Journal of Materials Science

, Volume 43, Issue 12, pp 4230–4235 | Cite as

Catalytic wet oxidations of aromatic compounds over supported copper oxides

  • Ayumu OndaEmail author
  • Yotaro Suzuki
  • Shinji Takemasa
  • Koji Kajiyoshi
  • Kazumichi Yanagisawa


Catalytic wet oxidations of naphthalene as a model compound of persistent aromatic compounds were carried out with hydrogen peroxide in a closed autoclave lined with Teflon. CuO/Al2O3 and CuO/AC catalyst showed the high activity for the naphthalene oxidation with hydrogen peroxide of 1.0 mol L−1 at 100 °C. Naphthalene, whose initial concentration was 1.0 g L−1, was converted completely and the concentration of water-soluble organic compounds in the resultant aqueous solution was less than 25 ppm-C. In contrast, platinum, and manganese oxide, silver oxide, and ruthenium oxide catalysts consumed hydrogen peroxide preferentially. Iron and nickel oxides catalysts showed lower activity than the copper oxide catalyst. During the reaction, the intermediate organic acids were formed and then were oxidized. Simultaneously, copper species of CuO catalysts were dissolved and then were precipitated. The precipitated copper species on the catalyst support showed the catalytic activity. CuO/Al2O3 catalysts showed high activity for the six successive batch reactions with the treatment of sodium carbonate after the reaction to precipitate copper ions.


Naphthalene Copper Oxide Copper Species Ruthenium Oxide Naphthalene Oxidation 


  1. 1.
    Bottini AT, Roberts JD (1957) J Am Chem Soc 79:1458CrossRefGoogle Scholar
  2. 2.
    Graebwl HP, Hagenmaier H (1998) Organohalogen Compd 36:21Google Scholar
  3. 3.
    Okuda K, Yanagisawa K, Moritaka S, Onda A, Kajiyoshi K (2003) Polym Degrad Stab 79:105CrossRefGoogle Scholar
  4. 4.
    Mishra VS, Mahajani VV, Joshi JB (1995) Ind Eng Chem Res 134:2CrossRefGoogle Scholar
  5. 5.
    Thornton TD, Savage PE (1992) Ind Eng Chem Res 31:2451CrossRefGoogle Scholar
  6. 6.
    Sadana A, Katzer JR (1974) J Catal 35:140CrossRefGoogle Scholar
  7. 7.
    Pintar A, Levec J (1992) J Catal 135:345CrossRefGoogle Scholar
  8. 8.
    Vaidya PD, Mahajani VV (2002) Adv Environ Res 6:429CrossRefGoogle Scholar
  9. 9.
    Jin FM, Kishita A, Moriya T, Enomoto H (2001) J Supercrit Fluid 19:251CrossRefGoogle Scholar
  10. 10.
    Shende RV, Levec J (2000) Ind Eng Chem Res 39:40CrossRefGoogle Scholar
  11. 11.
    Matatov-Meytal YI, Shwintuch M (1998) Ind Eng Chem Res 37:309CrossRefGoogle Scholar
  12. 12.
    Santos A, Yustos P, Quintanilla A, Ruiz G, Garcia-Ochoa F (2005) Appl Catal B: Environ 61:323CrossRefGoogle Scholar
  13. 13.
    Guo J, Al-Dahhan M (2003) Ind Eng Chem Res 42:2450CrossRefGoogle Scholar
  14. 14.
    Katzer JR (1978) Ind Eng Chem Fund 17:234CrossRefGoogle Scholar
  15. 15.
    Santos A, Yustos P, Quintanilla A, Garcia-Ochoa F, Casas JA, Rordriguez JJ (2004) Environ Sci Technol 28:133CrossRefGoogle Scholar
  16. 16.
    Furusawa T, Tsutsumi A (2004) Appl Catal A 278:207CrossRefGoogle Scholar
  17. 17.
    Zhao H, Draelants DJ, Baron GV (2000) Ind Eng Chem Res 39:3195CrossRefGoogle Scholar
  18. 18.
    Zhang XW, Shen SC, Yu LE, Kawi S, Hidajat K, Simon Ng KY (2003) Appl Catal A 250:341CrossRefGoogle Scholar
  19. 19.
    Shie JL, Chang CY, Chen JH, Tsai WT, Chen YH, Chiou CS, Chang CF (2005) Appl Catal B: Environ 58:289CrossRefGoogle Scholar
  20. 20.
    Carno J, Ferrandon M, Bjornbom E, Jaras S (1997) Appl Catal A 155:265CrossRefGoogle Scholar
  21. 21.
    Vostrikov AA, Dubov DY, Psarov SA (2001) Russ Chem Bull, Int Ed 50:1481CrossRefGoogle Scholar
  22. 22.
    Chen YH, Chang CY, Huang SF, Chiu CY, Ji D, Shang NC, Yu YH, Chiang PC, Ku Y, Chen JN (2002) Water Res 36:4144 CrossRefGoogle Scholar
  23. 23.
    Legube B, Guyon S, Sugimitsu H, Dore M (1986) Water Res 20:197CrossRefGoogle Scholar
  24. 24.
    Hefter GT (1989) Solubility data series, vol 38 (Hydrocarbons Water Seawater, Pt. 2), pp 236–249Google Scholar
  25. 25.
    Onda A, Suzuki Y, Kajiyoshi K, Yanagisawa K (2006) Ind Eng Chem Res 45:2194CrossRefGoogle Scholar
  26. 26.
    Sotelo JL, Ovejero G, Martinez F, Melero JA, Milieni A (2004) Appl Catal B: Environ 47:281CrossRefGoogle Scholar
  27. 27.
    Plgnatello JJ (1992) Environ Sci Technol 26:944CrossRefGoogle Scholar
  28. 28.
    Ramirez JH, Costa CA, Madeira LM, Mata G, Vicente MA, Rojas-Cervantes ML, López-Peinado AJ, Martín-Aranda RM (2007) Appl Catal B: Environ 71:44CrossRefGoogle Scholar
  29. 29.
    Hamoudi S, Sayari A, Belkacemi K, Bonneviot L, Larachi F (2000) Catal Today 62:379CrossRefGoogle Scholar
  30. 30.
    Masende ZPG, Kuster BFM, Ptasinski KJ, Janssen FJJG, Katima JHY, Schouten JC (2003) Appl Catal B: Environ 41:247CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Ayumu Onda
    • 1
    Email author
  • Yotaro Suzuki
    • 1
  • Shinji Takemasa
    • 1
  • Koji Kajiyoshi
    • 1
  • Kazumichi Yanagisawa
    • 1
  1. 1.Research Laboratory of Hydrothermal LaboratoryKochi UniversityKochiJapan

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