Glass and Ceramics

, Volume 76, Issue 3–4, pp 145–151 | Cite as

Mechanochemical Oxidation of Aluminum: Formation of the Porous Structure of Aluminum Hydroxides and Oxides

  • A. A. Il’inEmail author
  • R. N. Rumyantsev
  • K. K. Dao
  • A. A. Chuyasova
  • U. S. Uzhevskaya
  • D. S. Popov
  • A. P. Il’in

The main characteristics of aluminum oxides and hydroxides obtained by mechanochemical oxidation of aluminum powder, both in the initial state and after their heat-treatment in the interval 150 – 1100°C, are compared. The conditions for obtaining pseudoboehmite by thermal activation of mechanically oxidized product were established. The structure, morphology, and texture of the pseudoboehmite structure of aluminum hydroxide synthesized from mechanically oxidized product and aluminum oxides obtained on its basis in the temperature interval 450 – 1100°C are characterized.

Key words

aluminum oxide aluminum hydroxide mechanochemical synthesis structure heat-treatment 


  1. 1.
    Yu. A. Mazalov, A. V. Fedotov, A. V. Bersh, et al., “Outlook for applications of nanocrystalline aluminum oxides and hydroxides,” Tekhnol. Metallov, No. 1, 8 – 11 (2008).Google Scholar
  2. 2.
    P. A. Vityaz, A. F. Ilyushenko, L. V. Sudnik, et al., Functional Materials Based on Nanostructured Aluminum Hydroxide Powders [in Russian], Belarus. Navuka, Minsk (2010).Google Scholar
  3. 3.
    A. S. Ivanova, “Aluminum oxide and systems based on it: properties, applications,” Kinetika i Kataliz, 53(4), 446 – 457 (2012).Google Scholar
  4. 4.
    A. A. Ilyin, R. N. Rumyantsev, A. P. Ilyin, et al., “Mechanochemical oxidation of aluminum for obtaining its oxides, hydroxides, and hydrogen,” Zh. Fiz. Khim., 90(4), 1 – 7 (2016).Google Scholar
  5. 5.
    Yu. Yu. Tanashev, E. M. Moroz, L. A. Isupova, et al., “Obtaining aluminum oxides based on the products of rapid thermal decomposition of hydrargillite in a centrifugal flash reactor. I. Physico-chemical properties of the products of centrifugal thermo-activation of hydrargillite,” Kinetika i Kataliz, 48(1), 161 – 170 (2007).Google Scholar
  6. 6.
    E. V. Kul’ko, A. S. Ivanova, V. Yu. Kruglyakov, et al., “Production of aluminum oxides based on the products of rapid thermal decomposition of hydrargillite in a centrifugal flash-reactor. II. Structural and textural properties of hydroxide and aluminum oxide, obtained on the basis of the products of centrifugal-thermal activation of hydrargillite (CTA-product),” Kinetika i Kataliz, 48(2), 332 – 342 (2007).Google Scholar
  7. 7.
    A. P. Lysenko, E. S. Kondratieva, and S. Yu. Shilovskii, “Electrochemical technology for the production of aluminum hydroxide, including the purification of aluminum chloride solution by removal of iron,” Tsvetn. Met., No. 5, 41 – 44 (2018).Google Scholar
  8. 8.
    V. Yu. Tregubenko, I. E. Udras, and A. S. Bely, “Obtaining mesoporous Y-Al2O3 from organic-acid peptized aluminum hydroxide,” Zh. Prikl. Khim., 90(12), 1632 – 1639 (2017).Google Scholar
  9. 9.
    T. M. Karimov, A. D. Muhammadiev, I. I. Gilmutdinov, et al., “Experimental study of the process of producing aluminum hydroxide (boehmite) by hydrothermal synthesis,” Vest. Tekhnolog. Univer., 21(4), 95 – 97 (2018).Google Scholar
  10. 10.
    I. A. Kuznetsov, V. S. Chernoskutov,M. A. Perestoronina, et al., “Ways to produce coarse-grained aluminum hydroxide at the Ural Aluminum Plant,” Tsvetn. Met., No. 1, 57 – 62 (2007).Google Scholar
  11. 11.
    Yu. V. Sharikov, F. Yu. Sharikov, and O. V. Titov, “Optimal control of firing processes in the production of aluminum hydroxide and cement clinker in rotary tube furnaces,” Teor. Osnovy Khim. Tekhnolog., 51(4), 478 – 482 (2017).Google Scholar
  12. 12.
    V. A. Loseva, A. M. Gavrilenkov, A. N. Barannikova, and S. B. Zueva, Method of Producing Aluminum Oxide, RF Pat. No. 2260563 [in Russian], pub. September 20, 2005.Google Scholar
  13. 13.
    V. K. Smirnov, A. B. Bodry, K. N. Irisova, et al., Method for Producing Aluminum Hydroxide Powder (Variants) and Method for Producing Aluminum Oxide, RF Pat. No. 2432318 [in Russian], pub. February 3, 2010.Google Scholar
  14. 14.
    A. S. Ivanova, N. V. Karasyuk, V. Yu. Kruglyakov, et al., Method for Producing Aluminum Hydroxide with Pseudo-Boehmite Structure and Gamma-Alumina Based on It, RF Pat. No. 2234460 [in Russian], pub. May 15, 2003.Google Scholar
  15. 15.
    A. S. Ivanova, “Real structure of metastable forms of aluminum oxide,” Kinetika i Kataliz, 41(1), 155 – 160 (2000).Google Scholar
  16. 16.
    A. A. Il’in, N. N. Smirnov, R. N. Rumyantsev et al, “Mechanochemical synthesis of zinc oxides using liquid and gaseous media,” Zh. Prikl. Zpektrosk., 87(10), 1410 (2014).Google Scholar
  17. 17.
    R. N. Rumyantsev, A. A. Il’in, A. P. Il’in, et al., “Mechanochemical synthesis of iron oxide from iron scrap,” Izv. Vyssh. Uchebn. Zaved., Ser. Khim. Khimich. Tekhnol., 54(3), 50 – 53 (2011).Google Scholar
  18. 18.
    A. A. Il’in, R. N. Rumyantsev, A. P. Il’in, and N. N. Smirnov, Izv. Vyssh. Uchebn. Zaved., Ser. Khim. Khimich. Tekhnol., 54(1), 103 – 107 (2011).Google Scholar
  19. 19.
    K. Jost, Rontgenbeugung in Kristallen, Akad. Vlg, Berlin (1975).Google Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • A. A. Il’in
    • 1
    Email author
  • R. N. Rumyantsev
    • 1
    • 2
  • K. K. Dao
    • 1
  • A. A. Chuyasova
    • 1
  • U. S. Uzhevskaya
    • 1
  • D. S. Popov
    • 1
  • A. P. Il’in
    • 1
  1. 1.Ivanovo State University of Chemical Technology (ISUCT)IvanovoRussia
  2. 2.Scientific-Research Institute of Thermodynamics and Kinetics of Chemical Processes at Ivanovo State University of Chemical TechnologyIvanovoRussia

Personalised recommendations