Template-free, single-step electrochemical synthesis of nickel phosphide thin films with one-dimensional nano-pore channels

  • Yong-Guk Gwon
  • Jong-Won LeeEmail author
  • Heon-Cheol ShinEmail author
Research Article
Part of the following topical collections:
  1. Electrodeposition


This is the first study to report the synthesis of porous nickel phosphide (NiP) thin films with one-dimensional nano-pore channels via a porous template-free, single-step plating process. The nano-pores in the synthesized films were primarily formed in areas where multiple grain boundaries met during the island growth of three-dimensional grains. We investigated the factors that affect pore formation by considering the electroplating reaction mechanism of nickel phosphide and the pattern of grain growth over time, and we determined that grain size and gas generation were the dominant factors affecting pore density. Grain size and gas generation can be adjusted by altering the plating conditions, such as current density and electrolyte pH; we have demonstrated that by controlling these conditions, the pore density can be controlled in an expected manner.

Graphic abstract


Nickel phosphide Electrodeposition Nano-pore Single-step Template-free 



This work was supported by the National Research Foundation (NRF-2017R1D1A3B04031667, 2018R1A5A1025594) of the Ministry of Science and ICT. One of the authors (Y.-G. Gwon) was supported by a scholarship for graduate students in science and engineering funded by the Hyundai Motor Chung Mong-Koo Foundation (ENS-18-001).


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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringPusan National UniversityBusanRepublic of Korea
  2. 2.Department of Materials Science and EngineeringChosun UniversityGwangjuRepublic of Korea

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