Journal of Materials Science

, Volume 42, Issue 16, pp 6907–6912 | Cite as

An investigation on the surface properties of lyocell-based carbon fiber with inverse gas chromatography

  • Shun-jin PengEmail author
  • Qi-chao Zou


The surface thermodynamic properties of two types of cellulose-based carbon fibers (LYCF and RCF from lyocell and rayon precursors, respectively) were studied by inverse gas chromatography (IGC). It was found the molar free energy of adsorption (ΔG m ads ) of n-alkane probe molecules on the LYCF surface is higher than that of RCF at different temperatures. The interaction of probes on the surfaces of LYCF and RCF becomes stronger with the increasing in the chain length of the n-alkane probes. Simultaneously, the ln Ks is linear to 1/T, where Ks and T are the constant of Henry’s law and temperature, respectively. Similar results were obtained by using Dorris–Gray method (area per methylene unit) and measured probe areas. The results indicate that LYCF and RCF are different in the surface morphology and physical chemistry properties, which suggests that LYCF is a more promising cellulose-based carbon fiber material.


Carbon Fiber Probe Molecule Infinite Dilution Retention Volume Dispersive Component 
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  1. 1.
    Bolvari AE, Ward TC (1989) In: Lloyd D, Ward TC, Schreiber HP, Pizana CC (eds) Inverse gas chromatography characterization of polymers and other materials. American Chemical Society, Washington DC, p 185Google Scholar
  2. 2.
    Schultz J, Lavielle L, Martin C (1987) J Adhes 23:45CrossRefGoogle Scholar
  3. 3.
    Irzhak VI, Kuzub LI (1996) Comp Interf 4(1):45CrossRefGoogle Scholar
  4. 4.
    Kiselev AV (1976) In: Giddings JC, Kellers RA (eds) Advances in chromatography. Marcel Dekker, New York, p 12Google Scholar
  5. 5.
    Montes-morán MA, Paredos JI, Martinez-Alonso A, Tasón JMD (2002) Macromolecules 35:5085CrossRefGoogle Scholar
  6. 6.
    van Asten A, van Vecnendall N, Koster S (2000) J Chromatogr (A) 888:175CrossRefGoogle Scholar
  7. 7.
    Parcher FJ, Edwards RR, Yun KS (1997) Anal Chem Features 69(1):229CrossRefGoogle Scholar
  8. 8.
    Peng SJ, Shao HL, Hu XC (2003) J Appl Polym Sci 90(7):1941CrossRefGoogle Scholar
  9. 9.
    Zou QC, Peng SJ, Chen SZ (2000) Chinese J Chromatogr 18(1):17Google Scholar
  10. 10.
    Zhong MQ, Zhu YQ (1987) Chinese J Chromatogr 5(2):81Google Scholar
  11. 11.
    Fowkes FM, Mostafa MA (1978) Ind Eng Chem Prod Res Dev 17(1):3CrossRefGoogle Scholar
  12. 12.
    Dorris GM, Gray DG (1980) J Colloid Interf Sci 77:355CrossRefGoogle Scholar
  13. 13.
    Jacob PN, Berg JC (1994) Langmuir 10:3086CrossRefGoogle Scholar
  14. 14.
    Peng SJ, Shao HL, Hu XC (2004) Int J Polym Mater 53(7):601CrossRefGoogle Scholar
  15. 15.
    Wu Q, Pan D (2002) Textile Res J 72(5):405CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  1. 1.Science CollegeWuhan University of Science and TechnologyWuhanP.R. China
  2. 2.Chemistry and Chemical EngineeringHubei UniversityWuhanP.R. China

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