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Chemistry of Heterocyclic Compounds

, Volume 55, Issue 4–5, pp 478–480 | Cite as

Peculiarities of 4-methallyl-5-methallylamino-1,2,4-triazole-3-thione halogenation

  • Maksym M. Fizer
  • Mikhailo V. SlivkaEmail author
  • Vasil G. Lendel
Article
  • 2 Downloads

Bromination and iodination of 4-methallyl-5-methallylamino-1,2,4-triazole-3-thione lead to the annulation of five- and six-membered thiazaheterocycles, respectively. The usage of halogen excess does not give the product of 5-methallylamino group cyclization – the product of the bromine addition was isolated.

Keywords

[1,3]thiazolo[2,3-c][1,2,4]triazole 1,2,4-triazole [1,2,4]triazolo[3,4-b][1,3]thiazine electrophilic cyclization halogenation 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Maksym M. Fizer
    • 1
  • Mikhailo V. Slivka
    • 1
    Email author
  • Vasil G. Lendel
    • 1
  1. 1.Uzhhorod National UniversityUzhhorodUkraine

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