Journal of Applied Electrochemistry

, Volume 48, Issue 5, pp 509–518 | Cite as

A facile one-step hydrothermal synthesis of carbon–MoS2 yolk–shell hierarchical microspheres with excellent electrochemical cycling stability

  • Jingjing Wang
  • Ming Chen
  • Xuehua Yan
  • Chen Zhou
  • Qiong Wang
  • Dongfeng Wang
  • Xiaoxue Yuan
  • Jianmei Pan
  • Xiaonong Cheng
Research Article
  • 36 Downloads
Part of the following topical collections:
  1. Batteries

Abstract

Materials with yolk–shell structure have attracted wide attention and they have been applied in energy storage devices with long cycle life. Carbon (yolk)–MoS2 (shell) hierarchical microspheres were successfully prepared in this study by a facile one-step hydrothermal method. Scanning electron microscope and transmission electron microscope images showed that the carbon–MoS2 microspheres were obviously made up of carbon yolk and MoS2 shell. The diameter of the yolk and thickness of shell were 2.1 and 0.26 µm, respectively. The as-prepared carbon–MoS2 yolk–shell hierarchical microspheres displayed charge capacity of 120 F g−1 after 3000 charge and discharge cycles at the current density of 1 A g−1. The superior electrochemical performance of the as-prepared materials was attributed to the yolk–shell structure and smart combination between carbon and MoS2. The yolk–shell structure provided sufficient void space for expansion without causing shell damage, leading to stable structure with long cycle life. The possible formation mechanism for the carbon–MoS2 yolk–shell microsphere was also discussed according to the characterization results.

Graphical Abstract

Carbon (yolk)–MoS2 (shell) hierarchical microspheres were successfully prepared by a facile hydrothermal method with only one step. Materials with yolk–shell structure have been attracted wide attention and could be applied for long-cycle-life energy storage devices. When it was used as the electrode materials, it shown excellent electrochemical properties. Because the yolk–shell microsphere has sufficient void space for expansion without causing the shell to be destroyed, leading to stable structure and cycling.

Keywords

Molybdenum disulfide Carbon Yolk–shell Hydrothermal method Electrochemical performance 

Notes

Acknowledgements

This work is financially supported by Six Talents Peak Project in Jiangsu Province (2011-ZBZZ045) and Student Innovation Project of Jiangsu University (16A061).

References

  1. 1.
    Wang YG, Song YF, Xia YY (2016) Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem Soc Rev 45(21):5925–5950CrossRefGoogle Scholar
  2. 2.
    Cao XH, Tan CL, Zhang X (2016) Solution-processed two-dimensional metal dichalcogenide based annomaterials for energy storage and conversion. Adv Mater 28(29):6167–6196CrossRefGoogle Scholar
  3. 3.
    Wang GP, Zhang L, Zhang JJ (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41(2):797–828CrossRefGoogle Scholar
  4. 4.
    Sun SM, Wang S, Li SD, Li YN, Zhang YH, Chen JL, Zhang ZH, Fang SM, Wang PY (2016) Asymmetric supercapacitors based on a NiCo2O4/three dimensional graphene composite and three dimensional graphene with high energy density. J Mater Chem A 4:18646–18653CrossRefGoogle Scholar
  5. 5.
    Sun SM, Wang PY, Wang S, Wu Q, Fang SM (2015) Fabrication of MnO2/nanoporous 3D graphene for supercapacitor electrodes. Mater Lett 145:141–144CrossRefGoogle Scholar
  6. 6.
    Chhowalla M, Shin HS, Eda G, Li LJ, Loh KP, Zhang H (2013) The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. Nat Chem 5:263–275CrossRefGoogle Scholar
  7. 7.
    Nicolosi V, Chhowalla M, Kanatzidel MG, Strano MS, Coleman JN (2013) Liquid exfoliation of layered materials. Science 340(6139):1226419CrossRefGoogle Scholar
  8. 8.
    Huang X, Zeng ZY, Zhang H (2013) Metal dichalcogenide nanosheets: preparation, properties and applications. Chem Soc Rev 42(5):1934–1946CrossRefGoogle Scholar
  9. 9.
    Wang L, Ma Y, Yang M, Qi YX (2015) Hierarchical hollow MoS2 nanospheres with enhanced electrochemical properities used as an electrode in supercapacitor. Electrochim Acta 186:391–396CrossRefGoogle Scholar
  10. 10.
    Wang BB, Xia Y, Wang G, Zhou YX, Wang H (2017) Core shell MoS2/C nanospheres embedded in foam-like carbon sheets composite with an interconnected macroporous structure as stable and high-capacity anodes for sodium ion batteries. Chem Eng J 309:417–425CrossRefGoogle Scholar
  11. 11.
    Qiu WD, Xia J, He SX, Xu HJ, Zhong HM, Chen LP (2014) Facile synthesis of hollow MoS2 microspheres/amorphous carbon composites and their lithium storage properties. Electrochim Acta 117:145–152CrossRefGoogle Scholar
  12. 12.
    Seh ZW, Li WY, Cha JJ, Zheng GY, Yang Y, McDowell MT, Hsu P-C, Cui Y (2013) Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries. Nat Commun 4:1331–1336CrossRefGoogle Scholar
  13. 13.
    Hu H, Cheng HY, Liu ZF, Li GJ, Zhu QC, Yu Y (2015) In situ polymerized PAN-assisted S/C nanosphere with enhanced high-power performance as cathode for lithium/sulfur batteries. Nano Lett 15(8):5116–5123CrossRefGoogle Scholar
  14. 14.
    Choi SH, Kang YC (2015) Synergetic effect of yolk–shell structure and uniform mixing of SnS–MoS2 nanocrystals for improved Na-ion storage capabilities. ACS Appl Mater Interfaces 7(44):24694–24702CrossRefGoogle Scholar
  15. 15.
    Wang JX, Feng SS (2015) Synthesis of hierarchically porous carbon spheres with yolk–shell structure for high performance supercapacitors. Catal Today 243:199–208CrossRefGoogle Scholar
  16. 16.
    Lou X-W, Yuan CL, Archer LA (2007) Shell-by-shell synthesis of tin oxide hollow colloids with nanoarchitectured walls: cavity size tuning and functionalization. Small 3(2):261–265CrossRefGoogle Scholar
  17. 17.
    Liu N, Wu H (2012) A yolk–shell design for stabilized and scalable Li-ion batteries anodes. Nano Lett 12(6):3315–3321CrossRefGoogle Scholar
  18. 18.
    Zhu T, Wang J, Ho GW (2015) Self-supported yolk–shell nanocolloids towards high capacitance and excellent cycling performance. Nano Energy 18:273–282CrossRefGoogle Scholar
  19. 19.
    Hong YJ, Son MY, Kang YC (2013) One-pot facile synthesis of double-shelled SnO2 yolk–shell-structured powders by continuous process as anode materials for Li-ion batteries. Adv Mater 25(16):2279–2283CrossRefGoogle Scholar
  20. 20.
    Liu J, Qiao SZ, Chen JS, Lou XW, Xing XR, Lu GQ (2011) Yolk/shell nanoparticles: new platforms for nanoreactors, drug delivery and lithium-ion batteries. Chem Commun 47:12578–12591CrossRefGoogle Scholar
  21. 21.
    Deng D, Lee JY (2008) Hollow core–shell mesospheres of crystalline SnO2 nanoparticle aggregates for high capacity Li+ ion storage. Chem Mater 20(5):1841–1846CrossRefGoogle Scholar
  22. 22.
    Zhang WM, Hu JS, Guo YG, Zheng SF, Zhong LS, Song WG, Wan LJ (2008) Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Adv Mater 20(6):1160–1165CrossRefGoogle Scholar
  23. 23.
    Hao L, Lie XL, Zhi LJ (2013) Carbonaceous electrode materials for supercapacitors. Adv Mater 25(28):3899–3904CrossRefGoogle Scholar
  24. 24.
    Lee YH, Zhang XQ, Zhang W, Chang MT, Lin CT, Chang KD, Yu YC, Wang JT, Chang CS, Li LJ, Lin TW (2012) Synthesis of large-area MoS2 atomic layers with chemical vapor deposition. Adv Mater 24(17):2320–2325CrossRefGoogle Scholar
  25. 25.
    Zhang Q, Zhang T, Ge JP, Yin YD (2008) Permeable silica shell through surface-protected etching. Nano Lett 8(9):2867–2871CrossRefGoogle Scholar
  26. 26.
    Lie M, Chang XQ, Han XL, Yin WC, Ren MM (2016) Resorcinol-formaldehyde resin based porous carbon materials with yolk–shell structure for high-performance supercapacitors. Synth Met 219:67–75CrossRefGoogle Scholar
  27. 27.
    Li W, Deng YH, Wu ZX, Qian XF, Yang JP, Wang Y, Gu D, Zhang F, Tu B, Zhao DY (2011) Hydrothermal etching assisted crystallization: a facile route to functional yolk–shell titanate microspheres with ultrathin nanosheets-assembled double shells. J Am Chem Soc 133(40):15830–15833CrossRefGoogle Scholar
  28. 28.
    Wang HL, Liang YY, Mirfakhrai T, Chen Z, Casalongue HS, Dai HJ (2011) Advanced asymmetrical supercapacitors based on graphene hybrid materials. Nano Res 4(8):729–736CrossRefGoogle Scholar
  29. 29.
    Fan LQ, Liu GJ, Zhang CY, Wu JH, Wei YL (2015) Facile one-step hydrothermal preparation of molybdenum disulfide/carbon composite for use in supercapacitor. Int J Hydrog Energy 40(32):10150–10157CrossRefGoogle Scholar
  30. 30.
    Huang KJ, Wang L, Liu YJ, Wang HB, Gan T, Wang LL (2013) Layered MoS2-graphene composites for supercapacitor applications with enhanced capacitive performance. Int J Hydrog Energy 38(32):14027–14034CrossRefGoogle Scholar
  31. 31.
    Kumuthini R, Ramachandran R, Therese HA, Wang F (2017) Electrochemical properties of electrospun MoS2@C nanofiber as electrode material for high-performance supercapacitor application. J Alloy Compd 705:624–630CrossRefGoogle Scholar
  32. 32.
    Hu BL, Qin XY, Asiri AM, Alamry KA, Al-Youbi AO, Sun XP (2013) Synthesis of porous tubular C/MoS2 nanocomposites and their application as a novel electrode material for supercapacitors with excellent cycling stability. Electrochim Acta 100:24–28CrossRefGoogle Scholar
  33. 33.
    Huang KJ, Wang L, Zhang JZ, Wang LL, Mo YP (2014) One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor. Energy 67:234–240CrossRefGoogle Scholar
  34. 34.
    Zhang SC, Hu RR, Dai P, Yu XX, Ding ZL, Wu MZ, Li G, Ma YP, Tu CJ (2017) Synthesis of rambutan-like MoS2/mesoporous carbon spheres nanocomposites with excellent performance for supercapacitors. Appl Surf Sci 396:994–999CrossRefGoogle Scholar
  35. 35.
    Chen M, Dai Y, Wang JJ, Wang Q, Wang YP, Cheng XN, Yan XH (2017) Smart combination of three-dimensional-flower-like MoS2 nanospheres/interconnected carbon nanotubes for application in supercapacitor with enhanced electrochemical performance. J Alloy Compd 696:900–906CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  • Jingjing Wang
    • 1
  • Ming Chen
    • 1
  • Xuehua Yan
    • 1
    • 2
  • Chen Zhou
    • 1
  • Qiong Wang
    • 1
  • Dongfeng Wang
    • 1
  • Xiaoxue Yuan
    • 1
  • Jianmei Pan
    • 1
  • Xiaonong Cheng
    • 1
    • 2
  1. 1.School of Materials Science and EngineeringJiangsu UniversityZhenjiangChina
  2. 2.Institute for Advanced MaterialsJiangsu UniversityZhenjiangChina

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