Journal of Materials Science

, Volume 41, Issue 18, pp 6081–6086 | Cite as

Spontaneous formation of the B2 phase from a decagonal quasicrystal under reduced constraint

  • S. H. Kim
  • K. ChattopadhyayEmail author
  • B. J. Inkson
  • G. Möbus
  • W. T. Kim
  • D. H. Kim

Since the discovery that vacancies can quasiperiodically order in a basic B2 structure to yield a one-dimensional quasiperiodicity, these phases were subjected to intense investigations for possible links with quasicrystal [1, 2]. The B2 phase was found to co-exist extensively with the icosahedral quasicrystalline phase, particularly in Al–Cu–TM (TM = transition metal) systems where the two phase fields are often adjacent to each other [3]. The two phase exhibit a well-defined orientation relationship. There exist several studies dealing with quasicrystalline to B2 transformation, particularly in decagonal quasicrystals Döblinger et al. [4] has carefully explored different metastable states in Al–Co–Ni decagonal quasicrystals including nanodomained 1D quasicrystals and multiple twinned approximant phase. The decagonal to a cubic B2 ordered phase transformation can often be observed. The nanocrystals of the B2 phase could be observed on the surface of the decagonal quasicrystal. Zhang...


Orientation Relationship Body Centered Cubic Quasicrystalline Phase Thin Edge Decagonal Quasicrystal 



This work is partly supported by Creative Research Initiatives of the Korean Ministry of Science and Technology. The first author (SHK) thanks for financial support by postdoctoral fellowship program from Korea Science & Engineering Foundation (KOSEF).


  1. 1.
    Chattopadhyay K, Lele S, Thangaraj N, Ranganathan S (1987) Acta Metall 35:727CrossRefGoogle Scholar
  2. 2.
    Dong C (1995) Scripta Metall Mater 33:239CrossRefGoogle Scholar
  3. 3.
    Dong C, Perrot A, Dubois JM, Belin E (1994) Mater Sci Forum 403:150Google Scholar
  4. 4.
    Döblinger M, Wittmann R, Grushko B (2001) Phys Rev B 64:134208CrossRefGoogle Scholar
  5. 5.
    Zhang H, Urban K (1992) Phil Mag Lett 209:66Google Scholar
  6. 6.
    Zurkirch M, Bolliger B, Erbudak M, Kortan AR (1998) Phys Rev B58:14113CrossRefGoogle Scholar
  7. 7.
    Shimoda M, Guo JQ, Sato TJ, Tsai A-P (2000) Surf Sci 454–456:11CrossRefGoogle Scholar
  8. 8.
    Flückiger T, Michlmayr T, Biely C, Lüscher R, Erbudak M (2003) Appl Surf Sci 212–213:43CrossRefGoogle Scholar
  9. 9.
    Mukhopadhyay NK, Weatherly GC (2001) Mater Sci Eng A 304–306:855CrossRefGoogle Scholar
  10. 10.
    Murty BS et al (2004) J Non Cryst Solids 334&335:48CrossRefGoogle Scholar
  11. 11.
    Dong C, Wang DH, Wang YM, Ge F, He FZ, Zhang QH, Chattopadhyay K, Ranganathan S (1998) In: Proc of 6th International Conference on Quasicrystals. 223Google Scholar
  12. 12.
    Stuerer W (2000) Mater Sci Eng 294–296:268CrossRefGoogle Scholar
  13. 13.
    Song GS, Kim WT, Kim DH, Zhong ZZ, Yang GC, Zhou YH (2000) J Mater Sci Lett 19:363CrossRefGoogle Scholar
  14. 14.
    Jeong HT, Kim SH, Kim WT, Kim DH, Inkson BJ (2000) J Cryst Growth 217:217CrossRefGoogle Scholar
  15. 15.
    Chien CL, Lu M (1992) Phys Rev B45:12793CrossRefGoogle Scholar
  16. 16.
    Beeli C, Horiuchi S (1994) Phil Mag B70:215CrossRefGoogle Scholar
  17. 17.
    Dong C, Dubois JM, Kang SS, Audier M (1992) Phil Mag B65:107CrossRefGoogle Scholar
  18. 18.
    Yushenko M, Grushko B, Velikanova TA, Urban K (2004) J Alloy Compound 367:20CrossRefGoogle Scholar
  19. 19.
    Hull D (1962) Phil Mag 7:537CrossRefGoogle Scholar
  20. 20.
    Chattopadhyay K (1985) Z Metallkde 76:496Google Scholar
  21. 21.
    Burkov SE (1991) Phys Rev Lett 67:614CrossRefGoogle Scholar
  22. 22.
    Steurer W, Haibach T, Zhang B, Kek S, Luck R (1993) Acta Crystallogr B49:661CrossRefGoogle Scholar
  23. 23.
    Dong C, Zhang Q, Wang D, Wang Y (1999) Philos Mag A 79:501CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2006

Authors and Affiliations

  • S. H. Kim
    • 1
  • K. Chattopadhyay
    • 2
    Email author
  • B. J. Inkson
    • 3
  • G. Möbus
    • 3
  • W. T. Kim
    • 4
  • D. H. Kim
    • 5
  1. 1.School of Advanced Materials and Systems EngineeringKumoh National Institute of TechnologyGumiKorea
  2. 2.Department of MetallurgyIndian Institute of ScienceBangaloreIndia
  3. 3.Department of Engineering MaterialsThe University of SheffieldSheffieldUK
  4. 4.Center for Noncrystalline Materials, Department of PhysicsChongju UniversityChongjuKorea
  5. 5.Center for Noncrystalline Materials, Department of Metallurgical EngineeringYonsei UniversitySodaemun-ku, SeoulKorea

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