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Fabrication of Ag/AgCl/ZIF-8/TiO2 decorated cotton fabric as a highly efficient photocatalyst for degradation of organic dyes under visible light

  • Xinmei Guan
  • Shaojian LinEmail author
  • Jianwu LanEmail author
  • Jiaojiao Shang
  • Wenxu Li
  • Yifei Zhan
  • Hongyan Xiao
  • Qingshuang Song
Original Research
  • 22 Downloads

Abstract

In this work, a photocatalyst Ag/AgCl/ZIF-8/TiO2 was facilely assembled on the surface of cotton fabrics via a simple method to fabricate a visible-light photocatalyst composite. The resultant cotton fabric was comprehensively characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and UV–vis diffuse reflection spectroscopy. The results showed that the Ag/AgCl/ZIF-8/TiO2 aggregations have successfully assembled on the surface of cotton fabric. Subsequently, Ag/AgCl/ZIF-8/TiO2 coated cotton fabric was employed as a visible-light photocatalytic material for degradation of organic dyes using methylene blue (MB) as a model. Owing to the synergistic effect of the Ag/AgCl/ZIF-8/TiO2 composite, the functional cotton fabric presented highly efficient photocatalytic degradation performance towards MB, the degradation of MB by Ag/AgCl/ZIF-8/TiO2 coated cotton fabric can reach to 98.5% within 105 min under visible light irradiation. Moreover, the first-order kinetic constant of photocatalytic degradation was 0.0332 min−1. Additionally, Ag/AgCl/ZIF-8/TiO2 coated cotton fabric exhibited acceptable cycle stability. The photocatalytic degradation capacity of MB still can maintain approximately 85% after three cycles. Therefore, Ag/AgCl/ZIF-8/TiO2 coated cotton fabric can be viewed as a good material for dye wastewater treatment due to its good photocatalytic activity and acceptable cycle ability.

Graphic abstract

Keywords

Ag/AgCl/ZIF-8/TiO2 composite Cotton fabric Photocatalytic degradation Methylene blue 

Notes

Acknowledgments

This work was supported by “the Fundamental Research Funds for the Central Universities” (No: YJ201823). We would like to thank the Analytical & Testing Center of Sichuan University for SEM and XPS measurements.

References

  1. Ahmed A, Forster M, Jin JS, Myers P, Zhang HF (2015) Tuning morphology of nanostructured ZIF-8 on silica microspheres and applications in liquid chromatography and dye degradation. ACS Appl Mater Interfaces 7(32):18054–18063.  https://doi.org/10.1021/acsami.5b04979 Google Scholar
  2. Aijaz A, Fujiwara N, Xu Q (2014) From metal-organic framework to nitrogen-decorated nanoporous carbons: high CO2, uptake and efficient catalytic oxygen reduction. J Am Chem Soc 136(19):6790–6793.  https://doi.org/10.1021/ja5003907 Google Scholar
  3. Asghar A, Raman AAA, Daud WMAW (2015) Advanced oxidation processes for in situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: a review. J Clean Prod 87:826–838.  https://doi.org/10.1016/j.jclepro.2014.09.010 Google Scholar
  4. Bux H, Feldhoff A, Cravillon J, Wiebcke M, Caro J (2011) Oriented zeolitic imidazolate framework-8 membrane with sharp H2/C3H8 molecular sieve separation. Chem Mater 23(8):2262–2269.  https://doi.org/10.1021/cm200555s Google Scholar
  5. Chandra R, Mukhopadhyay S, Nath M (2016) TiO2@ZIF-8: a novel approach of modifying micro environment for enhanced photo-catalytic dye degradation and high usability of TiO2 nanoparticles. Mater Lett 164:571–574.  https://doi.org/10.1016/j.matlet.2015.11.018 Google Scholar
  6. Cheng DS, He MT, Ran JH, Cai GM et al (2017) In situ reduction of TiO2 nanoparticles on cotton fabrics through polydopamine templates for photocatalysis and UV protection. Cellulose 25(2):1413–1424.  https://doi.org/10.1007/s10570-017-1606-1 Google Scholar
  7. Cravillon J, Munzer S, Lohmeier SJ, Feldhoff A, Huber K, Wiebcke M (2009) Rapid room-temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework. Chem Mater 21(8):1410–1412.  https://doi.org/10.1021/cm900166h Google Scholar
  8. Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Biores Technol 97(9):1061–1085.  https://doi.org/10.1016/j.biortech.2005.05.001 Google Scholar
  9. de Souza ML, dos Santos DP, Corio P (2018) Localized surface plasmon resonance enhanced photocatalysis: an experimental and theoretical mechanistic investigation. RSC Adv 8(50):28753–28762.  https://doi.org/10.1039/C8RA03919D Google Scholar
  10. Ding K, Wang W, Yu D, Gao P, Liu BJ (2018) Facile formation of flexible Ag/AgCl/polydopamine/cotton fabric composite photocatalysts as an efficient visible-light photocatalysts. Appl Surf Sci 454(10):101–111.  https://doi.org/10.1016/j.apsusc.2018.05.154 Google Scholar
  11. Domingues RCC, Pereira CC, Borges CP et al (2017) Morphological control and properties of poly(lactic acid) hollow fibers for biomedical applications. J Appl Polym Sci 134(47):45494.  https://doi.org/10.1002/app.45494 Google Scholar
  12. Fan GD, Luo J, Guo L, Lin RJ et al (2018a) Doping Ag/AgCl in zeolitic imidazolate framework-8 (ZIF-8) to enhance the performance of photodegradation of methylene blue. Chemosphere 209:44–52.  https://doi.org/10.1016/j.chemosphere.2018.06.036 Google Scholar
  13. Fan GD, Zheng XM, Luo J, Peng HP, Lin H et al (2018b) Rapid synthesis of Ag/AgCl@ZIF-8 as a highly efficient photocatalyst for degradation of acetaminophen under visible light. Chem Eng J 351:782–790.  https://doi.org/10.1016/j.cej.2018.06.119 Google Scholar
  14. Fang HB, Cao X, Yu JJ, Lv X, Yang N et al (2019) Preparation of the all-solid-state Z-scheme WO3/Ag/AgCl film on glass accelerating the photodegradation of pollutants under visible light. J Mater Sci 54(1):286–301.  https://doi.org/10.1007/s10853-018-2856-5 Google Scholar
  15. Feng CX, Wang SZ, Geng BY (2011) Ti(iv) doped WO3 nanocuboids: fabrication and enhanced visible-light-driven photocatalytic performance. Nanoscale 3(9):3695–3699.  https://doi.org/10.1039/c1nr10460h Google Scholar
  16. Feng Y, Lu HG, Gu XL, Qiu JH et al (2017) Zif-8 derived porous n-doped ZnO with enhanced visible light-driven photocatalytic activity. J Phys Chem Solids 102:110–114.  https://doi.org/10.1016/j.jpcs.2016.11.022 Google Scholar
  17. French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896.  https://doi.org/10.1007/s10570-013-0030-4 Google Scholar
  18. Frunza L, Diamandescu L, Zgura I et al (2017) Photocatalytic activity of wool fabrics deposited at low temperature with ZnO or TiO2, nanoparticles: methylene blue degradation as a test reaction. Catal Today 306:251–259.  https://doi.org/10.1016/j.cattod.2017.02.044 Google Scholar
  19. Ghayempour S, Montazer M (2016) A robust friendly nano-encapsulated plant extract in hydrogel tragacanth gumon cotton fabric through one single step in situ synthesis and fabrication. Cellulose 23(4):2561–2572.  https://doi.org/10.1007/s10570-016-0958-2 Google Scholar
  20. Han L, Xu ZK, Wang P, Dong SJ (2013) Facile synthesis of a free-standing Ag@Agcl film for a high performance photocatalyst and photodetector. Chem Commun 49(43):4953–4955.  https://doi.org/10.1039/c3cc41798k Google Scholar
  21. Han BY, Hu XX, Yu MB, Peng TT, Li Y, He GH (2018) One-pot synthesis of enhanced fluorescent copper nanoclusters encapsulated in metal–organic frameworks. RSC Adv 8(40):22748–22754.  https://doi.org/10.1039/C8RA03632B Google Scholar
  22. Ibănescu M, Musat V, Textor T, Badilita V, Mahltig B et al (2014) Photocatalytic and antimicrobial Ag/ZnO nanocomposites for functionalization of textile fabrics. J Alloys Compd 610:244–249.  https://doi.org/10.1016/j.jallcom.2014.04.138 Google Scholar
  23. Jing HP, Wang CC, Zhang YW, Wang P, Li R (2014) Photocatalytic degradation of methylene blue in zif-8. RSC Adv 4(97):54454–54462.  https://doi.org/10.1039/c4ra08820d Google Scholar
  24. Karimi L, Yazdanshenas ME, Khajavi R, Rashidi A, Mirjalili M et al (2015) Functional finishing of cotton fabrics using graphene oxide nanosheets decorated with titanium dioxide nanoparticles. J Text Inst 107(9):1122–1134.  https://doi.org/10.1080/00405000.2015.1093311 Google Scholar
  25. Kaushik VK (1991) XPS core level spectra and auger parameters for some silver compounds. J Electron Spectrosc Relat Phenom 56(3):273–277.  https://doi.org/10.1016/0368-2048(91)85008-H Google Scholar
  26. Kole AK, Tiwary CS, Kumbhakar P (2013) Ethylenediamine assisted synthesis of wurtzite zinc sulphide nanosheets and porous zinc oxide nanostructures: near white light photoluminescence emission and photocatalytic activity under visible light irradiation. CrystEngComm 15(27):5515–5525.  https://doi.org/10.1039/c3ce40531a Google Scholar
  27. Kumbhakar P, Biswas S, Tiwary CS, Kumbhakar P (2017) Near white light emission and enhanced photocatalytic activity by tweaking surface defects of coaxial ZnO@ZnS core-shell nanorods. J Appl Phys 121(14):144301.  https://doi.org/10.1063/1.4980011 Google Scholar
  28. Kumbhakar P, Pramanik A, Biswas S et al (2018) In-situ synthesis of rGO-ZnO nanocomposite for demonstration of sunlight driven enhanced photocatalytic and self-cleaning of organic dyes and tea stains of cotton fabrics. J Hazard Mater 360:193–203.  https://doi.org/10.1016/j.jhazmat.2018.07.103 Google Scholar
  29. Li CM, Chen G, Sun J, Rao JC, Han ZH, Hu YD et al (2016a) Doping effect of phosphate in Bi2WO6 and universal improved photocatalytic activity for removing various pollutants in water. Appl Catal B 188:39–47.  https://doi.org/10.1016/j.apcatb.2016.01.054 Google Scholar
  30. Li SH, Huang JY, Chen Z, Chen GQ, Lai YK (2016b) A review on special wettability textiles: theoretical models, fabrication technologies and multifunctional applications. J Mater Chem A 5(1):31–55.  https://doi.org/10.1016/10.1039/c6ta07984a Google Scholar
  31. Li XY, Li X, Zhu BY, Wang JS, Lan HX, Chen XB et al (2017) Synthesis of porous ZnS, ZnO and ZnS/ZnO nanosheets and their photocatalytic properties. RSC Adv 7(49):30956–30962.  https://doi.org/10.1039/c7ra03243a Google Scholar
  32. Liu JX, Li R, Wang YF, Wang YW, Zhang XC, Fan CM (2017a) The active roles of zif-8 on the enhanced visible photocatalytic activity of Ag/AgCl: generation of superoxide radical and adsorption. J Alloy Compd 693:543–549.  https://doi.org/10.1016/j.jallcom.2016.09.201 Google Scholar
  33. Liu JX, Li R, Hu YY, Li T, Jia ZH et al (2017b) Harnessing Ag nanofilm as an electrons transfer mediator for enhanced visible light photocatalytic performance of Ag@AgCl/Ag nanofilm/ZIF-8 photocatalyst. Appl Catal B Environ 202:64–71.  https://doi.org/10.1016/j.apcatb.2016.09.015 Google Scholar
  34. Lu G, Li SZ, Guo Z, Far OK, Hauser BG, Qi XY et al (2012) Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation. Nat Chem 4(4):310–316.  https://doi.org/10.1038/nchem.1272 Google Scholar
  35. Mahdieh ZM, Ahekarriz S, Taromi FA, Montazer M (2018) A new method for in situ synthesis of Ag–TiO2 nanocomposite particles on polyester/cellulose fabric by photoreduction and self-cleaning properties. Cellulose 25(4):2355–2366.  https://doi.org/10.1007/s10570-018-1694-6 Google Scholar
  36. Malato S, Maldonado MI, Fernandez-lbanez P, Oller I, Polo I, Sanchez-Moreno R (2015) Decontamination and disinfection of water by solar photocatalysis: the pilot plants of the plataforma solar de almeria. Mater Sci Semicond Process 42(1):15–23.  https://doi.org/10.1016/j.mssp.2015.07.017 Google Scholar
  37. Metivier-Pignon H, Faur-Brasquet C, Le Cloirec P (2003) Adsorption of dyes onto activated carbon cloths: approach of adsorption mechanisms and coupling of ACC with ultrafiltration to treat coloured wastewaters. Sep Purif Technol 31(1):3–11.  https://doi.org/10.1016/S1383-5866(02)00147-8 Google Scholar
  38. Park KS, Ni Z, Cote AP, Choi JY, Huang RD, Uribe-Romo FJ et al (2006) Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proc Natl Acad Sci U S A 103(27):10186–10191.  https://doi.org/10.1073/pnas.0602439103 Google Scholar
  39. Qin Q, Guo RH, Lin SJ, Jiang SX, Lan JW, Lai XX et al (2019) Waste cotton fiber/Bi2WO6 composite film for dye removal. Cellulose 26(6):3909–3922.  https://doi.org/10.1007/s10570-019-02345-9 Google Scholar
  40. Rafatullah M, Sulaiman O, Hashim R, Ahmad A (2010) Adsorption of methylene blue on low-cost adsorbents: a review. J Hazard Mater 177(1–3):70–80.  https://doi.org/10.1016/j.jhazmat.2009.12.047 Google Scholar
  41. Rahman PM, Muraleedaran K, Mujeeb VMA (2015) Applications of chitosan powder with in situ synthesized nano ZnO particles as an antimicrobial agent. Int J Biol Macromol 77:266–272.  https://doi.org/10.1016/j.ijbiomac.2015.03.058 Google Scholar
  42. Rong YG, Liu LF, Mei AY, Li X, Han HW (2015) Beyond efficiency: the challenge of stability in mesoscopic perovskite solar cells. Adv Energy Mater 5(20):1501066.  https://doi.org/10.1002/aenm.201501066 Google Scholar
  43. Sahito IA, Sun KC, Arbab AA, Qadir MB, Jeong SH (2015) Integrating high electrical conductivity and photocatalytic activity in cotton fabric by cationizing for enriched coating of negatively charged graphene oxide. Carbohyd Polym 130:299–306.  https://doi.org/10.1016/j.carbpol.2015.05.010 Google Scholar
  44. Shannon MA, Bohn PW, Elimelech M, Georgiadis JG et al (2008) Science and technology for water purification in the coming decades. Nature 452(7185):301–310.  https://doi.org/10.1038/nature06599 Google Scholar
  45. Song YH, Hu DQ, Liu FF, Chen SH, Wang L et al (2014) Fabrication of fluorescent SiO2@zeolitic imidazolate framework-8 nanosensor for Cu2+ detection. The Analyst 140(2):623–629.  https://doi.org/10.1039/C4AN01773K Google Scholar
  46. Tauc JC (1974) Amorphous and liquid semiconductors. Springer, Boston, pp 25–27Google Scholar
  47. Wang H, Yuan XZ, Wu Y, Zeng GM, Chen XH, Leng LJ et al (2015) Synthesis and applications of novel graphitic carbon nitride/metal-organic frameworks mesoporous photocatalyst for dyes removal. Appl Catal B Environ 174:445–454.  https://doi.org/10.1016/j.apcatb.2015.03.037 Google Scholar
  48. Wee LH, Janssens N, Sree SP, Wiktor C, Gobechiya E, Fischer RA et al (2014) Local transformation of ZIF-8 powders and coatings into ZnO nanorods for photocatalytic application. Nanoscale 6(4):2056–2060.  https://doi.org/10.1039/c3nr05289c Google Scholar
  49. Wu DY, Wang LZ, Song XJ, Tan YB (2013) Enhancing the visible-light-induced photocatalytic activity of the self-cleaning TiO2-coated cotton by loading Ag/AgCl nanoparticles. Thin Solid Films 540:36–40.  https://doi.org/10.1016/j.tsf.2013.05.113 Google Scholar
  50. Xu H, Li HM, Xia JX, Yin S, Luo ZJ, Liu L, Xu L et al (2011) One-pot synthesis of visible-light-driven plasmonic photocatalyst Ag/AgCl in ionic liquid. ACS Appl Mater Interfaces 3(1):22–29.  https://doi.org/10.1021/am100781n Google Scholar
  51. Zeng X, Huang LQ, Wang CN, Wang JS, Li JT, Luo XT (2016) Sonocrystallization of ZIF-8 on electrostatic spinning TiO2 nanofibers surface with enhanced photocatalysis property through synergistic effect. ACS Appl Mater Interfaces 8(31):20274–20282.  https://doi.org/10.1021/acsami.6b05746 Google Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Xinmei Guan
    • 1
  • Shaojian Lin
    • 1
    Email author
  • Jianwu Lan
    • 1
    Email author
  • Jiaojiao Shang
    • 1
  • Wenxu Li
    • 1
  • Yifei Zhan
    • 1
  • Hongyan Xiao
    • 1
  • Qingshuang Song
    • 1
  1. 1.College of Light Industry and Textile and Food EngineeringSichuan UniversityChengduChina

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