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Hyperfine Interactions

, 240:21 | Cite as

A novel hybrid nanoparticle based on Fe3O4/TMAOH/poly(L-co-D,L lactic acid-co-trimethylene carbonate) prepared through the solvent displacement method

  • Vagner de Oliveira Machado
  • Ângela Leão AndradeEmail author
  • Luis Carlos Duarte Cavalcante
  • José Domingos Fabris
  • Rosana Zacarias Domingues
  • José Domingos Ardisson
  • Luís E. Fernandez-Outon
  • Carmen Pizarro
  • Carlos Nelson Elias
Article
  • 92 Downloads
Part of the following topical collections:
  1. Proceedings of the 16th Latin American Conference on the Applications of the Mössbauer Effect (LACAME 2018), 18-23 November 2018, Santiago de Chile, Chile

Abstract

TMAOH-dispersed nanoparticles of magnetite were first prepared through the reduction–precipitation of ferric chloride with Na2SO3 and NH4OH. The TMAOH-dispersed (Fe3O4) magnetic nanoparticles were then surface-coated with poly(L-co-D,L lactic acid-co-trimethylene carbonate) (PLDLA-co-TMC) to obtain the corresponding hybrid system (Fe3O4/TMAOH/PLDLA-co-TMC). Samples of so prepared material were analyzed by Fourier-transform infrared spectroscopy (FTIR), powder X-ray diffraction (XRD), magnetization measurements up to 2.5 T, and Mössbauer spectroscopy. Results indicate that this magnetic iron oxide soon after the synthesis is structurally close enough to a typically pure stoichiometric magnetite. FTIR data support clears evidences confirming the efficiency of the solvent displacement method to assure coating the TMAOH-dispersed (Fe3O4) magnetic nanoparticles with the terpolymer while preserves the main chemical structural characteristic of the nanosized magnetite.

Keywords

Magnetite Hybrid nanoparticles Biomaterial 

Notes

Acknowledgements

JD Fabris and LCD Cavalcante are indebted to the Brazilian National Council for the Scientific and Technological Development (CNPq), for the financial support under the grants # 304958-2017-4 and # 313431/2017-5, respectively. The Brazilian Coordination for the Improvement of Higher Education Personnel (CAPES) granted a DSc studenship to VO Machado at Military Insitute of Engineering (Brazil).

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Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Vagner de Oliveira Machado
    • 1
  • Ângela Leão Andrade
    • 2
    Email author
  • Luis Carlos Duarte Cavalcante
    • 3
    • 4
  • José Domingos Fabris
    • 4
    • 5
  • Rosana Zacarias Domingues
    • 4
  • José Domingos Ardisson
    • 6
  • Luís E. Fernandez-Outon
    • 6
  • Carmen Pizarro
    • 7
  • Carlos Nelson Elias
    • 1
  1. 1.Laboratory of BiomaterialsMilitary Institute of Engineering (IME)Rio de JaneiroBrazil
  2. 2.Department of ChemistryFederal University of Ouro Preto (UFOP)Ouro PretoBrazil
  3. 3.Center of Natural SciencesFederal University of Piauí (UFPI)TeresinaBrazil
  4. 4.Department of ChemistryFederal University of Minas Gerais (UFMG)Belo HorizonteBrazil
  5. 5.Institute of ChemistryFederal University of Uberlândia (UFU)UberlândiaBrazil
  6. 6.Laboratory of Applied PhysicsCenter for the Development of the Nuclear Tecnology (CDTN)Belo HorizonteBrazil
  7. 7.Faculty of Chemistry and BiologyUniversity of SantiagoSantiagoChile

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