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Monitoring of cellulose oxidation level by electrokinetic phenomena and numeric prediction model

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Abstract

Cellulose with a low level of oxidation is suitable for producing stable long-lasting materials with high added value, while extensively oxidized once is applicable for disposable products. In our previous comprehensive research, the fundamental behavior of the cotton under the action of different oxidants has been explored. Different levels of oxidation, as well as the type of functional groups, have been achieved by properly selected oxidants while controlling their concentration and treatment time. In this research, the electrokinetic ζ-potential of KIO4 and TEMPO-oxidized cotton and the isoelectric point are measured by the streaming potential method, while the surface charge is calculated from the adsorbed cationic surfactant by the back-titration method. The results of electrokinetic phenomena are compared with the amount of created carboxyl groups determined by the calcium acetate method. The machine learning algorithms Waikato Environment for Knowledge Analysis for regression analysis is employed to develop models that make numeric predictions of the ζ-potential values based on the known number of carboxyl groups. The model with the correlation coefficient between the actual and the predicted value of ζ-potential is given for the first time.

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Acknowledgments

This work has been supported in part by Croatian Science Foundation under the project UIP-2017-05-8780 HPROTEX.

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Authors and Affiliations

  1. Department of Textile Chemistry and Ecology, Faculty of Textile Technology, University of Zagreb, Prilaz baruna Filipovica 28a, Zagreb, Croatia

    Anita Tarbuk & Katia Grgić

  2. Department of Textile Engineering, Faculty of Technology and Metallurgy, Ss. Cyril and Methodius University, Ruger Boskovic 16, 1000, Skopje, Republic of North Macedonia

    Emilija Toshikj & Igor Jordanov

  3. Department of Fundamental Natural and Engineering Sciences, Faculty of Textile Technology, University of Zagreb, Prilaz baruna Filipovica 28a, Zagreb, Croatia

    Daniel Domović

  4. Department of Chemical and Control Engineering, Faculty of Technology and Metallurgy, Ss. Cyril and Methodius University, Ruger Boskovic 16, 1000, Skopje, Republic of North Macedonia

    Dejan Dimitrovski

  5. Department of Organic Technology, Faculty of Technology and Metallurgy, Ss. Cyril and Methodius University, Ruger Boskovic 16, 1000, Skopje, Republic of North Macedonia

    Vesna Dimova

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  1. Anita Tarbuk
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  2. Katia Grgić
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  3. Emilija Toshikj
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  4. Daniel Domović
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  6. Vesna Dimova
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  7. Igor Jordanov
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Correspondence to Anita Tarbuk or Igor Jordanov.

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Tarbuk, A., Grgić, K., Toshikj, E. et al. Monitoring of cellulose oxidation level by electrokinetic phenomena and numeric prediction model. Cellulose 27, 3107–3119 (2020). https://doi.org/10.1007/s10570-020-03028-6

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