Journal of Materials Science

, Volume 42, Issue 24, pp 10196–10202 | Cite as

Preparation of carbon microparticle assemblies from phenolic resin using an inverse opal templating method

  • Guoqing Guan
  • Katsuki KusakabeEmail author
  • Haruka Ozono
  • Masatsugu Taneda
  • Masato Uehara
  • Hideaki Maeda


Three-dimensionally (3D) well-ordered carbon microparticle assemblies with different particle morphologies were fabricated by infiltration of phenolic resin solution into SiO2 inverse opal structures and subsequent carbonization. The effect of the phenolic resin solution concentration and the carbonization temperature on the morphology of the fabricated carbon microparticles was investigated. At a carbonization temperature of 1000 °C, carbon microparticles with interlocked bridges were obtained when the concentration of phenolic resin solution is 40 wt% and hollow carbon microparticles with opened window channels were obtained at a concentration of 30–35 wt%. When the carbonization temperature was decreased to 500 °C, carbon microparticles with interlocked bridges also were observed, even when the phenolic resin concentration was 30 wt%. The structures and properties of the carbon microparticles and their assemblies were characterized using SEM, XRD, and N2 adsorption.


PMMA Inverse Opal Carbonization Temperature Carbon Sphere Phenolic Resin Solution 



This study was supported by Japan Society for the Promotion of Science (JSPS).


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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Guoqing Guan
    • 1
  • Katsuki Kusakabe
    • 1
    Email author
  • Haruka Ozono
    • 1
    • 2
  • Masatsugu Taneda
    • 1
  • Masato Uehara
    • 2
  • Hideaki Maeda
    • 2
  1. 1.Department of Living Environmental ScienceFukuoka Women`s UniversityHigashi-ku, FukuokaJapan
  2. 2.Nanotechnology Research InstituteNational Institute of Advanced Industrial Science and Technology (AIST)Tosu, SagaJapan

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