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Solvent-free Preparation of 5-Aryloxytetrazoles via [2+3] Cycloaddition of Cyanates and Sodium Azide Using Silica Supported Sulfuric Acid as an Effective Heterogeneous Catalyst

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Chemistry of Heterocyclic Compounds Aims and scope

A simple and efficient method is described for the preparation of 5-aryloxytetrazoles in excellent yields and high purity from aryl cyanates using silica sulfuric acid as catalyst. The rate of product formation was enhanced by introduction of electron-donating substituents. The 1H NMR spectral characteristics of the products are also discussed.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Zabol, Zabol, Iran

    F. Khamooshi, B. Haghighi, K. Jhaleh & R. Aryan

  2. University of Sistan & Baluchestan, Zahedan, Iran

    A. R. Modarresi Alam, A. R. Rezvani, A. A. Mirzaei & M. T. Maghsoodlou

Authors
  1. F. Khamooshi
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  2. B. Haghighi
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  3. K. Jhaleh
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  4. R. Aryan
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  5. A. R. Modarresi Alam
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  6. A. R. Rezvani
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  7. A. A. Mirzaei
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  8. M. T. Maghsoodlou
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Corresponding author

Correspondence to F. Khamooshi.

Additional information

Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1578-1582, October, 2013.

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Khamooshi, F., Haghighi, B., Jhaleh, K. et al. Solvent-free Preparation of 5-Aryloxytetrazoles via [2+3] Cycloaddition of Cyanates and Sodium Azide Using Silica Supported Sulfuric Acid as an Effective Heterogeneous Catalyst. Chem Heterocycl Comp 49, 1464–1468 (2014). https://doi.org/10.1007/s10593-014-1397-3

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  • DOI: https://doi.org/10.1007/s10593-014-1397-3

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