Ion transport and battery studies of a new (PVP + KIO3) polymer electrolyte system
- 106 Downloads
Polymer materials in combination with suitable metal salts give electrolytes for advanced high energy electrochemical devices, e.g. batteries/fuel cells, electrochemical display devices/smart windows and photoelectrochemical cells, etc. [1, 2, 3, 4, 5]. The main advantages of polymeric electrolytes are satisfactory mechanical properties, ease of fabrication as thin films and an ability to form good electrode/electrolyte contact. Most of the studies in this field are devoted to poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO) based polymer electrolytes using alkali metal salts [6, 7, 8, 9, 10, 11]. Some conducting polymer electrolytes have been reported based on PEO complexed with ammonium salts such as NH4SCN and NH4CF3SO3 , NH4ClO4 [13, 14] and NH4I .
In an attempt to study the possibility of fabricating electrochemical cells based on polymers other than widely studied polymers such as PEO, PPO, etc., studies have been undertaken on electrochemical cells based on...
KeywordsDifferential Scanning Calorimetry Polymer Electrolyte Transference Number Vinyl Pyrrolidone Short Circuit Current
The author M. Jaipal Reddy thanks CSIR, New Delhi, India for the financial support under Scientist’s Pool scheme.
- 1.Mac Callum JR, Vincent CA (eds) (1987) Polymer electrolyte Rev. Elsevier, AmsterdamGoogle Scholar
- 4.Owen JR (1989) In: Lasker AL, Chandra S (eds) Superionic solid electrolytes—recent trends, Academic Press, New York, p 111Google Scholar
- 7.Sorenson PR, Jacobson T (1985) Electrochem Acta 27:67Google Scholar
- 8.Fautex D, Robitaille C (1986) J Electrchem Soc 133:307Google Scholar
- 20.Wagner JB, Wagner CJ (1957) Chem Phys 26:1597Google Scholar
- 25.Scrosati B (1988) In: Chowdari BVR, Radha Krishna S (eds) Solid state ionic devices, World Scientific Publ. Company, Singapore, p 113Google Scholar