Advertisement

Fibre Chemistry

, Volume 51, Issue 1, pp 9–13 | Cite as

X-Ray Structure and PMR Spectra of Polycaproamide Modified by a Polyfluorinated Alcohol

  • S. V. KudashevEmail author
  • N. A. Zhuravlev
  • V. M. Shapovalov
  • T. A. Denisova
  • A. M. Valenkov
  • V. F. Zheltobryukhov
Article
  • 7 Downloads

Effects on polycaproamide structure of a polyfluorinated alcohol immobilized on montmorillonite clay nanoparticles were studied using x-ray structure analysis and broad-line PMR spectroscopy. An exfoliated composite formed and caused the crystal and molecular structures of this heterochain polymer to reorganize. A composite based on the polyfluorinated alcohol changed the mobility of macromolecular chain segments and increased the fraction of planar trans-conformations.

References

  1. 1.
    I. A. Novakov, N. A. Storozhakova, et al., Vysokomol. Soedin., Ser. B, 48, No. 1, 121-125 (2005).Google Scholar
  2. 2.
    I. A. Novakov, N. A. Rakhimova, et al., Zh. Prikl. Khim., 82, No. 1, 160-164 (2009).Google Scholar
  3. 3.
    S. V. Kudashev, Ya. V. Zubavichus, et al., Trenie Iznos, 34, No. 5, 524-529 (2013).Google Scholar
  4. 4.
    I. A. Novakov, N. A. Rakhimova, et al., Trenie Iznos, 32, No. 5, 476-488 (2011).Google Scholar
  5. 5.
    I. A. Novakov, N. A. Rakhimova, et al., Trenie Iznos, 32, No. 4, 344-354 (2011).Google Scholar
  6. 6.
    S. V. Kudashev, V. V. Rodaev, et al., Khim. Volokna, No. 5, 37-39 (2017).Google Scholar
  7. 7.
    S. V. Kudashev, S. A. Safronov, et al., Zh. Prikl. Khim., 90, No. 5, 642-647 (2017).Google Scholar
  8. 8.
    S. V. Kudashev, A. M. Valenkov, et al., Zh. Prikl. Khim., 90, No 8, 1089-1095 (2017).Google Scholar
  9. 9.
    N. A. Rakhimova and S. V. Kudashev, Zh. Prikl. Khim., 83, No. 11, 1905-1910 (2010).Google Scholar
  10. 10.
    V. K. Kapustkin, R. N. Pletnev, and V. P. Ivanov, Analysis of Nuclear Magnetic Resonance Spectra of Polycrystalline Hydrates [in Russian], UNTs AN SSSR, Sverdlovsk, 1985, 125 pp.Google Scholar
  11. 11.
    K. Bergmann, J. Polym. Sci., Polym. Phys. Ed., 16, 1011-1015 (1978).CrossRefGoogle Scholar
  12. 12.
    F. Auriemma, V. Petraccone, et al., Macromolecules, 30, No. 24, 7554-7559 (1997).CrossRefGoogle Scholar
  13. 13.
    I. A. Novakov, N. A. Storozhakova, et al., Vysokomol. Soedin., Ser. B, 49, No. 3, 559-564 (2007).Google Scholar
  14. 14.
    Y.-W. Mai and Z.-Z. Yu (eds.), Polymer Nanocomposites, Woodhead Publishing, Cambridge, 2006, 594 pp.CrossRefGoogle Scholar
  15. 15.
    L. A. Utracki, Clay-Containing Nanocomposites, Vol. 1, 2, Rapra Technol. Ltd., UK, 2004.Google Scholar
  16. 16.
    N. Abacha, M. Kubouchi, and T. Sakai, eXPRESS Polym. Lett., 3, No. 4, 245-255 (2009).CrossRefGoogle Scholar
  17. 17.
    T. L. Lebedeva, S. V. Shapovalov, and N. A. Plate, Vysokomol. Soedin., Ser. A, 38, No. 12, 1986-1992 (1996).Google Scholar
  18. 18.
    R. Blinc, T. Apih, et al., Appl. Magn. Reson., 29, 577 (2005).CrossRefGoogle Scholar
  19. 19.
    K. Jelsovska, Acta Electrotech. Inf., 2, No. 3 (2002); http://www.aei.tuke.sk/papers/2002/3/JELSOVSKA.pdf
  20. 20.
    D. Uo and E. I. Fedin, Fiz. Tverd. Tela, 4, No. 8, 2233-2237 (1962).Google Scholar

Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • S. V. Kudashev
    • 1
    Email author
  • N. A. Zhuravlev
    • 2
  • V. M. Shapovalov
    • 3
  • T. A. Denisova
    • 2
  • A. M. Valenkov
    • 4
  • V. F. Zheltobryukhov
    • 1
  1. 1.Volgograd State Technical UniversityVolgogradRussia
  2. 2.Institute of Solid State Chemistry, Ural BranchRussian Academy of SciencesEkaterinburgRussia
  3. 3.V. A. Belyi Metal-Polymer Research InstituteNational Academy of Sciences of BelarusGomelBelarus
  4. 4.Gomel State Medical UniversityHomieĺBelarus

Personalised recommendations