Journal of Materials Science

, Volume 42, Issue 15, pp 6453–6463 | Cite as

Investigation of solid solution of ZrP2O7–Sr2P2O7

  • Semih Seyyidoğlu
  • Macit Özenbaş
  • Necmeddin Yazıcı
  • Ayşen YılmazEmail author


In this study, ZrP2O7 was synthesized by the solid state reaction of ZrO2 and NH4H2PO4 at 900 °C. Then, in set 1; 10, 5, 1, 0.5, 0.1, 0.05, 0.03% previously prepared Sr2P2O7 were doped into ZrP2O7, and Sr2P2O7 slightly affect the unit cell parameter of cubic ZrP2O7 (a = 8.248(6)–8.233(8) Å). The reverse of this process was also applied to Sr2P2O7 system (set 2). ZrP2O7 changes the unit cell parameters of orthorhombic Sr2P2O7 in between a = 8.909(5)–8.877(5) Å, b = 13.163(3)–13.12(1) Å, and c = 5.403(2)–5.386(4) Å. Analysis of the vibrations of the P2O 7 4− ion and approximate band assignments for IR and Raman spectra are also reported in this work. Some coincidences in infrared and Raman spectra both sets were found and strong P–O–P bands were observed. Surface morphology, EDX analysis, and thermoluminescence properties of both sets were given the first time in this paper.


Raman Spectrum Pyrophosphate Unit Cell Parameter Glow Curve Ammoxidation 



This work was supported by BAP-01-03-DPT-03K-120920/09. The authors also dedicated this paper to the memory of Meral Kızılyallı.


  1. 1.
    Withers RL, Tabira Y, Evans JSO, King IJ, Sleight AW (2001) J Solid State Chem 157:186CrossRefGoogle Scholar
  2. 2.
    Khosrovani N, Korthuis V, Sleight AW (1996) Inorg Chem 35:485CrossRefGoogle Scholar
  3. 3.
    Lisnyak VV, Stus NV, Slobodyanik NS, Belyavina NM, Markiv VYA (2000) J Alloys Compd 309:83CrossRefGoogle Scholar
  4. 4.
    Gover RKB, Withers ND, Allen S, Withers RL, Evans JSO (2002) J Solid State Chem 166:42CrossRefGoogle Scholar
  5. 5.
    Chernaya VV, Mitaev AS, Chizhov PS, Dikarev EV, Shapanchenko RV, Antipov EV, Korolenko MV, Fabritchnyi PB (2005) Chem Mater 17:284CrossRefGoogle Scholar
  6. 6.
    Guler H, Kurtulus F (2005) J Mater Sci 40:6565CrossRefGoogle Scholar
  7. 7.
    Smaalen SV, Dinnebier R, Hanson J, Gollwitzer J, Bullesfeld F, Prokofiev A, Assmus W (2005) J Solid State Chem 178:2225CrossRefGoogle Scholar
  8. 8.
    Kizilyalli M, Darras M (1993) J Solid State Chem 107:373CrossRefGoogle Scholar
  9. 9.
    Kizilyalli M (1987) J Less-Common Metals 127:147CrossRefGoogle Scholar
  10. 10.
    Tie SL, Li YY, Yang YS (1997) J Phys Chem Solids 58(6):957CrossRefGoogle Scholar
  11. 11.
    Ferid M, Horchani-Naifer K (2004) Mater Res Bull 39:2209CrossRefGoogle Scholar
  12. 12.
    Ferid M, Horchani K, Amami J (2004) Mater Res Bull 39:1949CrossRefGoogle Scholar
  13. 13.
    Hamady A, Zid MF, Jouini T (1994) J Solid State Chem 113:120CrossRefGoogle Scholar
  14. 14.
    Trunov VK, Oboznenko YV, Sirotikin SP, Tskhelashvili NB (1990) Inorg Mater 27(9):1993Google Scholar
  15. 15.
    Trunov VK, Oboznenko YV, Sirotikin SP, Tskhelashvili NB (1991) Inorg Mater 27(11):2370–2374Google Scholar
  16. 16.
    Ledain S, Leclaire A, Borel MM, Raveau B (1996) Acta Cryst C42:1593Google Scholar
  17. 17.
    Boutfessi A, Boukhari A, Holt EM (1996) Acta Cryst C42:1594Google Scholar
  18. 18.
    Boutfessi A, Boukhari A, Holt EM (1996) Acta Cryst C42:1597Google Scholar
  19. 19.
    Khay N, Ennaciri AA, Harcharras M (2001) Vib Spectrosc 27:119CrossRefGoogle Scholar
  20. 20.
    Khay N, Ennaciri AA (2001) J Alloys Compd 323–324:800CrossRefGoogle Scholar
  21. 21.
    Idrissi MS, Rghioui L, Nejjar R, Benarafa L, Idrissi MS, Lorriaux A, Wallart F (2004) Spectrochim Acta Part A 60:2043CrossRefGoogle Scholar
  22. 22.
    Stock N, Ferey G, Cheetham AK (2000) Solid State Sci 2:307CrossRefGoogle Scholar
  23. 23.
    Assaaoudi H, Butler IS, Kozinski J, Belanger-Gariepy F (2005) J Chem Crystallogr 35(10):809CrossRefGoogle Scholar
  24. 24.
    Varga T, Wilinson AP, Haluska MS, Payzant EA (2005) J Solid State Chem 178:3541CrossRefGoogle Scholar
  25. 25.
    Pelova VA, Grigorov LS (1997) J Luminescence 72–74:241CrossRefGoogle Scholar
  26. 26.
    Kim CH, Yim HS (1999) Solid State Commun 110:137CrossRefGoogle Scholar
  27. 27.
    Marcu IC, Millet JMM, Herrmann JM (2002) Catal Lett 78(1–4):273Google Scholar
  28. 28.
    Inoue S, Ohtaki N (1993) J Chromatogr 645(1):57CrossRefGoogle Scholar
  29. 29.
    Srilakshmi Ch, Ramesh K, Nagaraju P, Lingaiah N, Prasad PSS (2006) Catal Lett 106(3–4):115CrossRefGoogle Scholar
  30. 30.
    Fukuda K, Moriyama A, Hashimoto S (2004) J Solid State Chem 177:3514CrossRefGoogle Scholar
  31. 31.
    Natarajan V, Bhide MK, Dhobale AR, Godbole SV, Seshagari TK, Page AG, Lu CH (2004) Mater Res Bull 39:2065CrossRefGoogle Scholar
  32. 32.
    Altermatt UD, Brown ID (1987) Acta Cryst A34:125CrossRefGoogle Scholar
  33. 33.
    Pillai VPM, Thomas BR, Nayar VU, Lii KH (1999) Spectrochim Acta Part A 55:1809CrossRefGoogle Scholar
  34. 34.
    Baran EJ, Mercader RC, Massafero A, Kremer E (2004) Spectrochim Acta Part A 60:1001CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Semih Seyyidoğlu
    • 1
  • Macit Özenbaş
    • 2
  • Necmeddin Yazıcı
    • 3
  • Ayşen Yılmaz
    • 1
    Email author
  1. 1.Department of ChemistryMiddle East Technical University AnkaraTurkey
  2. 2.Department of Metallurgical and Materials EngineeringMiddle East Technical UniversityAnkaraTurkey
  3. 3.Department of Engineering Physics, Faculty of EngineeringGaziantep University Gaziantep TurkeyTurkey

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