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Estimation of potential arsenic leaching from its phases in excavated sedimentary and metamorphic rocks

  • Shoji Suzuki
  • Masahiko KatohEmail author
Original Paper

Abstract

It is important that hazardous excavated sedimentary and metamorphic rocks are treated appropriately and reused without posing an environmental risk. Up-flow column leaching tests were conducted to examine whether arsenic leaching behavior varied among five hazardous excavated sedimentary and metamorphic rocks (two mudstones, clay sediment of marine origin, slate, and black schist) and to determine whether the potential amount of arsenic leaching could be estimated based on the arsenic-bearing mineral phases in the rock. Changes in arsenic concentration with pore volume (PV) showed the same pattern across all rock types, except for one that contained an extremely low amount of water-soluble arsenic, exhibiting an initial increase to reach a peak, followed by a decrease. The arsenic amounts leached before and after the PV at which the arsenic concentration peaked, corresponded to 88% ± 20% of the amount of arsenic fraction 1 obtained by sequential extraction and 76% ± 10% of the amount of arsenic fraction 2, respectively, while the potential amount of arsenic leaching corresponded to 65–89% of the summed total of arsenic fractions 1 + 2. These findings indicate that arsenic exhibits the same leaching behavior among different types of hazardous excavated sedimentary and metamorphic rocks except where extremely low amounts of water-soluble arsenic are present and that the potential amount of arsenic leaching can be approximated by calculating the summed total of arsenic fractions 1 + 2, which allows us to estimate the minimum amount of material required for treatments such as immobilization conducted to prevent arsenic leaching.

Keywords

Arsenic leaching Arsenic phases Column leaching test Excavated metamorphic rock Excavated sedimentary rock 

Notes

Acknowledgements

The authors are grateful to Mrs. T. Miura and T. Higasayama for rock sample collection.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interests.

Supplementary material

10653_2019_371_MOESM1_ESM.doc (758 kb)
Supplementary material 1 (DOC 758 kb)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of Agricultural Chemistry, School of AgricultureMeiji UniversityKawasakiJapan

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