Advertisement

Journal of Materials Science

, Volume 42, Issue 22, pp 9163–9169 | Cite as

Electrochemical deposition of Ni and Cu onto monocrystalline n-Si(100) wafers and into nanopores in Si/SiO2 template

  • Yu. A. Ivanova
  • D. K. Ivanou
  • A. K. Fedotov
  • E. A. StreltsovEmail author
  • S. E. Demyanov
  • A. V. Petrov
  • E. Yu. Kaniukov
  • D. Fink
Article

Abstract

Nickel and copper were potentiostatically deposited onto monocrystalline n-Si (100) wafers and in nanoporous SiO2/Si template from 0.5 M NiSO4 + 0.5 M H3BO3 and 0.005 M CuSO4 + 0.5 M H3BO3 solutions. Nanoporous SiO2/Si template was formed by etching in dilute HF solution of ion tracks. The latter were produced by high-energy (380 MeV) Au+ ions bombardment of silicon oxide thermally grown on silicon (100) substrate. The deposition of metals was studied using cyclic voltammetry (CV), chronoamperometry; the structure and morphology of products were ex-situ investigated by SEM and XRD. The level of pores filling was controlled by deposition time. Electrodeposition occurred selectively into nanopores and the deposition on SiO2 layer was excluded. It was found out that Ni and Cu electrodeposited into nanopores of SiO2/Si system formed the same structures as at electrodeposition on the surface of monocrystalline n-Si—granules for Ni and scale-shaped particles for Cu deposits.

Keywords

PbTe PbSe Space Charge Region Cathodic Current SiO2 Layer 

Notes

Acknowledgement

This work was supported by the Belarusian Foundation for Basic Research (Project X07M-128).

References

  1. 1.
    Fink D (2004) Fundamentals of ion-irradiated polymers. Springer Series in Materials Science, vol 63Google Scholar
  2. 2.
    Fink D, Alegaonkar PS, Petrov AV, Berdinsky AS, Rao V, Müller M, Dwivedi KK, Chadderton LT (2003) Radiat Measur 36:605CrossRefGoogle Scholar
  3. 3.
    Fink D, Petrov AV, Hoppe K, Fahrner WR et al (2004) Nucl Instr Meth B218:355CrossRefGoogle Scholar
  4. 4.
    Fink D, Alegaonkar PS, Petrov AV, Wilhelm M, Szimkowiak P, Behar M, Sinha D, Fahrner WR, Hoppe K, Chadderton LT (2005) Nucl Instr Meth B236:11CrossRefGoogle Scholar
  5. 5.
    Sinha D, Petrov AV, Fink D, Fahrner WR, Hoppe K, Chandra A (2004) Radiat Effects Defects Solids 159:517CrossRefGoogle Scholar
  6. 6.
    Fink D, Sinha D, Opitz-Coutureau J, Petrov AV, Demyanov SE, Fahrner WR, Hoppe K, Fedotov AK, Chadderton LT, Berdinsky AS (2005) In: Borisenko VE, Gaponenko SV, Gurin VS (eds) Physics, chemistry and application of nanostructures. World Scientific Pubs., p 474Google Scholar
  7. 7.
    Ivanou DK, Streltsov EA, Fedotov AK, Mazanik AV, Fink D, Petrov A, Tkazyk Z, Wosinski T, Figielski T (2005) In: Pődör B, Horváth J, Basa P (eds) Semiconductor nanocrystals (Proc. of the 1st Intern. Workshop on Semicond. Nanocrystals “SEMINANO-2005”, Budapest, Hungary, September 2005), p 63Google Scholar
  8. 8.
    Ivanou DK, Streltsov EA, Fedotov AK, Mazanik AV, Fink D, Petrov A (2005) Thin Solid Films 490:154CrossRefGoogle Scholar
  9. 9.
    Ubara H, Imura T, Hiraki A (1984) Solid State Commun 50:673CrossRefGoogle Scholar
  10. 10.
    Niwa D, Takano N, Yamada T, Osaka T (2003) Electrochim Acta 48:195CrossRefGoogle Scholar
  11. 11.
    Gurevich YuYa, Pleskov YuV (1983) Photoelektrokhimija poluprovodnikov. Nauka, Moscow, p 176 (in Russian)Google Scholar
  12. 12.
    Rashkova B, Guel B, Pötzschke RT, Staikov G (1998) Electrochim Acta 43:3021CrossRefGoogle Scholar
  13. 13.
    Munoz AG (2006) Surf Coat Technol 201:3030CrossRefGoogle Scholar
  14. 14.
    Oskam G, Long JG, Natarajan A, Searson PC (1998) J Phys D: Appl Phys 31:1927CrossRefGoogle Scholar
  15. 15.
    Pasa AA, Munford ML, Voltolini E, Seligmana L, Sardelab M, Sartorelli ML (2001) In: Proceedings of the magnetic materials, processes, and devices VI. The Electrochemical Society, vol 2000, p 137Google Scholar
  16. 16.
    Ji C, Oskam G, Searson PC (2001) Surf Sci 492:115CrossRefGoogle Scholar
  17. 17.
    Ivanova YuA, Ivanou DK, Streltsov EA (2007) Electrochem Commun 9:599CrossRefGoogle Scholar
  18. 18.
    Ivanova YuA, Ivanou DK, Streltsov EA (2007) Electrochim Acta 52:5213CrossRefGoogle Scholar
  19. 19.
    Gunawardena G, Hills G, Montenegro I, Scharifker B (1982) J Electroanal Chem 138:225CrossRefGoogle Scholar
  20. 20.
    Krumm R, Guel B, Schmitz C, Staikov G (2000) Electrochim Acta 45:3255CrossRefGoogle Scholar
  21. 21.
    Pasa AA, Scharzacher W (1999) Phys Stat Sol(a) 173:73CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Yu. A. Ivanova
    • 1
  • D. K. Ivanou
    • 1
  • A. K. Fedotov
    • 1
  • E. A. Streltsov
    • 1
    Email author
  • S. E. Demyanov
    • 2
  • A. V. Petrov
    • 2
  • E. Yu. Kaniukov
    • 2
  • D. Fink
    • 3
  1. 1.Chemistry DepartmentBelarusian State UniversityMinskBelarus
  2. 2.Joint Institute of Solid State and Semiconductor PhysicsNASBMinskBelarus
  3. 3.Hahn-Meitner-InstituteBerlinGermany

Personalised recommendations