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Journal of Materials Science

, Volume 42, Issue 3, pp 794–800 | Cite as

Mixed manganese spinel oxides: optical properties in the infrared range

  • N. ChasserioEmail author
  • B. Durand
  • S. Guillemet
  • A. Rousset
Article

Abstract

Spinel oxides in manganite family are studied in terms of optical properties in the infrared range (3–12 μm). The reflectivity is measured on sintered pellets. The complex refractive index is estimated by fitting hemispherical directional reflectance in both polarizations, perpendicular and parallel. The influence of different metallic cations (Ni, Co, Fe, Cu) is compared. In particular, in the case of manganese nickel copper oxides, the impact of variations in copper and nickel contents is evaluated. Cationic distribution is determined and correlated to the optical characteristics. These materials, usually used for NTC thermistor applications, are investigated for IR charges in coating.

Keywords

Manganite Copper Content Nickel Content Cationic Distribution Nickel Copper 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

The authors are grateful to DGA for financially support this work. They also thank B. Berton, N. Vukadinovic and Olivier Calvo-Perez (Dassault Aviation, France) and L. Sauques, P. Sigaud and T. Dubois (Centre Technique d’Arcueil, France) for their help in optical measurements.

References

  1. 1.
    Shannon RD, Shannon RC, Medenbach O, Fischer RX (2002) Journal of physical and chemical reference data 31:931CrossRefGoogle Scholar
  2. 2.
    Palik ED Handbook of optical constants of solids (I,II)Google Scholar
  3. 3.
    Battault T, Legros R, Rousset A (1995) Journal of european ceramic society 15:1141CrossRefGoogle Scholar
  4. 4.
    Chanel C, Fritsch S, Drouet C, Rousset A, Sarrion MLM, Mestres L, Morales M (2000) Materials research bulletin 35:431CrossRefGoogle Scholar
  5. 5.
    Drouard S, Tailhades P, Rousset A (1997) Comptes rendus de l’académie des sciences-Série IIB-Mechanics-Physics-Chemistry-Astronomy 325:739CrossRefGoogle Scholar
  6. 6.
    Villette C, Tailhades P, Rousset A (1995) Journal of solid state chemistry 117:64CrossRefGoogle Scholar
  7. 7.
    Maliston IH, Murphy FV, Rodeny WS (1958) Journal of optical society of America 48:72CrossRefGoogle Scholar
  8. 8.
    Thomas ME (1989) SPIE 1112Google Scholar
  9. 9.
    Barker AS (1963) Physical review 132:1474CrossRefGoogle Scholar
  10. 10.
    Herzberger MH, Salzberg CD (1962) Journal of optical society of America 52:240CrossRefGoogle Scholar
  11. 11.
    Boyd GD, Miller RC, Nassau K, Bond WL, Savage A (1964) Applied physics letters 5:934CrossRefGoogle Scholar
  12. 12.
    Piriou B, Cabannes F (1968) Optical acta 15:271CrossRefGoogle Scholar
  13. 13.
    Axe JD, O’Kane DF (1966) Applied Physics Letters 9:58CrossRefGoogle Scholar
  14. 14.
    Herzberger M (1958) Optical acta 6:197Google Scholar
  15. 15.
    Herzberger M, Salzberg CD (1962) Journal of optical society of America 52:420CrossRefGoogle Scholar
  16. 16.
    Servoin JL, Luspin Y, Gervais F (1980) Physical review B 22:5501CrossRefGoogle Scholar
  17. 17.
    Loh E (1968) Physical review 166:673CrossRefGoogle Scholar
  18. 18.
    O’Keeffe MI (1963) Journal of Chemical Physics 39:1789CrossRefGoogle Scholar
  19. 19.
    Servoin JL, Gervais F, Quittet AM, Luspin Y (1980) Physical review B 21:2038CrossRefGoogle Scholar
  20. 20.
    Caffin JP, Rousset A, Carnet R, Lagrange A (1987) Materials science monograph 380:1743Google Scholar
  21. 21.
    Jarrige J, Mexmain J (1976) Bulletin de la société chimique de France 3–4:405Google Scholar
  22. 22.
    Battault T (1996) Journal of material synthesis and processing 4:361Google Scholar
  23. 23.
    Hervé P, Techniques de l’ingénieur, Vol. Mesures Physiques/ Grandeurs thermiques R 2 7371Google Scholar
  24. 24.
    Elbadraoui E, Baudour JL, Bouree F, Gillot B, Fritsch S, Rousset A (1997) Solid state ionics 93:219CrossRefGoogle Scholar
  25. 25.
    Battault T, Legros R, Rousset A (1995) Journal of the european ceramic society 15:1141CrossRefGoogle Scholar
  26. 26.
    Rousset A (1996) Solid state ionics 84:293CrossRefGoogle Scholar
  27. 27.
    Trollund E, Chartier P, Gautier J-L (1990) Electrochimica acta 35:1303CrossRefGoogle Scholar
  28. 28.
    Bhandage GT, Keert HV (1976) Journal of physics C 9:1325CrossRefGoogle Scholar
  29. 29.
    Drouet C, Laberty C, Fierro JLG, Alphonse P, Rousset A (2000) International journal of inorganic materials 2:419CrossRefGoogle Scholar
  30. 30.
    Navrotsky A, Kleppa OJ (1967) Journal of inorganic nuclear chemistry 29:2701CrossRefGoogle Scholar
  31. 31.
    Meenakshisundaram A, Gunasekaram N, Srinvasan V (1982) Physica status solidi a 68Google Scholar
  32. 32.
    Caffin J-P (1986) thesis, Université Paul Sabatier (Toulouse)Google Scholar
  33. 33.
    Fritsch S (1995) thesis, Université Paul Sabatier (Toulouse)Google Scholar
  34. 34.
    Elbadraoui E, Baudour JL, Bouree F, Gillot B, Fritsch S, Rousset A (1997) Solid state ionics 93:219CrossRefGoogle Scholar
  35. 35.
    Boucher R, Buhl R, Perrin M (1969) Acta cristallographica B 25:2326CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • N. Chasserio
    • 1
    Email author
  • B. Durand
    • 1
  • S. Guillemet
    • 1
  • A. Rousset
    • 1
  1. 1.Centre Interuniversitaire de Recherche et d’Ingénierie des Matériaux (CIRIMAT), CNRS UMR 5085, Laboratoire de Chimie des Matériaux Inorganiques et EnergétiquesUniversité Paul SabatierToulouse cedex 9France

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