Advertisement

Journal of Materials Science

, Volume 41, Issue 15, pp 4876–4882 | Cite as

Effect of time on the reconstruction of the Mg4Al2(OH)12CO3·3H2O layered double hydroxide in a Na2CO3 solution

  • F. Delorme
  • A. Seron
  • M. Bizi
  • V. Jean-Prost
  • D. Martineau
Article

Abstract

The effect of time on the reconstruction of an Mg4Al2(OH)12CO3·3H2O LDH compound in a 0.1 M Na2CO3 solution have been investigated. It seems that the reconstruction phenomena of the Mg4Al2(OH)12CO3·3H2O LDH after a moderate thermal treatment is a very fast process, as it is already completed after 5 min of soaking in a 0.1 M Na2CO3 solution. Indeed, the weight of the reconstructed samples after the centrifuging-washing-drying cycle, as well as the carbon content of the reconstructed samples, remains constant whatever the time of contact between the solution and the mixed oxides issued from LDH. Powder XRD patterns are also similar for all the reconstructed samples without significant FWHM variations. SEM and TEM observations coupled with granulometric and BET measurements show that all the samples, both mixed oxides and reconstructed LDHs, are composed by aggregates of small plate-like particles (less than 100 nm) with a sub-hexagonal morphology but with different porosities.

Keywords

Mixed Oxide Reconstruction Process Na2CO3 Solution Sodium Polyacrylate Reconstructed Sample 

Notes

Acknowledgment

The authors would like to thank D. Jalabert (university of Orleans) for its technical support for the TEM observations.

References

  1. 1.
    Cavani F, Trifiro F, Vaccari A (1991) Catal Today 11:173CrossRefGoogle Scholar
  2. 2.
    Miyata S (1983) Clays Clay Miner 31:305CrossRefGoogle Scholar
  3. 3.
    Choy J-H (2004) J Phys Chem Solids 65:373CrossRefGoogle Scholar
  4. 4.
    Reichle WT (1986) Solid States Ionics 22:135CrossRefGoogle Scholar
  5. 5.
    Kagunya W, Hassan Z, Jones W (1996) Inorg Chem 35:5970CrossRefGoogle Scholar
  6. 6.
    Vaccari A (1998) Catal Today 41:53CrossRefGoogle Scholar
  7. 7.
    Constantino VRL, Pinnavaia TJ (1995) Inorg Chem 34:883CrossRefGoogle Scholar
  8. 8.
    Sanchez Valente J, Figueras F, Gravelle M, Kumbhar P, Lopez J, Besse J-P (2000) J Catal 189:370CrossRefGoogle Scholar
  9. 9.
    Alejandre A, Medina F, Rodriguez X, Salagre P, Cesteros Y, Sueiras JE (2001) Appl Catal B: Environ 30:195CrossRefGoogle Scholar
  10. 10.
    Giannelis EP, Nocera DG, Pinnavaia TJ (1987) Inorg Chem 26:203CrossRefGoogle Scholar
  11. 11.
    Bish DL (1980) Bull Mineral 103:170Google Scholar
  12. 12.
    Ookubo A, Ooi K, Hayashi H (1993) Langmuir 9:1418CrossRefGoogle Scholar
  13. 13.
    You Y, Vance GF, Zhao H (2001) Appl Clay Sci 20:13CrossRefGoogle Scholar
  14. 14.
    Seida Y, Nakano Y (2002) Water Res 36:1306CrossRefGoogle Scholar
  15. 15.
    Das DP, Das J, Parida K (2003) J Colloid and Interf Sci 261:213CrossRefGoogle Scholar
  16. 16.
    Orthman J, Zhu HY, Lu GQ (2003) Sep Purif Technol 31:53CrossRefGoogle Scholar
  17. 17.
    Lotsch B, Millange F, Walton RI, O’Hare D (2001) Solid State Sci 3:883CrossRefGoogle Scholar
  18. 18.
    Moroz T, Razvorotneva L, Grigorieva T, Mazurov M, Arkhipenko D, Prugov V (2001) Appl Clay Sci 18:29CrossRefGoogle Scholar
  19. 19.
    Kwak S-Y, Jeong Y-J, Park J-S, Choy J-H (2002) Solid State Ionics 151:229CrossRefGoogle Scholar
  20. 20.
    Chen W, Feng L, Qu B (2004) Solid State Commun 130:259CrossRefGoogle Scholar
  21. 21.
    Leroux F, Gachon J, Besse J-P (2004) J Solid State Chem 177:245CrossRefGoogle Scholar
  22. 22.
    Tichit D, Lhouty MH, Guida A, Chiche BH, Figueras F, Auroux A, Bartalini D, Garrone E (1995) J Catal 151:50CrossRefGoogle Scholar
  23. 23.
    Kooli F, Depege C, Ennaqadi A, De Roy A, Besse JP (1997) Clays Clay Miner 45:92CrossRefGoogle Scholar
  24. 24.
    Puttaswamy NS, Kamath PV (1997) J Mater Chem 7:1941CrossRefGoogle Scholar
  25. 25.
    Millange F, Walton RI, O’Hare D (2000) J Mater Chem 10:1713CrossRefGoogle Scholar
  26. 26.
    Rajamathi M, Nataraja GD, Ananthamurthy S, Kamath PV (2000) J Mater Chem 10:2754CrossRefGoogle Scholar
  27. 27.
    Stanimirova TS, Kirov G, Dinolova E (2001) J Mater Sci Lett 20:453CrossRefGoogle Scholar
  28. 28.
    Stanimirova TS, Kirov G (2003) Appl Clay Sci 22:295CrossRefGoogle Scholar
  29. 29.
    Chibwe K, Jones W (1989) Chem Mater 1:489CrossRefGoogle Scholar
  30. 30.
    Kooli F, Rives V, Ulibarri MA (1995) Inorg Chem 34:5114CrossRefGoogle Scholar
  31. 31.
    Shannon RD (1976) Acta Cryst A 32:751CrossRefGoogle Scholar
  32. 32.
    Prinetto F, Ghiotti G, Graffin P, Tichit D (2000) Micropor Mesopor Mat 39: 229CrossRefGoogle Scholar
  33. 33.
    Sato T, Fujita H, Endo T, Shimada M, Tsunashima A (1988) React Solid 5:219CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2006

Authors and Affiliations

  • F. Delorme
    • 1
  • A. Seron
    • 2
  • M. Bizi
    • 2
  • V. Jean-Prost
    • 1
  • D. Martineau
    • 3
  1. 1.BRGM, MMA/MEPOrleans Cedex 2France
  2. 2.BRGM, EPI/PROOrleans Cedex 2France
  3. 3.BRGM, MMA/ACIOrleans Cedex 2France

Personalised recommendations