Magnesium substituted cobalt spinel nanostructures for electrocatalytic water oxidation
- 42 Downloads
Two MgCo2O4 nanostructures in different morphologies have been synthesized by using two different structure-directing agents (urea (U) and nitrilotriacetic acid (NTA)) as new catalysts for water oxidation reactions. The properties of these nanostructures were discovered and characterized by a combination of analytical techniques, being TEM, SEM, EDX, XRD, XPS, and BET. While the urea-stabilized MgCo2O4 (U-MgCo2O4) nanostructures have spiky morphology, the NTA- stabilized ones (NTA-MgCo2O4) have wire-like structures. The synthesized nanostructures were utilized to modify glassy carbon electrodes (GCEs), and the electrochemical activities of the modified electrodes in water oxidation reactions were investigated in an alkaline medium by recording linear sweep voltammograms (LSVs). Even though both modified GCEs had almost the same onset potentials (1.67 V vs. RHE for U-MgCo2O4/GCE and 1.63 V vs. RHE for NTA-MgCo2O4/GCE), NTA-MgCo2O4/GCE required a lower overpotential (463 mV vs. 573 mV) to drive 10 mA cm− 2 catalytic current density. Besides being catalytically more active than U-MgCo2O4/GCE, NTA-MgCo2O4/GCE was also found to be more stable in constant potential electrolysis. Moreover, it demonstrated a comparable performance to that of RuO2 and has the advantage of being significantly economic.
KeywordsWater oxidation Oxygen evolution Spinel MgCo2O4 Metal oxide
We acknowledge the support from TUBITAK, Scientific and Technological Research Council of Turkey, Project: 117Z384. We also acknowledge Prof. Aysen Yilmaz for access to XRD instrument in METU Department of Chemistry.
- 18.Monteverde Videla AHA, Stelmachowski P, Ercolino G, Specchia S (2017) Benchmark comparison of Co3O4 spinel-structured oxides with different morphologies for oxygen evolution reaction under alkaline conditions. J Appl Electrochem 47:295–304. https://doi.org/10.1007/s10800-016-1040-3 CrossRefGoogle Scholar
- 23.Darbar D, Reddy MV, Sundarrajan S et al (2016) Anodic electrochemical performances of MgCo2O4 synthesized by oxalate decomposition method and electrospinning technique for Li-ion battery application. Mater Res Bull 73:369–376. https://doi.org/10.1016/j.materresbull.2015.09.025 CrossRefGoogle Scholar
- 24.Guan X (2018) Morphology-tuned synthesis of MgCo2O4 arrays on graphene coated nickel foam for high-rate supercapacitor electrode. Int J Electrochem Sci 2272–2285. https://doi.org/10.20964/2018.03.35
- 35.Guan X (2018) Magnesium cobaltate nanowires@magnanese Dioxide nanoflakes core-shell arrays on graphene-decorated nickel foam for high-performance supercapacitors. Int J Electrochem Sci 5016–5030. https://doi.org/10.20964/2018.05.14