Journal of Materials Science

, Volume 42, Issue 16, pp 6792–6797 | Cite as

Carbonate binders by “cold sintering” of calcium carbonate

  • Premalatha De Silva
  • Liana Bucea
  • Vute Sirivivatnanon
  • David R. Moorehead


The solubility of calcium carbonate (limestone) particles depends on the amount of CO2 dissolved in the water, which is a function of temperature and the pressure of CO2 that is in equilibrium with water. At a constant temperature, increasing CO2 pressure increases the solubility of CaCO3, and decreasing CO2 pressure favours the crystallisation of CaCO3. This dissolution–crystallisation behaviour of CaCO3 can be used in the development of carbonate binders—a process called “cold sintering”—of limestone. This paper examines the effect of a range of parameters on the cold sintering process of limestone powder. The parameters studied are CO2 gas pressure (atmospheric, 10 atm and 35 atm), exposure time (0–90 min), post-compaction pressure (10 and 15 MPa) and compact pressing time (10–60 min). The water/limestone powder ratio was kept constant at 0.2 (by weight). The compressive strength of the limestone compacts was used as a measure of the efficiency of the carbonate binder formation process, and scanning electron microscopy was used to study the microstructural developments. The results show that carbonate binders can be produced by cold sintering of limestone powder. Exposure of limestone compacts to high CO2 pressure followed by post-compaction at high mechanical pressure, enhances the strength of the compact. From the microstructural data, it is evident that newly formed calcium carbonate crystal growths are responsible for the strength improvements observed. The amount of water that is used in the limestone powder mixture is one factor that controls the quantity of the cementing phase. Future work has to be focussed on the application of methods to further increase the solubility of calcium carbonate, as the amount of calcium carbonate available for recrystallisation is important in producing a strong binder.


Compressive Strength CaCO3 Calcium Carbonate Compaction Pressure Strength Improvement 
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  1. 1.
    Pietsch W (1991) Size enlargement by agglomeration. Salle + Sauerlander, John Wiley & Sons, New YorkGoogle Scholar
  2. 2.
    Walter LM (1984) J Sediment Petrol 54(4):1081Google Scholar
  3. 3.
    Yamasaki N, Weiping T (1993) J Mater Sci Lett 12:516CrossRefGoogle Scholar
  4. 4.
    Yamasaki N, Shimomto S, Chen Q (1998) Mater Res Innov 2(1):45CrossRefGoogle Scholar
  5. 5.
    Yamasaki N, Weiping T (1995) J Mater Sci Lett 14:1751CrossRefGoogle Scholar
  6. 6.
    Miller JP (1952) Am J Sci 250:161CrossRefGoogle Scholar
  7. 7.
    Butler JN (1991) Carbon dioxide equilibria and their applications. Lewis PublishersGoogle Scholar
  8. 8.
    De Silva P, Bucea L, Moorehead D, Sirivivatnanon V (2006) Cem Concr Comp 28:613CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Premalatha De Silva
    • 1
  • Liana Bucea
    • 1
  • Vute Sirivivatnanon
    • 1
  • David R. Moorehead
    • 2
  1. 1.CSIRO Manufacturing & Infrastructure TechnologyNorth Ryde, SydneyAustralia
  2. 2.ArupNorth Ryde, SydneyAustralia

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