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Journal of Materials Science

, Volume 42, Issue 12, pp 4624–4629 | Cite as

Effects of calcination conditions on phase and morphology evolution of lead zirconate powders synthesized by solid-state reaction

  • W. Chaisan
  • O. Khamman
  • R. Yimnirun
  • S. AnantaEmail author
Article
First Online:

Abstract

Lead zirconate (PbZrO3) powder has been synthesized by a solid-state reaction via a rapid vibro-milling technique. The effects of calcination temperature, dwell time and heating/cooling rates on phase formation, morphology, particle size and chemical composition of the powders have been investigated by TG-DTA, XRD, SEM and EDX techniques. The results indicated that at calcination temperature lower than 800 °C minor phases of unreacted PbO and ZrO2 were found to form together with the perovskite PbZrO3 phase. However, single-phase PbZrO3 powders were successfully obtained at calcination conditions of 800 °C for 3 h or 850 °C for 1 h, with heating/cooling rates of 20 °C/min. Higher temperatures and longer dwell times clearly favored the particle growth and formation of large and hard agglomerates.

Keywords

Calcination Dwell Time Calcination Temperature Barium Titanate Lead Zirconate 
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Notes

Acknowledgements

We thank the Thailand Research Fund (TRF), the Comission on Higher Education (CHE), Graduate School, Faculty of Science, and Center of Excellence in Functional Nanomaterials, Chiang Mai University for all supports.

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • W. Chaisan
    • 1
  • O. Khamman
    • 1
  • R. Yimnirun
    • 1
  • S. Ananta
    • 1
    Email author
  1. 1.Department of Physics, Faculty of ScienceChiang Mai UniversityChiang MaiThailand

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