W, Heine M (1986) Carbon 24:387CrossRefGoogle Scholar
  14. 14.
    Bahl OP, Manocha LM (1976) Fiber Sci Technol 9:77CrossRefGoogle Scholar
  15. 15.
    Kissinger HE (1957) Anal Chem 29:1702CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Yongping Hou
    • 1
    Email author
  • Tongqing Sun
    • 1
  • Haojing Wang
    • 1
  • Dong Wu
    • 1
  1. 1.Key laboratory of Carbon Materials, Institute of Coal ChemistryChinese Academy of SciencesTaiyuanPeople’s Republic of China

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