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Cellulose

pp 1–16 | Cite as

Production of cellulose aerogels from coir fibers via an alkali–urea method for sorption applications

  • Mar’atul Fauziyah
  • Widiyastuti Widiyastuti
  • Ratna Balgis
  • Heru SetyawanEmail author
Original Research
  • 5 Downloads

Abstract

Biodegradable cellulose aerogels have been successfully prepared from coir fibers using a sulfur-free method and NaOH–urea system. Sulfur was avoided during pretreatment because it is environmentally harmful. Interestingly, these pretreatments had a strong effect on the physical properties of the aerogels produced. Good physical properties of the cellulose aerogels were obtained when the Kappa number, i.e., the lignin content, in the pulp was lower than 14.8. NaOH–urea played an important role in transforming cellulose I to cellulose II and crosslinked cellulose to form an aerogel structure. The aerogel had a macroporous structure, ultralight density, high porosity, good durability, and thermal stability. The aerogel was capable of absorbing 22 and 18 times its dry weight in water and oil, respectively. The material also had a high capacity for methylene blue dye adsorption of up to 62 g/g, which was one hundred times higher than that of adsorbents synthesized from the other natural matters. Therefore, the prepared aerogels have potential for various sorption applications.

Graphic abstract

Keywords

NaOH–urea system Absorbent Adsorbent Coir fibers Cellulose aerogel 

Notes

Acknowledgments

This work was supported by the Ministry of Research, Technology and Higher Education, Indonesia through a PMDSU Research Grant (Contract Numbers 15304/IT2.11/HK.00.02/2016, 77186/IT2.VII/HK.00.02/2017, and 798/PKS/ITS/2018). One of the authors (M.F.) would like to thank the Ministry of Research, Technology and Higher Education, Indonesia, for a doctoral scholarship through PMDSU. We thank Ms. Tiara Nur Pratiwi and Mr. Muhammad Abid Hidayatullah for their assistance with the experiments. We also thank Ms. Annie Mufyda Rahmatika for the TGA analysis.

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© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Department of Chemical Engineering, Faculty of Industrial TechnologySepuluh Nopember Institute of TechnologySurabayaIndonesia
  2. 2.Department of Chemical Engineering, Graduate School of EngineeringHiroshima UniversityHigashi-HiroshimaJapan

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